GB1365558A - Treating fibres with polymers - Google Patents
Treating fibres with polymersInfo
- Publication number
- GB1365558A GB1365558A GB3568671A GB3568671A GB1365558A GB 1365558 A GB1365558 A GB 1365558A GB 3568671 A GB3568671 A GB 3568671A GB 3568671 A GB3568671 A GB 3568671A GB 1365558 A GB1365558 A GB 1365558A
- Authority
- GB
- United Kingdom
- Prior art keywords
- resorcinol
- olefin
- rubber
- composition
- compositions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/06—Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/41—Phenol-aldehyde or phenol-ketone resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/693—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2321/00—Characterised by the use of unspecified rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Textile Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
1365558 Resorcinol-unsaturate polymers; rubber compositions MONSANTO CO 29 July 1971 [30 July 1970] 35686/71 Headings C3R and C3P [Also in Division D1] A composition suitable for treating a fibre to enhance its capacity to adhere to rubber is prepared by condensing an aldehyde with a mixture of resorcinol and an essentially saturated polymer, the mixture being obtained by the acidic condensation of resorcinol and an olefin of 3-10 carbon atoms having 2 or more sites capable of reacting with resorcinol at least one of which is an ethylenically unsaturated group, the molar ratio of olefin to resorcinol being 0À1 to 2 : 1, the aldehyde being selected from saturated aliphatic C 1-6 aldehydes having straight or branched chains, paraformaldehyde and paraldehyde. In an embodiment the molar ratio of olefin to resorcinol is 0À1 to 0À6 : 1, and the molar ratio of aldehyde to resorcinol is 0À3 to 0À5 : 1. The aldehyde condensate may be dissolved in an organic solvent or an aqueous alkaline medium. The olefin may be a mono- or dihalo-olefin or an acyclic or cyclic diolefin. A conventional RFL adhesive comprising a resorcinol-HCHO condensate and a butadienestyrene-vinyl-pyridine latex or the latex alone may be added to the composition. The fibretreating composition may alternatively comprise the said essentially saturated polymer of resorcinol and an olefin instead of the said aldehyde condensate. The fibre treated with the composition may be heat-treated at 250-500‹ F. for ¢-5 minutes, before it is embedded in a rubber which is then vulcanized. Suitable fibres are those of polyester, rayon, nylon, cotton, wool, wood cellulose, glass, Al, Cu, Sn, steel, brass-plated steel and Al-steel alloys. In examples 2-12 fibre-treating compositions are prepared by condensing formaldehyde with an essentially saturated polymer containing unreacted resorcinol prepared by the acidic condensation of resorcinol with any one of the following olefins: 1,4-dichloro-2-butene, allyl chloride, 1,3-dichloro-2-butene, 2,3-dichloropropene, 5,7-dimethyl, 1,6-octadiene, 1,7-octadiene, 3-chloro-2-methyl propene, 3,4-dichloro- 1-butene, 1,5-cyclooctadiene, and 1,3-pentadiene, to which NH 4 OH is subsequently added. Single dip adhesive compositions are then prepared by mixing the above compositions with RFL or vinylpyridine styrene butadiene latex alone and water and polyester tire cords are dipped therein, heat-treated and then embedded in a rubber stock comprising natural rubber, oil-extended styrene-butadiene rubber, carbon black, stearic acid, zinc oxide, sulphur and sulphenamide, which is then cured. In examples 13-17 compositions are prepared comprising the essentially saturated polymer of resorcinol and the olefin and used in either a one dip adhesive composition containing the above latex or in a 2-dip system in which the polyester cord is first dipped into the said polymer composition and then into the latex alone. The polyester cords treated by either the 1- or 2-dip system are then treated as in Examples 2-12. The adhesive compositions can also be used to bond polyester cord to HRH rubber stocks containing in addition to the ingredients listed above precipitated silica, resorcinol and hexamethylenetetramine.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US5972070A | 1970-07-30 | 1970-07-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1365558A true GB1365558A (en) | 1974-09-04 |
Family
ID=22024814
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3568671A Expired GB1365558A (en) | 1970-07-30 | 1971-07-29 | Treating fibres with polymers |
Country Status (6)
Country | Link |
---|---|
JP (1) | JPS542237B1 (en) |
BE (1) | BE770688A (en) |
CA (1) | CA1043485A (en) |
DE (1) | DE2137989A1 (en) |
FR (1) | FR2099685B1 (en) |
GB (1) | GB1365558A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2033811A1 (en) | 2007-08-14 | 2009-03-11 | The Goodyear Tire & Rubber Company | Pneumatic tire |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE787461A (en) * | 1972-08-15 | 1973-02-12 | Monsanto Co | CONDENSING PRODUCTS OF RESOL AND INSATURE-RESORCINOL POLYMERS, USEFUL AS ADHESIVES |
-
1971
- 1971-07-29 BE BE770688A patent/BE770688A/en unknown
- 1971-07-29 DE DE19712137989 patent/DE2137989A1/en not_active Withdrawn
- 1971-07-29 GB GB3568671A patent/GB1365558A/en not_active Expired
- 1971-07-29 JP JP5644071A patent/JPS542237B1/ja active Pending
- 1971-07-29 FR FR7127886A patent/FR2099685B1/fr not_active Expired
- 1971-07-29 CA CA119,466A patent/CA1043485A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2033811A1 (en) | 2007-08-14 | 2009-03-11 | The Goodyear Tire & Rubber Company | Pneumatic tire |
Also Published As
Publication number | Publication date |
---|---|
CA1043485A (en) | 1978-11-28 |
JPS542237B1 (en) | 1979-02-03 |
DE2137989A1 (en) | 1972-02-03 |
FR2099685B1 (en) | 1974-05-31 |
BE770688A (en) | 1972-01-31 |
FR2099685A1 (en) | 1972-03-17 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |