GB1398078A - Reducing gas - Google Patents

Reducing gas

Info

Publication number
GB1398078A
GB1398078A GB4622871A GB4622871A GB1398078A GB 1398078 A GB1398078 A GB 1398078A GB 4622871 A GB4622871 A GB 4622871A GB 4622871 A GB4622871 A GB 4622871A GB 1398078 A GB1398078 A GB 1398078A
Authority
GB
United Kingdom
Prior art keywords
gas
steam
bed
reformer
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4622871A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB4622871A priority Critical patent/GB1398078A/en
Priority to NO3513/72A priority patent/NO133899C/no
Priority to FR7235222A priority patent/FR2156046B3/fr
Priority to BE789681D priority patent/BE789681A/en
Priority to IT7230069A priority patent/IT968603B/en
Priority to NL7213485A priority patent/NL7213485A/xx
Priority to DE19722248913 priority patent/DE2248913A1/en
Priority to JP7299490A priority patent/JPS4845485A/ja
Publication of GB1398078A publication Critical patent/GB1398078A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/36—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Multi-step processes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

1398078 Reducing gas IMPERIAL CHEMICAL INDUSTRIES Ltd 25 Sept 1972 [5 Oct 1971] 46228/71 Heading C5E Reducing gas is made by reforming a hydrocarbon feedstock with an excess of steam in an externally heated catalyst bed, cooling the resulting reforming gas, condensing and removing at least a portion of the unreacted steam, reheating the dried gas to 750-1100‹ C. and reacting carbon dioxide and unreacted steam contained in the gas with hydrocarbon contained therein or added thereto. Suitable hydrocarbon feedstocks are methane, refinery off-gas, ethane, propane, butane and naphthas boiling up to 350‹C. which should first be hydrodesulphurized with a bed of nickel molybdate-on-alumina catalyst and with a bed of zinc oxide-sulphide adsorbent. The reforming can be carried out with a refractory-supported nickelzirconia catalyst at up to 50 atmospheres using a steam-carbon ratio of 1À35 to 5. The dried reformer gas can be reheated (a) within a bed of catalyst effective for the reaction of hydrocarbon with steam or carbon dioxide, or (b) by partial combustion of hydrocarbons either present in the reformer gas or added as methane, naphtha or fuel oil. The reheated, dried reducing gas can be used in blast furnaces, shaft furnaces, pellet reduction furnaces and fluidized bed reduction furnaces to reduce metal ores, e.g. to iron; the used gas can be recycled to the reforming stage and the hot reduced ore charge can be used to reheat the dried reformer gas. As shown desulphurized natural gas is mixed at 14 with steam from a boiler 10 and the mixture is preheated at 16 by flue gases and passed through tubular catalyst beds 18 in a radiant furnace 20 fuelled by natural gas. The reformer gas, e.g. at 850‹ C., is cooled in an indirect gas/ gas heat exchanger 22, then in a boiler 24 and then in an air cooled condenser 26 (alternatively the final cooling at 26 can be by direct contact with water). The condensed water is separated from the reformer gas at 28 which is then reheated at 22, after the addition of more natural gas at 30, and finally in the tubular catalytic beds 32 to a final temperature of 950-1000‹ C.
GB4622871A 1971-10-05 1971-10-05 Reducing gas Expired GB1398078A (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
GB4622871A GB1398078A (en) 1971-10-05 1971-10-05 Reducing gas
NO3513/72A NO133899C (en) 1971-10-05 1972-10-02
FR7235222A FR2156046B3 (en) 1971-10-05 1972-10-04
BE789681D BE789681A (en) 1971-10-05 1972-10-04 REDUCING GAS
IT7230069A IT968603B (en) 1971-10-05 1972-10-04 REDUCING GAS AND PROCESS FOR ITS PRODUCTION
NL7213485A NL7213485A (en) 1971-10-05 1972-10-05
DE19722248913 DE2248913A1 (en) 1971-10-05 1972-10-05 PROCESS FOR PRODUCING A REDUCING GAS AND USING IT
JP7299490A JPS4845485A (en) 1971-10-05 1972-10-05

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB4622871A GB1398078A (en) 1971-10-05 1971-10-05 Reducing gas

Publications (1)

Publication Number Publication Date
GB1398078A true GB1398078A (en) 1975-06-18

Family

ID=10440383

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4622871A Expired GB1398078A (en) 1971-10-05 1971-10-05 Reducing gas

Country Status (8)

Country Link
JP (1) JPS4845485A (en)
BE (1) BE789681A (en)
DE (1) DE2248913A1 (en)
FR (1) FR2156046B3 (en)
GB (1) GB1398078A (en)
IT (1) IT968603B (en)
NL (1) NL7213485A (en)
NO (1) NO133899C (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2758395A1 (en) * 1977-03-22 1978-09-28 Banquy David L METHOD FOR PRODUCING SYNTHESIS GAS
GB2170508A (en) * 1985-01-17 1986-08-06 Linde Ag Production of H2/CO synthesis gas
US4756750A (en) * 1987-04-27 1988-07-12 Air Products And Chemicals, Inc. Process for the direct reduction of iron ore
US20120091036A1 (en) * 2010-10-13 2012-04-19 George Ii Paul E Fuel processing system and method for sulfur bearing fuels
US8414666B2 (en) 2009-12-18 2013-04-09 Air Products And Chemicals, Inc. Integrated hydrogen production and hydrocarbon extraction
EP3050944A1 (en) * 2015-02-02 2016-08-03 Panasonic Intellectual Property Management Co., Ltd. Desulfurization process and a desulfurizer

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4072625A (en) * 1975-03-03 1978-02-07 Imperial Chemical Industries Limited Steam-hydrocarbon process

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2758395A1 (en) * 1977-03-22 1978-09-28 Banquy David L METHOD FOR PRODUCING SYNTHESIS GAS
GB2170508A (en) * 1985-01-17 1986-08-06 Linde Ag Production of H2/CO synthesis gas
US4756750A (en) * 1987-04-27 1988-07-12 Air Products And Chemicals, Inc. Process for the direct reduction of iron ore
US8414666B2 (en) 2009-12-18 2013-04-09 Air Products And Chemicals, Inc. Integrated hydrogen production and hydrocarbon extraction
US20120091036A1 (en) * 2010-10-13 2012-04-19 George Ii Paul E Fuel processing system and method for sulfur bearing fuels
US20190185767A1 (en) * 2010-10-13 2019-06-20 Battelle Memorial Institute Fuel Processing System and Method for Sulfur Bearing Fuels
US10941359B2 (en) * 2010-10-13 2021-03-09 Battelle Memorial Institute Fuel processing system and method for sulfur bearing fuels
EP3050944A1 (en) * 2015-02-02 2016-08-03 Panasonic Intellectual Property Management Co., Ltd. Desulfurization process and a desulfurizer

Also Published As

Publication number Publication date
FR2156046B3 (en) 1975-10-31
JPS4845485A (en) 1973-06-29
IT968603B (en) 1974-03-20
FR2156046A1 (en) 1973-05-25
DE2248913A1 (en) 1973-05-03
NO133899C (en) 1976-07-14
BE789681A (en) 1973-04-04
NO133899B (en) 1976-04-05
NL7213485A (en) 1973-04-09

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees