GB1330549A - Alkaline earth metal organometllic compounds their preparation by metallation and catalysts comprising same - Google Patents
Alkaline earth metal organometllic compounds their preparation by metallation and catalysts comprising sameInfo
- Publication number
- GB1330549A GB1330549A GB3924871A GB3924871A GB1330549A GB 1330549 A GB1330549 A GB 1330549A GB 3924871 A GB3924871 A GB 3924871A GB 3924871 A GB3924871 A GB 3924871A GB 1330549 A GB1330549 A GB 1330549A
- Authority
- GB
- United Kingdom
- Prior art keywords
- barium
- compounds
- xanthene
- methoxyphenyl
- bis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003054 catalyst Substances 0.000 title abstract 2
- 150000001875 compounds Chemical class 0.000 title abstract 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 title 1
- 150000001342 alkaline earth metals Chemical class 0.000 title 1
- 238000006263 metalation reaction Methods 0.000 title 1
- 229910052788 barium Inorganic materials 0.000 abstract 4
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 abstract 3
- 229910052791 calcium Inorganic materials 0.000 abstract 3
- 239000011575 calcium Substances 0.000 abstract 3
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 3
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 abstract 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- UEXCJVNBTNXOEH-UHFFFAOYSA-N Ethynylbenzene Chemical group C#CC1=CC=CC=C1 UEXCJVNBTNXOEH-UHFFFAOYSA-N 0.000 abstract 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 abstract 2
- 150000002902 organometallic compounds Chemical class 0.000 abstract 2
- 239000002798 polar solvent Substances 0.000 abstract 2
- 229910052712 strontium Inorganic materials 0.000 abstract 2
- KIIBETRYVBIAOO-UHFFFAOYSA-N 1,2-diphenylethylbenzene Chemical compound C=1C=CC=CC=1CC(C=1C=CC=CC=1)C1=CC=CC=C1 KIIBETRYVBIAOO-UHFFFAOYSA-N 0.000 abstract 1
- RDCOLDLJNDPOTK-UHFFFAOYSA-N 1,3-diphenylprop-2-enylbenzene Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)C=CC1=CC=CC=C1 RDCOLDLJNDPOTK-UHFFFAOYSA-N 0.000 abstract 1
- DPRFNHUMLZJXNR-UHFFFAOYSA-N 1-methoxy-2-[(2-methoxyphenyl)methyl]benzene Chemical compound COC1=CC=CC=C1CC1=CC=CC=C1OC DPRFNHUMLZJXNR-UHFFFAOYSA-N 0.000 abstract 1
- CUEFLECFBSJEHF-UHFFFAOYSA-N 9-(2-methoxyphenyl)-9h-fluorene Chemical compound COC1=CC=CC=C1C1C2=CC=CC=C2C2=CC=CC=C21 CUEFLECFBSJEHF-UHFFFAOYSA-N 0.000 abstract 1
- MINJGMSWMGWGPN-UHFFFAOYSA-N 9-(2-methoxyphenyl)-9h-xanthene Chemical compound COC1=CC=CC=C1C1C2=CC=CC=C2OC2=CC=CC=C21 MINJGMSWMGWGPN-UHFFFAOYSA-N 0.000 abstract 1
- NOTOICASFLUBBM-UHFFFAOYSA-N 9-naphthalen-1-yl-9h-fluorene Chemical compound C1=CC=C2C(C3C=4C(C5=CC=CC=C53)=CC=CC=4)=CC=CC2=C1 NOTOICASFLUBBM-UHFFFAOYSA-N 0.000 abstract 1
- SVHZQUOTMFEBBI-UHFFFAOYSA-N 9-naphthalen-1-yl-9h-xanthene Chemical compound C1=CC=C2C(C3C4=CC=CC=C4OC4=CC=CC=C43)=CC=CC2=C1 SVHZQUOTMFEBBI-UHFFFAOYSA-N 0.000 abstract 1
- ZJQCOVBALALRCC-UHFFFAOYSA-N 9-phenyl-9h-fluorene Chemical compound C1=CC=CC=C1C1C2=CC=CC=C2C2=CC=CC=C21 ZJQCOVBALALRCC-UHFFFAOYSA-N 0.000 abstract 1
- JAPCXGFREZPNHK-UHFFFAOYSA-N 9-phenyl-9h-xanthene Chemical compound C12=CC=CC=C2OC2=CC=CC=C2C1C1=CC=CC=C1 JAPCXGFREZPNHK-UHFFFAOYSA-N 0.000 abstract 1
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 abstract 1
- YTOLQPHBEVXBMO-UHFFFAOYSA-N C=1C=CC=CC=1C(C=1C=CC=CC=1)(C=1C=CC=CC=1)[Ba]C(C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(C=1C=CC=CC=1)[Ba]C(C=1C=CC=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 YTOLQPHBEVXBMO-UHFFFAOYSA-N 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 1
