GB1438417A - Detergent composition - Google Patents
Detergent compositionInfo
- Publication number
- GB1438417A GB1438417A GB4352374A GB4352374A GB1438417A GB 1438417 A GB1438417 A GB 1438417A GB 4352374 A GB4352374 A GB 4352374A GB 4352374 A GB4352374 A GB 4352374A GB 1438417 A GB1438417 A GB 1438417A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sulphate
- polycarboxylate
- weight ratio
- detergent composition
- organic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003599 detergent Substances 0.000 title abstract 4
- 239000000203 mixture Substances 0.000 title abstract 4
- 229920005646 polycarboxylate Polymers 0.000 abstract 5
- 125000003342 alkenyl group Chemical group 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 229910021645 metal ion Inorganic materials 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 239000004254 Ammonium phosphate Substances 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 abstract 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 abstract 1
- 229940022663 acetate Drugs 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 125000002877 alkyl aryl group Chemical group 0.000 abstract 1
- 239000001132 aluminium potassium sulphate Substances 0.000 abstract 1
- 235000011126 aluminium potassium sulphate Nutrition 0.000 abstract 1
- 239000001164 aluminium sulphate Substances 0.000 abstract 1
- 235000011128 aluminium sulphate Nutrition 0.000 abstract 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 abstract 1
- 235000019289 ammonium phosphates Nutrition 0.000 abstract 1
- 239000003945 anionic surfactant Substances 0.000 abstract 1
- 229940050390 benzoate Drugs 0.000 abstract 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 229940001468 citrate Drugs 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 abstract 1
- BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 abstract 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 abstract 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 abstract 1
- KIWBPDUYBMNFTB-UHFFFAOYSA-M ethyl sulfate Chemical compound CCOS([O-])(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-M 0.000 abstract 1
- -1 fluorosilicate Chemical compound 0.000 abstract 1
- 229940104869 fluorosilicate Drugs 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 125000000468 ketone group Chemical group 0.000 abstract 1
- 229940049920 malate Drugs 0.000 abstract 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N malic acid Chemical compound OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002736 metal compounds Chemical class 0.000 abstract 1
- 239000002736 nonionic surfactant Substances 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Chemical group 0.000 abstract 1
- GRLPQNLYRHEGIJ-UHFFFAOYSA-J potassium aluminium sulfate Chemical compound [Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRLPQNLYRHEGIJ-UHFFFAOYSA-J 0.000 abstract 1
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 abstract 1
- 229960001860 salicylate Drugs 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 239000001119 stannous chloride Substances 0.000 abstract 1
- 235000011150 stannous chloride Nutrition 0.000 abstract 1
- 229940086735 succinate Drugs 0.000 abstract 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 abstract 1
- 229910021653 sulphate ion Inorganic materials 0.000 abstract 1
- 229940095064 tartrate Drugs 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 abstract 1
- 239000011686 zinc sulphate Substances 0.000 abstract 1
- 235000009529 zinc sulphate Nutrition 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/123—Sulfonic acids or sulfuric acid esters; Salts thereof derived from carboxylic acids, e.g. sulfosuccinates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/34—Derivatives of acids of phosphorus
- C11D1/342—Phosphonates; Phosphinates or phosphonites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3472—Organic compounds containing sulfur additionally containing -COOH groups or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/365—Organic compounds containing phosphorus containing carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
- C11D2111/18—Glass; Plastics
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Detergent Compositions (AREA)
Abstract
