GB1306693A - Process for polymerizing tetraoxane and certain products of the process - Google Patents

Process for polymerizing tetraoxane and certain products of the process

Info

Publication number
GB1306693A
GB1306693A GB2511270A GB2511270A GB1306693A GB 1306693 A GB1306693 A GB 1306693A GB 2511270 A GB2511270 A GB 2511270A GB 2511270 A GB2511270 A GB 2511270A GB 1306693 A GB1306693 A GB 1306693A
Authority
GB
United Kingdom
Prior art keywords
dimethyl
polymerization
methyl
thiocyanate
sulphone
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2511270A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Daicel Corp
Ube Corp
Original Assignee
Daicel Corp
Ube Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP4828469A external-priority patent/JPS4838633B1/ja
Application filed by Daicel Corp, Ube Industries Ltd filed Critical Daicel Corp
Publication of GB1306693A publication Critical patent/GB1306693A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2/00Addition polymers of aldehydes or cyclic oligomers thereof or of ketones; Addition copolymers thereof with less than 50 molar percent of other substances
    • C08G2/10Polymerisation of cyclic oligomers of formaldehyde

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1306693 Tetraoxan polymerization DAICEL Ltd and UBE INDUSTRIES Ltd 26 May 1970 [26 May 1969 20 June 1969 9 March 1970 4 April 1970] 25112/70 Heading C3P Oxymethylene polymers, which may contain units derived from a thiirane, a thiocyanate or a trithianoxide either as comonomer, on chainends or on the stem of the polymer, are obtained by the polymerization of tetraoxan in the presence of sulphur, carbon disulphide, or certain specified classes of organic sulphur compounds. The polymerization is suitably carried out with solid phase monomer, and may be further promoted by the use of ionizing radiation or ultra-violet light, either prior to or during the polymerization. In examples the sulphur compound is CS 2 , methyl thiocyanate, trithian, dimethyl disulphide, methyl thioglycolate, methyl sulphide, S, thiourea, thiocetamide, ethylene trithiocarbonate, tetrahydrothiophen, ethylene thiourea, diethyl- or dimethyl-sulphate, dimethyl sulphone, dimethyl sulphoxide, glycol sulphite, dimethyl sulphite, ethylene-, propylene- and cyclohexene sulphide, methyl- or benzyl-thiocyanate, trimethylene tri-sulphone, tetrahydrothiophen-1-oxide or -1-dioxide, dihydrothiophen-1-oxide, thiophen and tetramethylene sulphone. Comparative experiments with trioxan are described.
GB2511270A 1969-05-26 1970-05-26 Process for polymerizing tetraoxane and certain products of the process Expired GB1306693A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP4127769 1969-05-26
JP4828469A JPS4838633B1 (en) 1969-06-20 1969-06-20
JP1961570 1970-03-09
JP2836270 1970-04-04

Publications (1)

Publication Number Publication Date
GB1306693A true GB1306693A (en) 1973-02-14

Family

ID=27457227

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2511270A Expired GB1306693A (en) 1969-05-26 1970-05-26 Process for polymerizing tetraoxane and certain products of the process

Country Status (5)

Country Link
CA (1) CA928895A (en)
DE (1) DE2025723A1 (en)
FR (1) FR2044821B1 (en)
GB (1) GB1306693A (en)
NL (1) NL163805C (en)

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL123945C (en) * 1959-01-07

Also Published As

Publication number Publication date
DE2025723A1 (en) 1970-12-17
CA928895A (en) 1973-06-19
FR2044821A1 (en) 1971-02-26
NL163805C (en) 1980-10-15
NL7007561A (en) 1970-11-30
FR2044821B1 (en) 1973-07-13
NL163805B (en) 1980-05-16

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Legal Events

Date Code Title Description
PS Patent sealed
PLE Entries relating assignments, transmissions, licences in the register of patents
PE20 Patent expired after termination of 20 years