GB1338909A - Production of polymers based on phenols with an unsaturated substituent - Google Patents

Production of polymers based on phenols with an unsaturated substituent

Info

Publication number
GB1338909A
GB1338909A GB5958470A GB5958470A GB1338909A GB 1338909 A GB1338909 A GB 1338909A GB 5958470 A GB5958470 A GB 5958470A GB 5958470 A GB5958470 A GB 5958470A GB 1338909 A GB1338909 A GB 1338909A
Authority
GB
United Kingdom
Prior art keywords
yne
ene
cured
vinyl
pent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5958470A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Utyansky Z S
Original Assignee
Utyansky Z S
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from SU1384056A external-priority patent/SU292484A1/en
Priority claimed from SU7001428985A external-priority patent/SU434763A1/en
Priority claimed from SU7001467053A external-priority patent/SU448725A1/en
Application filed by Utyansky Z S filed Critical Utyansky Z S
Publication of GB1338909A publication Critical patent/GB1338909A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F38/00—Homopolymers and copolymers of compounds having one or more carbon-to-carbon triple bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
    • C08G8/04—Condensation polymers of aldehydes or ketones with phenols only of aldehydes
    • C08G8/08—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Laminated Bodies (AREA)

Abstract

1338909 Vinyl ethynyl phenol polymers Z S UTYANSKY K A IOTKOVSKAYA E K CHEVRANOVA E A KIMEL E M LUZYANINA A L PESHEKHONOVA V M ILIINA I I KROTKOVA and A G SHVARTS 15 Dec 1970 [15 Dec 1969 13 May 1970 11 Sept 1970] 59584/70 Headings C3P and C3R [Also in Division C2] Polymers are obtained by addition polymerization via the double bond of a compound of the formula in which R and R<SP>1</SP> are H or aliphatic or alicyclic groups, n is 0 or an integer, X and Y are H or alkyl and Z is H or OH, R<SP>11</SP> is a hydrogen atom or an epoxide group and W is a hydrogen atom or a hydroxy alkyl group, optionally together with mono- or diolefinic compounds or by condensation thereof with an unsaturated aldehyde. The products may be cured and compounded with elastomers. They may also be reacted with aldehydes. In examples, typical monomers of the above formula used are vinyl ethynyl phenol, 1 - hydroxy - phenyl - 1,1 - dimethylpent - 4 - ene - 2 - yne, 1 - (m - methyl - phydroxyphenyl) - 1,1 - dimethyl - pent - 4- ene - 2 - yne, 1 - hydroxyphenyl - 1 - cyclohexyl - pent - 4 - ene - 2 - yne, and epoxidized 1 - hydroxy phenyl - 1 - methyl - 1 - ethyl - pent - 4 - ene - 2 - yne, which are homopolymerized or copolymerized with methacrylic acid, 2-vinyl pyridine, acrylonitrile, maleic anhydride or a mixture of butadiene and styrene in the presence of hydrogen peroxide, benzoyl peroxide, azobisisobutyronitrile, diazoaminobenzene, or potassium persulphate/dimethylaniline /sodium alkylnaphthalene sulphonate, and cured in the presence of hexamethylenetetramine or a reaction product thereof with vinyl ethynyl phenol or derivative, urotropin, paraform, formalin, acetaldehyde or maleic anhydride; 1-(4-hydroxyphenyl)-hept-4-yne-6-ene is condensed with acrolein in the presence of p-toluene sulphonic acid and cured using benzyl or dicumyl peroxide, and a condensation product of a vinyl ethynyl phenol derivative, and furfural mixed with elastomer and cured with dicumyl peroxide. Blends are formed of some of the polymerization and condensation products with butadiene/nitrile, butadiene/styrene and chloroprene rubbers.
GB5958470A 1969-12-15 1970-12-15 Production of polymers based on phenols with an unsaturated substituent Expired GB1338909A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
SU1384056A SU292484A1 (en) 1969-12-15 1969-12-15 METHOD OF OBTAINING COPOLYMERS
SU7001428985A SU434763A1 (en) 1970-05-13 1970-05-13 Method of preparing thermoreactive phenolaldehyde resins
SU7001467053A SU448725A1 (en) 1970-09-11 1970-09-11 Curable unsaturated rubber-based latex

Publications (1)

Publication Number Publication Date
GB1338909A true GB1338909A (en) 1973-11-28

Family

ID=27356188

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5958470A Expired GB1338909A (en) 1969-12-15 1970-12-15 Production of polymers based on phenols with an unsaturated substituent

Country Status (4)

Country Link
AT (1) AT317544B (en)
DE (1) DE2060918A1 (en)
FR (1) FR2073809A5 (en)
GB (1) GB1338909A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5470728A (en) * 1992-02-05 1995-11-28 Bio-Technical Resources Formation of and dehydration of hydroxylated diphenyl acetylenes using Pseudomonas ATCC 55272
JP2009299065A (en) * 2003-09-29 2009-12-24 Sumitomo Bakelite Co Ltd Thermosetting resin and method for manufacturing the same
US8492507B2 (en) 2008-09-23 2013-07-23 Nexam Chemical Ab Acetylenic polyamide

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010071532A1 (en) * 2008-12-16 2010-06-24 Nexam Chemical Ab Acetylenic phenol-aldehyde resin

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5470728A (en) * 1992-02-05 1995-11-28 Bio-Technical Resources Formation of and dehydration of hydroxylated diphenyl acetylenes using Pseudomonas ATCC 55272
JP2009299065A (en) * 2003-09-29 2009-12-24 Sumitomo Bakelite Co Ltd Thermosetting resin and method for manufacturing the same
US8492507B2 (en) 2008-09-23 2013-07-23 Nexam Chemical Ab Acetylenic polyamide

Also Published As

Publication number Publication date
DE2060918A1 (en) 1971-06-16
AT317544B (en) 1974-09-10
FR2073809A5 (en) 1971-10-01

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee