GB1405652A - Process for the preparation of amines suitable for incorporation as additives into lubricatns and fuels - Google Patents

Process for the preparation of amines suitable for incorporation as additives into lubricatns and fuels

Info

Publication number
GB1405652A
GB1405652A GB4329472A GB4329472A GB1405652A GB 1405652 A GB1405652 A GB 1405652A GB 4329472 A GB4329472 A GB 4329472A GB 4329472 A GB4329472 A GB 4329472A GB 1405652 A GB1405652 A GB 1405652A
Authority
GB
United Kingdom
Prior art keywords
polyamine
sept
carbonates
metal compound
hydroxides
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4329472A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of GB1405652A publication Critical patent/GB1405652A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/22—Organic compounds containing nitrogen
    • C10L1/234—Macromolecular compounds
    • C10L1/238—Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/2383—Polyamines or polyimines, or derivatives thereof (poly)amines and imines; derivatives thereof (substituted by a macromolecular group containing 30C)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/06—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of halogen atoms
    • C07C209/08—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of halogen atoms with formation of amino groups bound to acyclic carbon atoms or to carbon atoms of rings other than six-membered aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/52—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of 30 or more atoms
    • C10M133/54—Amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/221—Six-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/225—Heterocyclic nitrogen compounds the rings containing both nitrogen and oxygen
    • C10M2215/226—Morpholines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/26—Amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/30—Heterocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/042—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds between the nitrogen-containing monomer and an aldehyde or ketone
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/043—Mannich bases
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/04—Macromolecular compounds from nitrogen-containing monomers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/046—Polyamines, i.e. macromoleculars obtained by condensation of more than eleven amine monomers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/06—Macromolecular compounds obtained by functionalisation op polymers with a nitrogen containing compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00—Specific manufacturing methods for lubricant compositions
    • C10N2070/02—Concentrating of additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Lubricants (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

1405652 Polyolefin derivatives SHELL ININTERNATIONALE RESEARCH MAATSCHAPPIJ NV 19 Sept 1972 [21 Sept 1971] 43294/72 Heading C3P [Also in Division C5] Polyamines suitable for use as lubricant and fuel additives are prepared by reacting a halogen-substituted polyolefin of molecular weight at least 500 and a polyamine, with liberation of hydrogen halide, in the presence of successively a basic alkali metal compound and a basic alkaline earth metal compound, and removing solid constituents from the resulting mixture. The polymer may be a chlorinated polyethylene, polypropylene, polybutene or ethylene/propylene copolymer. The polyamine may be an ethylenediamine, propylenediamine, butylenediamine, N,N-dimethylpropylenediamine, diethylenetriamine, triethylenetetramine or tetraethylenepentamine. Specified metal compounds are sodium, potassium and lithium hydroxides and carbonates, and calcium, strontium and barium oxides, hydroxides and carbonates. Solids may be removed by filtration, optionally after adding a C 1-3 alkanol. In examples chlorinated polyisobutylene is reacted with (I) tetraethylene pentamine and (III) N,N-dimethyl propylene diamine in the presence of sodium carbonate with subsequent addition of calcium hydroxide, and the products diluted with heptane and methanol and filtered.
GB4329472A 1971-09-21 1972-09-19 Process for the preparation of amines suitable for incorporation as additives into lubricatns and fuels Expired GB1405652A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NLAANVRAGE7112993,A NL176177C (en) 1971-09-21 1971-09-21 PROCESS FOR THE PREPARATION OF AMINES SUITABLE AS ADDITIVE FOR LUBRICANTS AND FUELS.

Publications (1)

Publication Number Publication Date
GB1405652A true GB1405652A (en) 1975-09-10

Family

ID=19814077

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4329472A Expired GB1405652A (en) 1971-09-21 1972-09-19 Process for the preparation of amines suitable for incorporation as additives into lubricatns and fuels

Country Status (7)

