GB1329451A - Process for the preparation of aldehydes and ketones by oxidation of unsaturated hydrocarbons - Google Patents

Process for the preparation of aldehydes and ketones by oxidation of unsaturated hydrocarbons

Info

Publication number
GB1329451A
GB1329451A GB1329451DA GB1329451A GB 1329451 A GB1329451 A GB 1329451A GB 1329451D A GB1329451D A GB 1329451DA GB 1329451 A GB1329451 A GB 1329451A
Authority
GB
United Kingdom
Prior art keywords
compound
palladium
catalyst
prepared
oxygen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Publication of GB1329451A publication Critical patent/GB1329451A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/648—Vanadium, niobium or tantalum or polonium
    • B01J23/6482—Vanadium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

1329451 Carbonyl compounds UNION CARBIDE CORP 28 Aug 1970 [28 Aug 1969 29 July 1970] 41562/70 Heading C2C [Also in Divisions B1 and C1] An aldehyde or ketone is prepared by a process which comprises contacting an unsaturated hydrocarbon in the vapour phase with molecular oxygen and water vapour in the presence of catalyst which has been prepared by heating, for at least 3 hours at a temperature of from 200‹ to 500‹ C. in the presence of a gas consisting of or comprising oxygen, a mixture which contains (a) a vanadium compound, (b) palladium or a compound thereof and, optionally, (c) at least one constituent selected from ruthenium, osmium, iridium, platinum and compounds thereof and/or (d) a compound of another transition metal, for example selected from niobium, tantalum, molybdenum and tungsten. The palladium component may comprise a compound containing palladium, an additional transition metal and oxygen, for example selected from vanadates, chromates, titanates and manganates of palladium. The catalyst may contain support material, for example selected from alpha-alumina, zirconia, zinc oxide, silicon carbide and porous glass, or a minor proportion of binder material, for example silica or clay. The unsaturated hydrocarbon may be an alkene, a cycloalkene, a diene or an aralkyl compound, for example toluene. The catalyst may be used in the form of a fixed, moving or fluidized bed, the contacting being effected, optionally in the presence of saturated alkane, for example methane or ethane, and/or a minor proportion of acetylene or allene, at a temperature preferably of from 60‹ to 200‹ C. and a pressure preferably of from 1 to 50 atmospheres. Examples (including comparative examples) relate to the conversion of ethylene to acetaldehyde and by-product acetic acid (Examples I to XX and XXIII), of propylene to acetone (Example XXI) and of butene-1 or butene-2 to methylethylketone and by-product acetaldehyde and acetic acid (Example XXII) in the presence of catalysts which contain alphaalumina support material and which usually have been prepared by a procedure involving spray deposition and subsequent heating for 16 hours at 400‹ C. in air.
GB1329451D 1969-08-28 1970-08-28 Process for the preparation of aldehydes and ketones by oxidation of unsaturated hydrocarbons Expired GB1329451A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US85397469A 1969-08-28 1969-08-28
US5933870A 1970-07-29 1970-07-29

Publications (1)

Publication Number Publication Date
GB1329451A true GB1329451A (en) 1973-09-12

Family

ID=26738647

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1329451D Expired GB1329451A (en) 1969-08-28 1970-08-28 Process for the preparation of aldehydes and ketones by oxidation of unsaturated hydrocarbons

Country Status (5)

Country Link
BE (1) BE755476A (en)
DE (1) DE2042815C3 (en)
FR (1) FR2059914A5 (en)
GB (1) GB1329451A (en)
NL (1) NL7012802A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004067167A1 (en) * 2003-01-27 2004-08-12 Bp Chemicals Limited Oxidation catalyst and its preparation

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4202934A (en) * 1978-07-03 1980-05-13 United Technologies Corporation Noble metal/vanadium alloy catalyst and method for making
DE3566081D1 (en) * 1984-12-15 1988-12-15 Draegerwerk Ag Platinum catalyst on a support as air purifying agent

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004067167A1 (en) * 2003-01-27 2004-08-12 Bp Chemicals Limited Oxidation catalyst and its preparation
KR100999329B1 (en) 2003-01-27 2010-12-08 비피 케미칼즈 리미티드 Oxidation catalyst and its preparation
US8242048B2 (en) 2003-01-27 2012-08-14 Bp Chemicals Limited Oxidation catalyst and its preparation
CN103224439A (en) * 2003-01-27 2013-07-31 英国石油化学品有限公司 Oxidation catalyst and its preparation

Also Published As

Publication number Publication date
DE2042815C3 (en) 1975-02-13
DE2065585B2 (en) 1976-07-08
FR2059914A5 (en) 1971-06-04
DE2065585A1 (en) 1974-05-16
BE755476A (en) 1971-03-01
NL7012802A (en) 1971-03-02
DE2042815B2 (en) 1974-05-22
DE2042815A1 (en) 1971-03-11

Similar Documents

Publication Publication Date Title
US5102851A (en) Supported catalyst for hydrocarbon synthesis
US3156735A (en) Oxidative dehydrogenation using goldplatinum group metal catalyst
Tan et al. Catalytic oxidation of olefin over oxide catalysts containing molybdenum: III. Oxidation of olefin to ketone over Co3O4 MoO3 and SnO2 MoO3 catalysts
US4456694A (en) Catalysts for producing alcohols from olefins and synthesis gas
US4857497A (en) Supported metal catalysts and use thereof
US3810953A (en) Dehydrogenation of organic compounds
Seiyama et al. Oxyhydrative scission of olefins: I. Oxidation of lower olefins
EP0091662B1 (en) Catalyst and process for dehydrating 2-alcohols
Xu et al. Rh/NaY: A selective catalyst for direct synthesis of acetic acid from syngas
US3981923A (en) Dehydrogenation of alcohols to ketones
US4230897A (en) Process for selectively hydrogenating a hydrocarbon cut containing at least one diolefinic hydrocarbon and at least one acetylenic hydrocarbon using a palladium catalyst with crystallites of at least 50 angstroms
US4380589A (en) Novel Fischer-Tropsch catalysts
US4417089A (en) Hydroisomerization
US4415480A (en) Transition metal oxide Bronsted acid catalysts
GB1329451A (en) Process for the preparation of aldehydes and ketones by oxidation of unsaturated hydrocarbons
US3926845A (en) Catalysts compositions
US20050113251A1 (en) Catalyst and process for selective hydrogenation
US4167532A (en) Dehydrogenation of organic compounds
EP0217855A1 (en) Process and low sodium catalyst for the production of formaldehyde from methane
US4705771A (en) Process and catalyst for the production of formaldehyde from methane
US2393537A (en) Catalytic dehydrogenation
US4737482A (en) Catalysts for oxidation of olefins to ketones
KR20230040342A (en) Dehydrogenation catalyst and method of use thereof
US4280959A (en) Oxidative dehydrogenation of alkenes or alkadienes to furan compounds
US3647903A (en) Method of preparing diolefins having conjugated double bonds

Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees