GB1430602A - Processes for the treatment of waste liquids - Google Patents
Processes for the treatment of waste liquidsInfo
- Publication number
- GB1430602A GB1430602A GB3507173A GB3507173A GB1430602A GB 1430602 A GB1430602 A GB 1430602A GB 3507173 A GB3507173 A GB 3507173A GB 3507173 A GB3507173 A GB 3507173A GB 1430602 A GB1430602 A GB 1430602A
- Authority
- GB
- United Kingdom
- Prior art keywords
- gas
- effluent
- stage
- liquor
- sulphate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/52—Hydrogen sulfide
- B01D53/523—Mixtures of hydrogen sulfide and sulfur oxides
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treating Waste Gases (AREA)
- Industrial Gases (AREA)
Abstract
1430602 Wet air oxidation NIPPON STEEL CORP 23 July 1973 [22 July 1972 (2) 22 Nov 1972] 35071/73 Heading C1C [Also in Divisions C4-C5] Removal of H 2 S, NH 3 and, where present, HCN, from gases is effected by successively contacting the gas with (i) (optional) an aqueous solution or dispersion containing sulphur and/or polysulphides at pH > 7 to absorb HCN; (ii) an aqueous solution containing a redox catalyst at pH # 7 to absorb H 2 S; and (iii) an aqueous solution containing sulphate ions to absorb NH 3 and precipitate ammonium sulphate. Before recycling, the spent liquor from (ii) is regenerated by contact with an oxygen-containing gas (e.g. air) and its pH restored by drawing off a part thereof and replacing it with water, with addition of alkali if necessary. The drawn-off liquid is optionally filtered to remove sulphur (which may be fed to stage (i)), and is fed, optionally together with liquor similarly drawn off from absorbing solution circulating in stage (i), to a wet air oxidation stage (vide infra) from the effluent of which ammonium or calcium sulphate may be recovered; alternatively the effluent is fed to stage (iii). The gas may be coke oven gas, petroleum decomposition gas, petroleum purification gas, coal decomposition gas, natural gas, or gas from organic waste treatment. The redox catalyst may be iron oxide, manganese oxide, picric acid or a derivative thereof, or a quinone, naphthoquinone or anthraquinone derivative. Wet air oxidation of the above effluent, which contains one or more of sulphur, sulphites, thiosulphates, thiocyanates and polysulphides, is effected by contacting it with an oxygencontaining gas (e.g. air or oxygen, preferably in excess) at a temperature above 150‹ C. and at a pressure (e.g. 4À7-120 atm.) greater than the saturated vapour pressure of water at the temperature used. The effluent may be initially diluted with water and pre-heated by heatexchange with the oxidized liquor. Alkali (e.g. lime, quicklime, CaCO 3 , NaOH, Na 2 CO 3 , KOH, K 2 CO 3 , NH 3 , NH 4 OH) may be added before or after the oxidation so that the pH of the oxidized sulphate-containing liquor is above 7.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP47073553A JPS519761B2 (en) | 1972-07-22 | 1972-07-22 | |
JP47073552A JPS513481B2 (en) | 1972-07-22 | 1972-07-22 | |
JP47117522A JPS4975462A (en) | 1972-11-22 | 1972-11-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1430602A true GB1430602A (en) | 1976-03-31 |
Family
ID=27301248
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3507173A Expired GB1430602A (en) | 1972-07-22 | 1973-07-23 | Processes for the treatment of waste liquids |
Country Status (6)
Country | Link |
---|---|
CA (1) | CA1008638A (en) |
DE (1) | DE2337364C3 (en) |
FR (1) | FR2199477B1 (en) |
GB (1) | GB1430602A (en) |
IT (1) | IT998273B (en) |
NL (1) | NL169416C (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1119519A1 (en) * | 1998-07-21 | 2001-08-01 | Crystatech, Inc. | Improved regeneration method for process which removes hydrogen sulfide from gas streams |
CN111983134A (en) * | 2019-05-24 | 2020-11-24 | 中国石油天然气股份有限公司 | Method for measuring contents of hydrogen sulfide and hydrogen polysulfide in liquid sulfur |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4367212A (en) * | 1979-05-03 | 1983-01-04 | Fmc Corporation | Control of thiosulfate in wet desulfurization process solutions |
US4455236A (en) * | 1982-12-20 | 1984-06-19 | General Electric Company | Method for removing hydrogen sulfide from aqueous streams |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE457524A (en) * | ||||
US2044167A (en) * | 1931-11-11 | 1936-06-16 | Firm Of Bayerische Stickstoff | Process of producing ammonium sulphate |
DE923156C (en) * | 1943-07-06 | 1955-02-03 | Kalman Von Dr Szombathy | Removal of hydrogen sulphide, ammonia and hydrogen cyanide from gases and simultaneous processing of the ammonia water and recovery of ammonium sulphate or sulfur |
DE909138C (en) * | 1950-09-10 | 1954-04-15 | Bergwerksverband Zur Verwertun | Process for removing hydrogen cyanide, ammonia and hydrogen sulphide from coke oven gases with the production of ammonium sulphate |
US2898190A (en) * | 1951-11-22 | 1959-08-04 | Grosskinsky Otto | Method of producing ammonium sulfate and ammonium thiosulfate |
DE1005047B (en) * | 1953-06-11 | 1957-03-28 | Dr Phil Kalman Von Szombathy | Process for the dehydrogenation or oxidation of inorganic and organic sulfur compounds |
FR1588620A (en) * | 1967-11-03 | 1970-04-17 |
-
1973
- 1973-07-20 CA CA176,924A patent/CA1008638A/en not_active Expired
- 1973-07-20 FR FR7326810A patent/FR2199477B1/fr not_active Expired
- 1973-07-23 DE DE19732337364 patent/DE2337364C3/en not_active Expired
- 1973-07-23 NL NL7310225A patent/NL169416C/en not_active IP Right Cessation
- 1973-07-23 GB GB3507173A patent/GB1430602A/en not_active Expired
- 1973-07-23 IT IT2691073A patent/IT998273B/en active
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1119519A1 (en) * | 1998-07-21 | 2001-08-01 | Crystatech, Inc. | Improved regeneration method for process which removes hydrogen sulfide from gas streams |
EP1119519A4 (en) * | 1998-07-21 | 2004-12-29 | Crystatech Inc | Improved regeneration method for process which removes hydrogen sulfide from gas streams |
CN111983134A (en) * | 2019-05-24 | 2020-11-24 | 中国石油天然气股份有限公司 | Method for measuring contents of hydrogen sulfide and hydrogen polysulfide in liquid sulfur |
CN111983134B (en) * | 2019-05-24 | 2022-08-05 | 中国石油天然气股份有限公司 | Method for measuring contents of hydrogen sulfide and hydrogen polysulfide in liquid sulfur |
Also Published As
Publication number | Publication date |
---|---|
DE2337364A1 (en) | 1974-02-14 |
NL169416C (en) | 1982-07-16 |
IT998273B (en) | 1976-01-20 |
DE2337364C3 (en) | 1985-11-21 |
NL169416B (en) | 1982-02-16 |
CA1008638A (en) | 1977-04-19 |
NL7310225A (en) | 1974-01-24 |
FR2199477A1 (en) | 1974-04-12 |
DE2337364B2 (en) | 1978-06-01 |
FR2199477B1 (en) | 1977-12-23 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PE20 | Patent expired after termination of 20 years |
Effective date: 19930722 |