Country Link
JP (1) JPS5735178B2 (en)
CA (1) CA1003442A (en)
DE (1) DE2245918C2 (en)
FR (1) FR2154120A5 (en)
GB (1) GB1405652A (en)
IT (1) IT967631B (en)
NL (1) NL176177C (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5350429A (en) * 1992-03-19 1994-09-27 Basf Aktiengesellschaft Diaminoalkanes, their preparation and fuels and lubricants containing the diaminoalkanes
EP0639589A1 (en) * 1993-08-19 1995-02-22 Ferro Corporation Process for the production of fuel additives from chlorinated polybutenes
US5437695A (en) * 1992-04-25 1995-08-01 Basf Aktiengesellschaft Fuels and lubricants containing n-alkylcarboxamides
US5492641A (en) * 1992-05-04 1996-02-20 Basf Aktiengesellschaft β-aminonitriles and N-alkyl-1,3-propylenediamines and their use as fuel additives and lubricant additives
US6140541A (en) * 1996-05-20 2000-10-31 Basf Aktiengesellschaft Process for preparing polyalkene amines
US6909018B1 (en) 1996-05-20 2005-06-21 Basf Aktiengesellschaft Preparation of polyalkeneamines
CN102976952A (en) * 2012-12-01 2013-03-20 张家港市大伟助剂有限公司 Preparation method of octyl diethylenetriamine

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5146061A (en) * 1974-10-18 1976-04-20 Hitachi Ltd KOTAISUITSUCHINGUSOSHINO GOTENKOBOSHIKAIRO
US6299655B1 (en) * 1985-03-14 2001-10-09 The Lubrizol Corporation Diesel fuel compositions
DE3611230A1 (en) * 1986-04-04 1987-10-08 Basf Ag POLYBUTYL AND POLYISOBUTYLAMINE, METHOD FOR THE PRODUCTION THEREOF AND THE FUEL AND LUBRICANT COMPOSITIONS CONTAINING THE SAME
US5225092A (en) * 1990-02-01 1993-07-06 Exxon Chemical Patents Inc. Ethylene alpha-olefin polymer substituted amine dispersant additives
DE4030164A1 (en) 1990-09-24 1992-03-26 Basf Ag FUELS FOR COMBUSTION ENGINES AND LUBRICANTS CONTAINING HIGHLY MOLECULAR AMINO ALCOHOLS
DE4309271A1 (en) * 1993-03-23 1994-09-29 Basf Ag Fuel additives, processes for their production and fuels for gasoline engines containing the additives
DE4313088A1 (en) * 1993-04-22 1994-10-27 Basf Ag Poly-1-n-alkeneamines and fuel and lubricant compositions containing them

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL145565B (en) * 1965-01-28 1975-04-15 Shell Int Research PROCESS FOR PREPARING A LUBRICANT COMPOSITION.
US3574576A (en) * 1965-08-23 1971-04-13 Chevron Res Distillate fuel compositions having a hydrocarbon substituted alkylene polyamine
NL169595C (en) * 1970-05-21 1982-08-02 Shell Int Research PROCESS FOR PREPARING AMINS AND LUBRICATING OILS AND LIQUID ENGINE FUELS CONTAINING THESE.

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5350429A (en) * 1992-03-19 1994-09-27 Basf Aktiengesellschaft Diaminoalkanes, their preparation and fuels and lubricants containing the diaminoalkanes
US5437695A (en) * 1992-04-25 1995-08-01 Basf Aktiengesellschaft Fuels and lubricants containing n-alkylcarboxamides
US5492641A (en) * 1992-05-04 1996-02-20 Basf Aktiengesellschaft β-aminonitriles and N-alkyl-1,3-propylenediamines and their use as fuel additives and lubricant additives
EP0639589A1 (en) * 1993-08-19 1995-02-22 Ferro Corporation Process for the production of fuel additives from chlorinated polybutenes
US6140541A (en) * 1996-05-20 2000-10-31 Basf Aktiengesellschaft Process for preparing polyalkene amines
US6909018B1 (en) 1996-05-20 2005-06-21 Basf Aktiengesellschaft Preparation of polyalkeneamines
CN102976952A (en) * 2012-12-01 2013-03-20 张家港市大伟助剂有限公司 Preparation method of octyl diethylenetriamine

Also Published As

Publication number Publication date
FR2154120A5 (en) 1973-05-04
JPS4836107A (en) 1973-05-28
NL176177C (en) 1985-03-01
IT967631B (en) 1974-03-11
NL7112993A (en) 1973-03-23
JPS5735178B2 (en) 1982-07-27
DE2245918C2 (en) 1983-09-15
CA1003442A (en) 1977-01-11
DE2245918A1 (en) 1973-03-22

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Legal Events

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PS Patent sealed
PE20 Patent expired after termination of 20 years