GB1358394A - Electrochemical reductive coupling of substituted olefin reactans - Google Patents
Electrochemical reductive coupling of substituted olefin reactansInfo
- Publication number
- GB1358394A GB1358394A GB1797071A GB1797071A GB1358394A GB 1358394 A GB1358394 A GB 1358394A GB 1797071 A GB1797071 A GB 1797071A GB 1797071 A GB1797071 A GB 1797071A GB 1358394 A GB1358394 A GB 1358394A
- Authority
- GB
- United Kingdom
- Prior art keywords
- bis
- diethyl
- butane
- acrylonitrile
- olefin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract 4
- 238000006578 reductive coupling reaction Methods 0.000 title abstract 3
- -1 tetramethylammonium ions Chemical class 0.000 abstract 5
- KWYHDKDOAIKMQN-UHFFFAOYSA-N N,N,N',N'-tetramethylethylenediamine Chemical compound CN(C)CCN(C)C KWYHDKDOAIKMQN-UHFFFAOYSA-N 0.000 abstract 3
- 239000003792 electrolyte Substances 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 150000002500 ions Chemical class 0.000 abstract 2
- KYPOHTVBFVELTG-UPHRSURJSA-N (z)-but-2-enedinitrile Chemical compound N#C\C=C/C#N KYPOHTVBFVELTG-UPHRSURJSA-N 0.000 abstract 1
- OZXIZRZFGJZWBF-UHFFFAOYSA-N 1,3,5-trimethyl-2-(2,4,6-trimethylphenoxy)benzene Chemical compound CC1=CC(C)=CC(C)=C1OC1=C(C)C=C(C)C=C1C OZXIZRZFGJZWBF-UHFFFAOYSA-N 0.000 abstract 1
- PPMLLCVWIDDIDW-UHFFFAOYSA-N 3,4-diethylhexanediamide Chemical compound NC(=O)CC(CC)C(CC)CC(N)=O PPMLLCVWIDDIDW-UHFFFAOYSA-N 0.000 abstract 1
- NFCUAPLTILMPPT-UHFFFAOYSA-N 3,4-dimethylhexanediamide Chemical compound NC(=O)CC(C)C(C)CC(N)=O NFCUAPLTILMPPT-UHFFFAOYSA-N 0.000 abstract 1
- WJTRXLCSEJMCRJ-UHFFFAOYSA-N 4-phenylbut-3-en-2-one;prop-2-enenitrile Chemical compound C=CC#N.CC(=O)C=CC1=CC=CC=C1 WJTRXLCSEJMCRJ-UHFFFAOYSA-N 0.000 abstract 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 1
- OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- ZFDIRQKJPRINOQ-HWKANZROSA-N Ethyl crotonate Chemical compound CCOC(=O)\C=C\C ZFDIRQKJPRINOQ-HWKANZROSA-N 0.000 abstract 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 abstract 1
- BNPOWUJWEMIKII-UHFFFAOYSA-N N,N-dibutylpent-2-enamide Chemical compound CCCCN(CCCC)C(=O)C=CCC BNPOWUJWEMIKII-UHFFFAOYSA-N 0.000 abstract 1
- NQRYJNQNLNOLGT-UHFFFAOYSA-O Piperidinium(1+) Chemical compound C1CC[NH2+]CC1 NQRYJNQNLNOLGT-UHFFFAOYSA-O 0.000 abstract 1
- RWRDLPDLKQPQOW-UHFFFAOYSA-O Pyrrolidinium ion Chemical compound C1CC[NH2+]C1 RWRDLPDLKQPQOW-UHFFFAOYSA-O 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical group 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical group 0.000 abstract 1
- 125000003342 alkenyl group Chemical group 0.000 abstract 1
- 150000003863 ammonium salts Chemical class 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- VUEDNLCYHKSELL-UHFFFAOYSA-N arsonium Chemical compound [AsH4+] VUEDNLCYHKSELL-UHFFFAOYSA-N 0.000 abstract 1
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 1
- 125000004990 dihydroxyalkyl group Chemical group 0.000 abstract 1
- SHOJXDKTYKFBRD-UHFFFAOYSA-N mesityl oxide Natural products CC(C)=CC(C)=O SHOJXDKTYKFBRD-UHFFFAOYSA-N 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- YNAVUWVOSKDBBP-UHFFFAOYSA-O morpholinium Chemical compound [H+].C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-O 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- HISNRBVYBOVKMB-UHFFFAOYSA-N stibonium Chemical compound [SbH4+] HISNRBVYBOVKMB-UHFFFAOYSA-N 0.000 abstract 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 abstract 1
- ZFDIRQKJPRINOQ-UHFFFAOYSA-N transbutenic acid ethyl ester Natural products CCOC(=O)C=CC ZFDIRQKJPRINOQ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
- C25B3/29—Coupling reactions
- C25B3/295—Coupling reactions hydrodimerisation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Pyridine Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US4209170A | 1970-06-01 | 1970-06-01 | |
| US6177170A | 1970-08-06 | 1970-08-06 | |
| US9192270A | 1970-11-23 | 1970-11-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1358394A true GB1358394A (en) | 1974-07-03 |
Family
ID=27366047
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1797071A Expired GB1358394A (en) | 1970-06-01 | 1971-05-28 | Electrochemical reductive coupling of substituted olefin reactans |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS5118931B1 (enrdf_load_stackoverflow) |
| BE (1) | BE767916A (enrdf_load_stackoverflow) |
| CA (1) | CA978497A (enrdf_load_stackoverflow) |
| DE (1) | DE2126689B2 (enrdf_load_stackoverflow) |
| FR (1) | FR2093963B1 (enrdf_load_stackoverflow) |
| GB (1) | GB1358394A (enrdf_load_stackoverflow) |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA813877A (en) * | 1969-05-27 | Petrovich Tomilov Andrei | Method of preparing adiponitrile | |
| FR1548304A (enrdf_load_stackoverflow) * | 1967-06-01 | 1968-12-06 |
-
1971
- 1971-04-19 CA CA110,695A patent/CA978497A/en not_active Expired
- 1971-05-28 GB GB1797071A patent/GB1358394A/en not_active Expired
- 1971-05-28 DE DE19712126689 patent/DE2126689B2/de not_active Withdrawn
- 1971-06-01 JP JP46038199A patent/JPS5118931B1/ja active Pending
- 1971-06-01 FR FR7119792A patent/FR2093963B1/fr not_active Expired
- 1971-06-01 BE BE767916A patent/BE767916A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA978497A (en) | 1975-11-25 |
| DE2126689B2 (de) | 1976-02-05 |
| JPS5118931B1 (enrdf_load_stackoverflow) | 1976-06-14 |
| FR2093963A1 (enrdf_load_stackoverflow) | 1972-02-04 |
| FR2093963B1 (enrdf_load_stackoverflow) | 1973-10-19 |
| DE2126689A1 (de) | 1972-01-13 |
| BE767916A (fr) | 1971-12-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |