GB1437361A - Preparation of monosilane and hydrogen silane esters - Google Patents
Preparation of monosilane and hydrogen silane estersInfo
- Publication number
- GB1437361A GB1437361A GB2560673A GB2560673A GB1437361A GB 1437361 A GB1437361 A GB 1437361A GB 2560673 A GB2560673 A GB 2560673A GB 2560673 A GB2560673 A GB 2560673A GB 1437361 A GB1437361 A GB 1437361A
- Authority
- GB
- United Kingdom
- Prior art keywords
- monosilane
- carbonate
- acetylacetonate
- manganese
- hydrogen silane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 hydrogen silane esters Chemical class 0.000 title abstract 5
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 title abstract 3
- 239000001257 hydrogen Substances 0.000 title abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 title abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 2
- 229910052788 barium Inorganic materials 0.000 abstract 2
- 229910052792 caesium Inorganic materials 0.000 abstract 2
- 229910052791 calcium Inorganic materials 0.000 abstract 2
- 150000004820 halides Chemical class 0.000 abstract 2
- 229910052742 iron Inorganic materials 0.000 abstract 2
- 229910052744 lithium Inorganic materials 0.000 abstract 2
- 229910052749 magnesium Inorganic materials 0.000 abstract 2
- 229910052748 manganese Inorganic materials 0.000 abstract 2
- 239000011572 manganese Substances 0.000 abstract 2
- 229910052700 potassium Inorganic materials 0.000 abstract 2
- 229910052701 rubidium Inorganic materials 0.000 abstract 2
- 229910052708 sodium Inorganic materials 0.000 abstract 2
- 229910052712 strontium Inorganic materials 0.000 abstract 2
- HYZQBNDRDQEWAN-LNTINUHCSA-N (z)-4-hydroxypent-3-en-2-one;manganese(3+) Chemical compound [Mn+3].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O HYZQBNDRDQEWAN-LNTINUHCSA-N 0.000 abstract 1
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical compound C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 abstract 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 abstract 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052684 Cerium Inorganic materials 0.000 abstract 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 abstract 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 1
- BVMWIXWOIGJRGE-UHFFFAOYSA-N NP(O)=O Chemical compound NP(O)=O BVMWIXWOIGJRGE-UHFFFAOYSA-N 0.000 abstract 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 1
- 229910052776 Thorium Inorganic materials 0.000 abstract 1
- 229910052770 Uranium Inorganic materials 0.000 abstract 1
- 229910052768 actinide Inorganic materials 0.000 abstract 1
- 150000001255 actinides Chemical class 0.000 abstract 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 150000001413 amino acids Chemical class 0.000 abstract 1
- 229910052793 cadmium Inorganic materials 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 238000007323 disproportionation reaction Methods 0.000 abstract 1
- 235000003891 ferrous sulphate Nutrition 0.000 abstract 1
- 239000011790 ferrous sulphate Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- LZKLAOYSENRNKR-LNTINUHCSA-N iron;(z)-4-oxoniumylidenepent-2-en-2-olate Chemical compound [Fe].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O LZKLAOYSENRNKR-LNTINUHCSA-N 0.000 abstract 1
- 229910052747 lanthanoid Inorganic materials 0.000 abstract 1
- 150000002602 lanthanoids Chemical class 0.000 abstract 1
- 229910052746 lanthanum Inorganic materials 0.000 abstract 1
- 235000006748 manganese carbonate Nutrition 0.000 abstract 1
- 239000011656 manganese carbonate Substances 0.000 abstract 1
- 229940093474 manganese carbonate Drugs 0.000 abstract 1
- 229910000016 manganese(II) carbonate Inorganic materials 0.000 abstract 1
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910017464 nitrogen compound Inorganic materials 0.000 abstract 1
- 150000002897 organic nitrogen compounds Chemical class 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 1
- 239000010452 phosphate Substances 0.000 abstract 1
- 230000002269 spontaneous effect Effects 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/025—Silicon compounds without C-silicon linkages
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/04—Hydrides of silicon
- C01B33/043—Monosilane
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Silicon Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