- RNBKWIFPYLHFCC-UHFFFAOYSA-N [Ba](C(c1ccccc1)c1ccccc1)C(c1ccccc1)c1ccccc1 Chemical compound [Ba](C(c1ccccc1)c1ccccc1)C(c1ccccc1)c1ccccc1 RNBKWIFPYLHFCC-UHFFFAOYSA-N 0.000 abstract 1
- 150000001335 aliphatic alkanes Chemical group 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- DMSZORWOGDLWGN-UHFFFAOYSA-N ctk1a3526 Chemical compound NP(N)(N)=O DMSZORWOGDLWGN-UHFFFAOYSA-N 0.000 abstract 1
- 150000001983 dialkylethers Chemical class 0.000 abstract 1
- 125000000623 heterocyclic group Chemical group 0.000 abstract 1
- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- QDLAGTHXVHQKRE-UHFFFAOYSA-N lichenxanthone Natural products COC1=CC(O)=C2C(=O)C3=C(C)C=C(OC)C=C3OC2=C1 QDLAGTHXVHQKRE-UHFFFAOYSA-N 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 229920000768 polyamine Polymers 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 abstract 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
- C08G79/02—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/122—Metal aryl or alkyl compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/50—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkaline earth metals, zinc, cadmium, mercury, copper or silver
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
- C08G65/08—Saturated oxiranes
- C08G65/10—Saturated oxiranes characterised by the catalysts used
- C08G65/12—Saturated oxiranes characterised by the catalysts used containing organo-metallic compounds or metal hydrides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polymerization Catalysts (AREA)
- Polyethers (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US6947670A | 1970-09-03 | 1970-09-03 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1330549A true GB1330549A (en) | 1973-09-19 |
Family
ID=22089237
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3924871A Expired GB1330549A (en) | 1970-09-03 | 1971-10-20 | Alkaline earth metal organometllic compounds their preparation by metallation and catalysts comprising same |
Country Status (4)
| Country | Link |
|---|---|
| JP (2) | JPS5412455B1 (cs) |
| CA (1) | CA933171A (cs) |
| DE (1) | DE2144332C2 (cs) |
| GB (1) | GB1330549A (cs) |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3041312A (en) | 1959-07-31 | 1962-06-26 | Monsanto Chemicals | Anionic polymerization process |
-
1971
- 1971-06-22 CA CA116332A patent/CA933171A/en not_active Expired
- 1971-08-30 JP JP6595771A patent/JPS5412455B1/ja active Pending
- 1971-09-03 DE DE2144332A patent/DE2144332C2/de not_active Expired
- 1971-10-20 GB GB3924871A patent/GB1330549A/en not_active Expired
-
1975
- 1975-06-24 JP JP50077153A patent/JPS5231268B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE2144332A1 (de) | 1972-06-29 |
| JPS5412455B1 (cs) | 1979-05-23 |
| JPS5176376A (cs) | 1976-07-01 |
| DE2144332C2 (de) | 1982-07-01 |
| CA933171A (en) | 1973-09-04 |
| JPS5231268B2 (cs) | 1977-08-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| 429A | Application made for amendment of specification (sect. 29/1949) | ||
| 429H | Application (made) for amendment of specification now open to opposition (sect. 29/1949) | ||
| 429D | Case decided by the comptroller ** specification amended (sect. 29/1949) | ||
| 429O | Case decided by the comptroller (sect. 29/1949) |
Free format text: DELETE IN JOURNAL NO 4497 PAGE 1378 |
|
| 429D | Case decided by the comptroller ** specification amended (sect. 29/1949) | ||
| PE20 | Patent expired after termination of 20 years |