GB1425770A - Use of chlorinated bis-phenylethylnyl- anthracenes as fluorescers in chemiluminescent systems - Google Patents
Use of chlorinated bis-phenylethylnyl- anthracenes as fluorescers in chemiluminescent systemsInfo
- Publication number
- GB1425770A GB1425770A GB2142173A GB2142173A GB1425770A GB 1425770 A GB1425770 A GB 1425770A GB 2142173 A GB2142173 A GB 2142173A GB 2142173 A GB2142173 A GB 2142173A GB 1425770 A GB1425770 A GB 1425770A
- Authority
- GB
- United Kingdom
- Prior art keywords
- bis
- phenylethynyl
- anthracene
- hydroperoxide
- dichloro
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
- C09K11/07—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials having chemically interreactive components, e.g. reactive chemiluminescent compositions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2603/00—Systems containing at least three condensed rings
- C07C2603/02—Ortho- or ortho- and peri-condensed systems
- C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
- C07C2603/22—Ortho- or ortho- and peri-condensed systems containing three rings containing only six-membered rings
- C07C2603/24—Anthracenes; Hydrogenated anthracenes
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Luminescent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1425770 Chemiluminescence AMERICAN CYANAMID CO 4 May 1973 [12 June 1972] 21421/73 Heading C4S Chemiluminescent reactants which react with a hydroperoxide to give chemiluminescent light comprises (1) an oxalic acid ester of formula R 1 OOC-COOR 2 in which R 1 and R 2 each represents an aliphatic or an aromatic group; (2) a fluorescer comprising a bis-(phenylethynyl)- anthracene selected from 1,5-dichloro-9,10- bis-(phenylethynyl)anthracene, 1,8-dichloro- 9,10 - bis - (phenylethynyl)anthracene, 2,3- dichloro - 9,10 - bis - (phenylethynyl)anthracene, 1 - chloro - 9,10 - bis - (phenylethynyl)anthracene, 2 - chloro - 9,10 - bis - (phenylethynyl)- anthracene and 2-methyl-9,10-bis-(phenylethynyl)anthracene and optionally (3) a diluent. R 1 and R 2 may be, for example, alkyl groups which are optionally substituted, e.g. hexafluoro - 2 - propyl, alkanyl groups or optionally substituted aryl or heterocyclic groups. The diluent may be omitted when the oxalic acid is a solvent for the fluorescer and the hydroperoxide compound. Chemiluminescent light is obtained by mixing the above components with hydroperoxide or hydroperoxide producing compound, e.g. hydrogen peroxide, which is preferred, urea peroxide, sodium pyrophosphate peroxide, histidine peroxide or sodium perborate. Suitable diluents, when used, are esters, ether-esters, cyclic and acyclic ethers, hydrocarbons and halohydrocarbons. If desired additional fluorescers may be added to the compositions
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US26188872A | 1972-06-12 | 1972-06-12 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1425770A true GB1425770A (en) | 1976-02-18 |
Family
ID=22995312
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2142173A Expired GB1425770A (en) | 1972-06-12 | 1973-05-04 | Use of chlorinated bis-phenylethylnyl- anthracenes as fluorescers in chemiluminescent systems |
Country Status (13)
Country | Link |
---|---|
JP (1) | JPS5347798B2 (en) |
AR (1) | AR197335A1 (en) |
AU (1) | AU475513B2 (en) |
BE (1) | BE800790A (en) |
BR (1) | BR7304371D0 (en) |
CA (1) | CA1015555A (en) |
DE (1) | DE2329779C3 (en) |
FR (1) | FR2187871B1 (en) |
GB (1) | GB1425770A (en) |
HK (1) | HK65179A (en) |
IT (1) | IT985420B (en) |
NL (1) | NL176688C (en) |
SE (1) | SE386908B (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0096749A1 (en) * | 1982-06-16 | 1983-12-28 | American Cyanamid Company | Enhanced aqueous chemiluminescent systems |
EP0107008A1 (en) * | 1982-10-25 | 1984-05-02 | American Cyanamid Company | 9,10-bis(phenylethynyl)-anthracenes |
CN102781904A (en) * | 2009-10-13 | 2012-11-14 | 克禄美科技股份有限公司 | Chemical light producing formulations and devices containing branched oxalate esters |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GR72790B (en) * | 1977-12-19 | 1983-12-05 | American Cyanamid Co | |
US4401585A (en) * | 1982-01-21 | 1983-08-30 | American Cyanamid Company | Bis(p-alkylphenylethynyl)anthracene |
US4678608A (en) * | 1985-04-15 | 1987-07-07 | American Cyanamid Company | Chemiluminescent composition |
JP4726237B2 (en) * | 2004-04-27 | 2011-07-20 | 株式会社ルミカ | Chemiluminescent composition |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL6712108A (en) * | 1965-09-08 | 1968-03-08 | ||
NL152290B (en) * | 1965-09-08 | 1977-02-15 | American Cyanamid Co | PROCESS FOR PREPARING CHEMILUMINESCENT MIXTURES. |
BE686610A (en) * | 1966-09-08 | 1967-03-08 |
-
1973
- 1973-04-30 CA CA169,875A patent/CA1015555A/en not_active Expired
- 1973-05-04 GB GB2142173A patent/GB1425770A/en not_active Expired
- 1973-05-04 AU AU55269/73A patent/AU475513B2/en not_active Expired
- 1973-05-17 AR AR248075A patent/AR197335A1/en active
- 1973-06-08 SE SE7308192A patent/SE386908B/en unknown
- 1973-06-11 IT IT50692/73A patent/IT985420B/en active
- 1973-06-11 JP JP6488973A patent/JPS5347798B2/ja not_active Expired
- 1973-06-12 BE BE132162A patent/BE800790A/en not_active IP Right Cessation
- 1973-06-12 FR FR7321274A patent/FR2187871B1/fr not_active Expired
- 1973-06-12 DE DE2329779A patent/DE2329779C3/en not_active Expired
- 1973-06-12 BR BR4371/73A patent/BR7304371D0/en unknown
- 1973-06-12 NL NLAANVRAGE7308133,A patent/NL176688C/en active Search and Examination
-
1979
- 1979-09-13 HK HK651/79A patent/HK65179A/en unknown
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0096749A1 (en) * | 1982-06-16 | 1983-12-28 | American Cyanamid Company | Enhanced aqueous chemiluminescent systems |
EP0107008A1 (en) * | 1982-10-25 | 1984-05-02 | American Cyanamid Company | 9,10-bis(phenylethynyl)-anthracenes |
CN102781904A (en) * | 2009-10-13 | 2012-11-14 | 克禄美科技股份有限公司 | Chemical light producing formulations and devices containing branched oxalate esters |
Also Published As
Publication number | Publication date |
---|---|
BE800790A (en) | 1973-12-12 |
IT985420B (en) | 1974-11-30 |
NL7308133A (en) | 1973-12-14 |
AR197335A1 (en) | 1974-03-29 |
DE2329779C3 (en) | 1982-02-18 |
SE386908B (en) | 1976-08-23 |
AU5526973A (en) | 1974-11-07 |
JPS4951185A (en) | 1974-05-17 |
AU475513B2 (en) | 1976-08-26 |
NL176688C (en) | 1985-05-17 |
FR2187871B1 (en) | 1977-12-30 |
HK65179A (en) | 1979-09-21 |
BR7304371D0 (en) | 1974-09-05 |
DE2329779A1 (en) | 1974-01-03 |
FR2187871A1 (en) | 1974-01-18 |
DE2329779B2 (en) | 1981-03-12 |
JPS5347798B2 (en) | 1978-12-23 |
CA1015555A (en) | 1977-08-16 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PE20 | Patent expired after termination of 20 years |
Effective date: 19930503 |