GB1379628A - Process for the production of unsaturated nitriles - Google Patents

Process for the production of unsaturated nitriles

Info

Publication number
GB1379628A
GB1379628A GB3904972A GB3904972A GB1379628A GB 1379628 A GB1379628 A GB 1379628A GB 3904972 A GB3904972 A GB 3904972A GB 3904972 A GB3904972 A GB 3904972A GB 1379628 A GB1379628 A GB 1379628A
Authority
GB
United Kingdom
Prior art keywords
moles
olefin
unsaturated nitriles
per mole
production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3904972A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SnamProgetti SpA
Original Assignee
SnamProgetti SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SnamProgetti SpA filed Critical SnamProgetti SpA
Publication of GB1379628A publication Critical patent/GB1379628A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00Preparation of carboxylic acid nitriles
    • C07C253/24Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/057Selenium or tellurium; Compounds thereof
    • B01J27/0576Tellurium; Compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1379628 Unsaturated nitriles SNAM PROGETTI SpA 22 Aug 1972 [2 Sept 1971] 39049/72 Heading C2C Unsaturated nitriles are prepared by reacting (e.g. at 400-500‹ C.) an olefin, ammonia and oxygen (or a gaseous mixture including oxygen) in the presence of gaseous CO 2 and/or CO and an antimony-based catalyst, using a total of from 1 to 50 moles of the carbon oxide(s) per mole of olefin. Another diluent in addition to the CO 2 and/or CO may also be present. The reaction is preferably carried out using 1-5 moles of O 2 and 0À8-1À5 moles of NH 3 per mole of olefin. Preferred catalysts are Fe-Sb and Sn-Sb oxycompounds optionally containing as promoter one or more of Cu, Ag, Te, Bi, Nb, Ce, Mn, W, Mo and V. The examples describe the preparation of acrylonitrile by ammoxidation of propylene.
GB3904972A 1971-09-02 1972-08-22 Process for the production of unsaturated nitriles Expired GB1379628A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
IT28153/71A IT938781B (en) 1971-09-02 1971-09-02 PERFECTED PROCESS FOR THE PRODUCTION OF UNSATURATED NITRILS

Publications (1)

Publication Number Publication Date
GB1379628A true GB1379628A (en) 1975-01-02

Family

ID=11223043

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3904972A Expired GB1379628A (en) 1971-09-02 1972-08-22 Process for the production of unsaturated nitriles

Country Status (24)

Country Link
JP (1) JPS4834821A (en)
AR (1) AR198795A1 (en)
AT (1) AT324297B (en)
AU (1) AU471694B2 (en)
BE (1) BE788069A (en)
BR (1) BR7206032D0 (en)
CA (1) CA982607A (en)
CH (1) CH545279A (en)
CS (1) CS187362B2 (en)
DD (1) DD101888A5 (en)
DE (1) DE2243013A1 (en)
ES (1) ES406365A1 (en)
FR (1) FR2151946A5 (en)
GB (1) GB1379628A (en)
HU (1) HU166001B (en)
IT (1) IT938781B (en)
LU (1) LU65963A1 (en)
NL (1) NL7211981A (en)
PL (1) PL89027B1 (en)
RO (1) RO62335A (en)
SE (1) SE402767B (en)
SU (1) SU438179A3 (en)
TR (1) TR17844A (en)
ZA (1) ZA725973B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108017557A (en) * 2017-12-06 2018-05-11 中国科学院兰州化学物理研究所苏州研究院 A kind of Process for the cyanation for preparing nitrile compounds

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108017557A (en) * 2017-12-06 2018-05-11 中国科学院兰州化学物理研究所苏州研究院 A kind of Process for the cyanation for preparing nitrile compounds
CN108017557B (en) * 2017-12-06 2020-11-24 中国科学院兰州化学物理研究所苏州研究院 Cyanidation method for preparing nitrile compound

Also Published As

Publication number Publication date
RO62335A (en) 1977-10-15
LU65963A1 (en) 1973-01-15
JPS4834821A (en) 1973-05-22
AU471694B2 (en) 1976-04-29
SU438179A3 (en) 1974-07-30
CS187362B2 (en) 1979-01-31
NL7211981A (en) 1973-03-06
CA982607A (en) 1976-01-27
AR198795A1 (en) 1974-07-24
IT938781B (en) 1973-02-10
HU166001B (en) 1974-12-28
ZA725973B (en) 1973-05-30
CH545279A (en) 1973-12-15
FR2151946A5 (en) 1973-04-20
DD101888A5 (en) 1973-11-20
ES406365A1 (en) 1975-07-01
TR17844A (en) 1976-04-13
BE788069A (en) 1972-12-18
PL89027B1 (en) 1976-10-30
BR7206032D0 (en) 1973-07-03
SE402767B (en) 1978-07-17
AT324297B (en) 1975-08-25
AU4551272A (en) 1974-02-14
DE2243013A1 (en) 1973-03-08

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee