GB1336394A - Pigmentary compositions their preparation and their applications to the colouration of bulk acrylic material - Google Patents

Pigmentary compositions their preparation and their applications to the colouration of bulk acrylic material

Info

Publication number
GB1336394A
GB1336394A GB2520871*A GB2520871A GB1336394A GB 1336394 A GB1336394 A GB 1336394A GB 2520871 A GB2520871 A GB 2520871A GB 1336394 A GB1336394 A GB 1336394A
Authority
GB
United Kingdom
Prior art keywords
acrylonitrile
copolymer
colouring matter
water
pigmentary
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2520871*A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pechiney Ugine Kuhlmann SA
Original Assignee
Pechiney Ugine Kuhlmann SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pechiney Ugine Kuhlmann SA filed Critical Pechiney Ugine Kuhlmann SA
Publication of GB1336394A publication Critical patent/GB1336394A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D17/00—Pigment pastes, e.g. for mixing in paints
    • C09D17/002—Pigment pastes, e.g. for mixing in paints in organic medium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0001—Post-treatment of organic pigments or dyes
    • C09B67/0004—Coated particulate pigments or dyes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0071—Process features in the making of dyestuff preparations; Dehydrating agents; Dispersing agents; Dustfree compositions
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/06—Treatment with inorganic compounds
    • C09C3/063—Coating
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/10—Treatment with macromolecular organic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Artificial Filaments (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

1336394 Pigment compositions comprising polyacrylonitrile PECHINEY UGINE KUHLMANN 19 April 1971 [25 March 1970] 25208/71 Heading C3P A pigmentary composition comprises (a) at least one colouring matter which is insoluble in water and in the organic solvents used for spinning fibres based on homo- or copolymers of acrylonitrile, (b) a non-ionic surface-active agent which is insoluble in water but soluble in the organic solvents used for spinning fibres based on these homo- or copolymers in a weight (B) of between 1 and 10% inclusive of the weight (A) of the colouring matter, and (c) a homo- or copolymer based on acrylonitrile in a weight (C) such that the weight ratio is between 20 and 95. The colouring matter may be a mineral pigment, e.g. carbon black, iron oxides, cadmium oranges, chromium yellow, molybdenum red or titanium dioxide, or an organic pigment, such as an azo, azomethine, anthraquinone, phthalocyanine or indigo pigment. The non-ionic surfactant may be (a) a water-insoluble product of addition of ethylene oxide to a fatty alcohol or alkylphenol, (b) a water-insoluble polyalkylene glycol or ether thereof, having a viscosity of 10 to 470 centistokes at 37À8‹C, (c) a compound of Formula I where x is a whole number greater than 20 and y + z is such that the content of -(OCH 2 CH 2 )- is less than 10% of the molecular weight, or (d) a compound of Formula II where x 1 +x 2 +x 3 +x 4 is a whole number greater than 16 and y 1 +y 2 +y 3 +y 4 is such that the content of -(OC 2 H 4 ) is less than 10% of the molecular weight. The polymer may be a copolymer of acrylonitrile with an acrylic or methacrylic acid ester or a terpolymer of acrylonitrile, methylvinylpyridine and vinyl acetate or vinyl chloride. The pigmentary compositions of the invention may be prepared by (a) introducing zinc chloride or ammonium thiocyanate or an alkali metal thiocyanate and the polymer into an aqueous dispersion of the colouring matter and the surface-active agent, the weights of colouring matter (A), surface active agent (B), water (A<SP>1</SP>), polymer (C), and zinc chloride (D) or thiocyanate (D<SP>1</SP>) being such that the following relations are satisfied then (b) diluting the mixture with water until the ratio is less than or equal to 0À4, and (c) isolating the precipitate obtained. The colouring matter may be in the form of a pressed aqueous paste, or the colouring matter, in the form of a powder may be ground in aqueous medium. The pigmentary compositions of the invention may be used for bulk coloration of homo- or copolymers of acrylonitrile. In the examples the polymer component of the pigmentary composition is: (1) to (4) and (7) to (32) a copolymer of 94% acrylonitrile and 6% methyl methacrylate; (5) a copolymer of 90% acrylonitrile and 10% of a mixture of vinyl acetate and methylvinylpyridine; and (33) a copolymer of 91% acrylonitrile and 9% methyl acrylate. In Examples (34) to (36), polyacrylonitrile and a copolymer of 90% acrylonitrile and 10% methyl acrylate are mass coloured using the pigmentary compositions of the invention.
GB2520871*A 1970-03-25 1971-04-19 Pigmentary compositions their preparation and their applications to the colouration of bulk acrylic material Expired GB1336394A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7010703A FR2082729A5 (en) 1970-03-25 1970-03-25

Publications (1)

Publication Number Publication Date
GB1336394A true GB1336394A (en) 1973-11-07

Family

ID=9052858

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2520871*A Expired GB1336394A (en) 1970-03-25 1971-04-19 Pigmentary compositions their preparation and their applications to the colouration of bulk acrylic material

Country Status (7)

Country Link
JP (1) JPS5224052B1 (en)
BE (1) BE764433A (en)
CH (1) CH520759A (en)
DE (2) DE2113090C3 (en)
FR (1) FR2082729A5 (en)
GB (1) GB1336394A (en)
NL (1) NL7103778A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998036111A1 (en) * 1997-02-12 1998-08-20 Akzo Nobel Uk Limited Manufacture of acrylic fibres
EP2048202A1 (en) 2007-10-10 2009-04-15 Clariant International Ltd. Glycol based pigment preparation for mass dyeing of polyacrylonitrile fibers
CN110205593A (en) * 2019-05-20 2019-09-06 陈玲玲 A kind of preparation method of polyhedron metal effect pigments

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5480847A (en) * 1977-12-08 1979-06-27 Kazuo Nomura Growthhcontrol type cultivating machine

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998036111A1 (en) * 1997-02-12 1998-08-20 Akzo Nobel Uk Limited Manufacture of acrylic fibres
EP2048202A1 (en) 2007-10-10 2009-04-15 Clariant International Ltd. Glycol based pigment preparation for mass dyeing of polyacrylonitrile fibers
US7905929B2 (en) 2007-10-10 2011-03-15 Clariant Finance (Bvi) Limited Glycol based pigment preparation for mass dyeing of polyacrylonitrile fibers
CN110205593A (en) * 2019-05-20 2019-09-06 陈玲玲 A kind of preparation method of polyhedron metal effect pigments

Also Published As

Publication number Publication date
BE764433A (en) 1971-09-17
NL7103778A (en) 1971-09-28
DE2113090B2 (en) 1973-05-10
DE2113090A1 (en) 1971-10-07
CH520759A (en) 1972-03-31
FR2082729A5 (en) 1971-12-10
DE2113090C3 (en) 1973-12-06
JPS5224052B1 (en) 1977-06-29

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee