GB1433524A - Water-repellent and oil-repellent compositions based on fluorine compounds - Google Patents

Water-repellent and oil-repellent compositions based on fluorine compounds

Info

Publication number
GB1433524A
GB1433524A GB1146673A GB1146673A GB1433524A GB 1433524 A GB1433524 A GB 1433524A GB 1146673 A GB1146673 A GB 1146673A GB 1146673 A GB1146673 A GB 1146673A GB 1433524 A GB1433524 A GB 1433524A
Authority
GB
United Kingdom
Prior art keywords
monomers
per cent
alkyl
repellent
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1146673A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Produits Chimiques Ugine Kuhlmann
Ugine Kuhlmann SA
Original Assignee
Produits Chimiques Ugine Kuhlmann
Ugine Kuhlmann SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Produits Chimiques Ugine Kuhlmann, Ugine Kuhlmann SA filed Critical Produits Chimiques Ugine Kuhlmann
Publication of GB1433524A publication Critical patent/GB1433524A/en
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • D06M15/277—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F28/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
    • C08L33/16—Homopolymers or copolymers of esters containing halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L41/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a bond to sulfur or by a heterocyclic ring containing sulfur; Compositions of derivatives of such polymers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • D06M15/3335—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol fluorinated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)
  • Coating Of Shaped Articles Made Of Macromolecular Substances (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Paper (AREA)
  • Laminated Bodies (AREA)

Abstract

1433524 Polymer compositions for providing protective coatings PRODUITS CHIMIQUES UGINE KUHLMANN 9 March 1973 [10 March 1972] 11466/73 Heading C3P [Also in Divisions B2 and D1] A mixture for rendering substrates oil and water repellent comprises: (A) an aqueous dispersion of a copolymer containing in interpolymerized form (1) 30-99 wt. per cent of one or more monomers of the formula in which Rf is a C 1-20 perfluorocarbon chain (straight or branched); a is an integer of 2-20; R is H, C 1-10 alkyl, C 5-12 cycloalkyl, C 2-4 hydroxyalkyl, or aryl optionally substituted with a C 1-6 alkyl group; R<SP>1</SP>, R<SP>11</SP>, X and X<SP>1</SP> may be the same or different and represent H, or C 1-4 alkyl, b is an integer of 1-4; and Y represents the residue of an alkene monocarboxylic acid or dicarboxylic acid or monoalkyl ester thereof; (2) up to 70 wt, per cent of one or more non-perfluoro group containing ethylenic monomers; and (3) up to 10 wt. per cent of one or more ethylenic monomers containing at least one reactive group; and (B) an aqueous dispersion of a copolymer containing in interpolymerized form: (1) 1-70 wt. per cent of one or more monomers of the above formula in (A) (1); (2) 30-99 wt. per cent of one or more monomers as in (A) (2); and (3) 0 to 10 wt. per cent of one or more monomers as in (A) (3). Non perfluoro group containing monomers (A) (2) and (B) (2) may be virtually any ethylenic monomer including vinyl, vinylidene, allyl, and diene compounds, an exhaustive list of which is given. Monomers (A) (3) and (B) (3) containing reactive groups are those containing such groups as will produce cross-links either between the two polymers or one or both of them and the substrate. Suitable reactive groups are -OH, -NH 2 , -NH-alkyl, -COOCH 3 , -SO 3 H, Again, an exhaustive list is given. In the examples the perfluoro monomers used are perfluoroalkyl sulphonamido alkyl acrylates in which the perfluoro group is C 8 F 17 or C 6 F 13 . Substrates which may be rendered oil- and water-repellent are woven and non-woven articles based on cellulose or regenerated cellulose, cotton, cellulose acetate, wool, silk, polyamide, polyester, polyolefin, polyurethane and polyacrylonitrile fibres. Other substrates are paper, cardboard, leather, plastics, glass, wood, metals (Al, Fe, steel, Cu, Mg, Cr, Zn or Sn), porcelain and concrete.
GB1146673A 1972-03-10 1973-03-09 Water-repellent and oil-repellent compositions based on fluorine compounds Expired GB1433524A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7208366A FR2175332A5 (en) 1972-03-10 1972-03-10

Publications (1)

Publication Number Publication Date
GB1433524A true GB1433524A (en) 1976-04-28

Family

ID=9094979

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1146673A Expired GB1433524A (en) 1972-03-10 1973-03-09 Water-repellent and oil-repellent compositions based on fluorine compounds

Country Status (9)

Country Link
JP (1) JPS5625945B2 (en)
BE (1) BE796578A (en)
CA (1) CA1012668A (en)
CH (2) CH571100B5 (en)
DE (1) DE2311784C2 (en)
FR (1) FR2175332A5 (en)
GB (1) GB1433524A (en)
IT (1) IT984409B (en)
NL (1) NL173860C (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4366300A (en) 1980-06-03 1982-12-28 Pcuk - Produits Chimiques Ugine Kuhlmann Composition and process for the protection of materials against spots or stains
EP1201815A1 (en) * 2000-10-31 2002-05-02 Asahi Glass Co., Ltd. Water repellent composition
US6774176B1 (en) 1998-11-13 2004-08-10 E. I. Du Pont De Nemours And Company Polymers fluorinated by polymerization in mini-emulsion
CN113737525A (en) * 2021-09-24 2021-12-03 中国计量大学 Preparation method of novel combined capillary force oil-water separation non-woven fabric

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5755742B2 (en) * 1972-05-16 1982-11-26
US4043923A (en) * 1974-02-26 1977-08-23 Minnesota Mining And Manufacturing Company Textile treatment composition
DE3428023A1 (en) * 1984-07-30 1986-02-06 Werner & Mertz Gmbh IMPREGNATION SPRAY FOR LEATHER AND TEXTILES AND THEIR USE
DE4201603A1 (en) * 1992-01-22 1993-07-29 Bayer Ag MIXTURES OF FLUORINE COPOLYMERISATE
FR2713649B1 (en) * 1993-12-15 1996-08-02 Oreal Film-forming composition containing a perfluorinated alkyl copolymer, usable as nail varnish.
US6113925A (en) * 1993-12-15 2000-09-05 L'oreal Method of forming a film using a composition containing a fluoroalkyl copolymer
FR2722791B1 (en) * 1994-07-22 1996-09-06 Atochem Elf Sa PROCESS FOR THE MANUFACTURE OF AQUEOUS EMULSIONS OF FLUORINATED COPOLYMERS
DE19631735A1 (en) * 1996-08-06 1998-02-12 Calwer Decken & Tuchfab Ag Finishing textile goods made of high-grade natural fibres
FR2762509B1 (en) 1997-04-28 2003-03-07 Oreal COSMETIC OR DERMATOLOGICAL COMPOSITION COMPRISING A FILM-FORMING POLYMER, METHOD FOR MAKING-UP AND NON-THERAPEUTIC TREATMENT
EP2045276A1 (en) * 2007-10-05 2009-04-08 E.I. Du Pont De Nemours And Company Fluoropolymer

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE635437A (en) * 1961-05-03

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4366300A (en) 1980-06-03 1982-12-28 Pcuk - Produits Chimiques Ugine Kuhlmann Composition and process for the protection of materials against spots or stains
US6774176B1 (en) 1998-11-13 2004-08-10 E. I. Du Pont De Nemours And Company Polymers fluorinated by polymerization in mini-emulsion
EP1201815A1 (en) * 2000-10-31 2002-05-02 Asahi Glass Co., Ltd. Water repellent composition
US6590035B2 (en) 2000-10-31 2003-07-08 Asahi Glass Company, Limited Water repellent composition
CN113737525A (en) * 2021-09-24 2021-12-03 中国计量大学 Preparation method of novel combined capillary force oil-water separation non-woven fabric

Also Published As

Publication number Publication date
FR2175332A5 (en) 1973-10-19
IT984409B (en) 1974-11-20
DE2311784A1 (en) 1973-09-13
BE796578A (en) 1973-09-10
JPS48102788A (en) 1973-12-24
CH571100B5 (en) 1975-12-31
JPS5625945B2 (en) 1981-06-16
CA1012668A (en) 1977-06-21
NL173860C (en) 1984-03-16
NL173860B (en) 1983-10-17
CH340673A4 (en) 1975-05-15
DE2311784C2 (en) 1984-08-02
NL7303244A (en) 1973-09-12

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Legal Events

Date Code Title Description
PS Patent sealed
PE20 Patent expired after termination of 20 years

Effective date: 19930308