1437361 Monosilane DYNAMIT NOBEL AG 29 May 1973 [30 May 1972] 25606/73 Heading CIA [Also in Division C3] Monosilane and hydrogen silane esters are made by disproportionation of hydrogen silane esters of the formula wherein R denotes alkyl and/or alkoxyalkyl, and x is 1, 2 or 3, into at least one of H 2 Si(OR) 2 , HSi(OR) 3 and Si(OK) 4 on the one hand, and at least one of SiH 4 , H 3 Si(OR) and H 2 Si(OR) 2 on the other, in the presence of a catalyst which is (a) iron, manganese or an element of Groups Ia, IIa, IIb, IIIa (including the Lanthanide and Actinide Series) or IIIb of the Periodic Table, in elemental or combined form (other than a halide or cyanide of a transition metal element, i.e. a metal having partly filled d off f shells in any of their commonly occurring oxidation states) or (b) an organic nitrogen compound other than those which undergo spontaneous decomposition. The catalyst may be used in quantities varying from 0À001 to 2% by weight. Preferred catalysts include metallic Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Zn, Cd, Al, La, Ce, Th, U, Fe or Mn; ferrous sulphate or an iron acetylacetonate, manganese carbonate or manganese acetylacetonate; an oxide, hydroxide, carbonate, bicarbonate, alcoholate, phosphate, halide, silicate or borate of Li, Na, K, Rb or Cs; an oxide, chloride, carbonate, acetate, alcoholate or acetylacetonate of Mg, Ca, Sr or Ba; and an amino acid, amine, carboxylic acid amide, phosphoric or phosphonic acid amide or heterocyclic nitrogen compound.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19722226265 DE2226265C3 (en) | 1972-05-30 | Process for the production of monosilane and lower silane esters |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1437361A true GB1437361A (en) | 1976-05-26 |
Family
ID=5846317
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2560673A Expired GB1437361A (en) | 1972-05-30 | 1973-05-29 | Preparation of monosilane and hydrogen silane esters |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS604195B2 (en) |
| BE (1) | BE800120A (en) |
| CH (1) | CH577520A5 (en) |
| DD (1) | DD106388A5 (en) |
| FR (1) | FR2186473B1 (en) |
| GB (1) | GB1437361A (en) |
| IT (1) | IT985222B (en) |
| SE (1) | SE410462B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0725535B2 (en) * | 1985-06-04 | 1995-03-22 | 三菱化学株式会社 | Method for producing monosilane |
| JPH0725534B2 (en) * | 1985-05-22 | 1995-03-22 | 三菱化学株式会社 | Manufacturing method of monosilane |
| JP2535525B2 (en) * | 1987-02-10 | 1996-09-18 | チッソ株式会社 | Production method of silane |
| JP2523123B2 (en) * | 1987-02-26 | 1996-08-07 | チッソ株式会社 | Silane gas manufacturing method |
| US5250490A (en) * | 1991-12-24 | 1993-10-05 | Union Carbide Chemicals & Plastics Technology Corporation | Noble metal supported on a base metal catalyst |
| JP4663079B2 (en) * | 2000-08-29 | 2011-03-30 | 日揮株式会社 | Method for producing silane from trialkoxysilane and method for producing trialkoxysilane from tetraalkoxysilane |
| US8163261B2 (en) * | 2005-04-05 | 2012-04-24 | Voltaix, Llc | System and method for making Si2H6 and higher silanes |
| JP5647620B2 (en) * | 2009-11-25 | 2015-01-07 | 昭和電工株式会社 | Method for producing monosilane and tetraalkoxysilane |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2735861A (en) * | 1956-02-21 | Disproportionation of alkoxy silane |
-
1973
- 1973-04-09 DD DD17004873A patent/DD106388A5/xx unknown
- 1973-05-25 CH CH755373A patent/CH577520A5/xx not_active IP Right Cessation
- 1973-05-28 BE BE131589A patent/BE800120A/en not_active IP Right Cessation
- 1973-05-29 FR FR7319570A patent/FR2186473B1/fr not_active Expired
- 1973-05-29 IT IT5026273A patent/IT985222B/en active
- 1973-05-29 SE SE7307600A patent/SE410462B/en unknown
- 1973-05-29 GB GB2560673A patent/GB1437361A/en not_active Expired
- 1973-05-30 JP JP48060753A patent/JPS604195B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS4941321A (en) | 1974-04-18 |
| FR2186473A1 (en) | 1974-01-11 |
| DD106388A5 (en) | 1974-06-12 |
| BE800120A (en) | 1973-09-17 |
| IT985222B (en) | 1974-11-30 |
| SE410462B (en) | 1979-10-15 |
| CH577520A5 (en) | 1976-07-15 |
| JPS604195B2 (en) | 1985-02-01 |
| DE2226265B2 (en) | 1976-11-04 |
| FR2186473B1 (en) | 1978-02-17 |
| DE2226265A1 (en) | 1973-12-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PE20 | Patent expired after termination of 20 years |
Effective date: 19930528 |