1438417 Detergent compositions containing polycarboxylates PROCTOR & GAMBLE CO 8 Oct 1974 [9 Oct 1973] 43523/74 Heading C5D A detergent composition, especially suitable for cleaning glass and vitreous surfaces, comprises: (a) a surface active polycarboxylate of the general formula wherein X is an -SO 3 M or PO 3 M 2 radical; M is sodium, potassium, ammonium, monoethanolammonium or diethanolammonium; R 1 is a multivalent aliphatic hydrocarbon radical having from 2 to 12 carbon atoms, optionally containing a keto group; R 2 represents a C 1-20 alkyl, C 3-20 alkenyl, -(C 2 H 4 O) p H or group, wherein R 3 is C 1-16 alkyl, C 3-16 alkenyl, or C 8-14 alkylaryl, and p and q are each an integer from 2 to 15; and n is 1 to 7; m is 1 to 4 (and the R 2 radicals need not be identical when m is 2, 3 or 4); and the total m+n is 3 to 8, and (b) a metal compound yeilding in aqueous solution a metal ion selected from Al + + +, Zn + +, Sn + +, Cr + + +, Ni + +, Mn + + and Cu + + ; wherein the weight ratio of polycarboxylate of the general Formula (I) to metal ion is between 20,000 : 1 and 100 : 1; and wherein a 2 g./litre aqueous solution of said detergent composition has a pH of between 5 and 8À5. The metal salts may be (A) inorganic, e.g. sulphate, dichromate, fluorosilicate, chloride or phosphate, e.g. manganous ammonium phosphate; aluminium sulphate, aluminium potassium sulphate, zinc sulphate and stannous chloride being preferred; (B) organic, e.g. citrate, tartrate, acetate, malate, benzoate, salicylate, succinate, ethyl sulphate or phenolsulphonate. Optional ingredients are (C) non-ionic and/or anionic surfactants the weight ratio of (C) to polycarboxylate being between 3 : 1 and 1 : 3; (D) inorganic and/or organic builders the weight ratio of builder salt to polycarboxylate being between 2 : 1 and 1 : 20; (E) conventional additives including up to 15% of organic solvents such as C 2 -C 8 alkanols.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| LU68583A LU68583A1 (en) | 1973-10-09 | 1973-10-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1438417A true GB1438417A (en) | 1976-06-09 |
Family
ID=19727484
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB4352374A Expired GB1438417A (en) | 1973-10-09 | 1974-10-08 | Detergent composition |
Country Status (7)
| Country | Link |
|---|---|
| BE (1) | BE820862A (en) |
| DE (1) | DE2445710A1 (en) |
| FR (1) | FR2246630B1 (en) |
| GB (1) | GB1438417A (en) |
| IT (1) | IT1022690B (en) |
| LU (1) | LU68583A1 (en) |
| NL (1) | NL7413220A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004002994A2 (en) * | 2002-06-26 | 2004-01-08 | Rhodia Consumer Specialities Limited | Novel phosphonocarboxylic acid esters |
| CN113574156A (en) * | 2019-03-06 | 2021-10-29 | 埃科莱布美国股份有限公司 | Concentrated solid hard surface cleaner |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4069066A (en) * | 1976-11-10 | 1978-01-17 | The Procter & Gamble Company | Method and composition for cleaning polished surfaces |
| EP0256148A1 (en) * | 1986-08-12 | 1988-02-24 | Joh. A. Benckiser GmbH | Liquid, granulated or powdery detergent, in particular for dish-washing machines |
| EP0748864B1 (en) * | 1995-06-12 | 2001-11-28 | The Procter & Gamble Company | Cleaning composition and method for the cleaning of delicate surfaces |
-
1973
- 1973-10-09 LU LU68583A patent/LU68583A1/xx unknown
-
1974
- 1974-09-25 DE DE19742445710 patent/DE2445710A1/en active Pending
- 1974-10-08 FR FR7433824A patent/FR2246630B1/fr not_active Expired
- 1974-10-08 GB GB4352374A patent/GB1438417A/en not_active Expired
- 1974-10-08 IT IT28195/74A patent/IT1022690B/en active
- 1974-10-08 NL NL7413220A patent/NL7413220A/en unknown
- 1974-10-09 BE BE149353A patent/BE820862A/en unknown
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004002994A2 (en) * | 2002-06-26 | 2004-01-08 | Rhodia Consumer Specialities Limited | Novel phosphonocarboxylic acid esters |
| WO2004002994A3 (en) * | 2002-06-26 | 2004-04-08 | Rhodia Consumer Specialities L | Novel phosphonocarboxylic acid esters |
| CN113574156A (en) * | 2019-03-06 | 2021-10-29 | 埃科莱布美国股份有限公司 | Concentrated solid hard surface cleaner |
| CN113574156B (en) * | 2019-03-06 | 2023-07-14 | 埃科莱布美国股份有限公司 | Concentrated solid hard surface cleaner |
Also Published As
| Publication number | Publication date |
|---|---|
| BE820862A (en) | 1975-04-09 |
| DE2445710A1 (en) | 1975-04-10 |
| NL7413220A (en) | 1975-04-11 |
| IT1022690B (en) | 1978-04-20 |
| LU68583A1 (en) | 1975-06-16 |
| FR2246630A1 (en) | 1975-05-02 |
| FR2246630B1 (en) | 1978-06-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |