GB1298462A - Recording information by forming fluorescent material images - Google Patents
Recording information by forming fluorescent material imagesInfo
- Publication number
- GB1298462A GB1298462A GB48043/69A GB4804369A GB1298462A GB 1298462 A GB1298462 A GB 1298462A GB 48043/69 A GB48043/69 A GB 48043/69A GB 4804369 A GB4804369 A GB 4804369A GB 1298462 A GB1298462 A GB 1298462A
- Authority
- GB
- United Kingdom
- Prior art keywords
- fluorescent
- disclosed
- examples
- anthracene
- conversion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/77—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
- B01J19/122—Incoherent waves
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/46—Doubly bound oxygen atoms, or two oxygen atoms singly bound to the same carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D307/68—Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D493/00—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system
- C07D493/02—Heterocyclic compounds containing oxygen atoms as the only ring hetero atoms in the condensed system in which the condensed system contains two hetero rings
- C07D493/08—Bridged systems
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B11/00—Diaryl- or thriarylmethane dyes
- C09B11/04—Diaryl- or thriarylmethane dyes derived from triarylmethanes, i.e. central C-atom is substituted by amino, cyano, alkyl
- C09B11/06—Hydroxy derivatives of triarylmethanes in which at least one OH group is bound to an aryl nucleus and their ethers or esters
- C09B11/08—Phthaleins; Phenolphthaleins; Fluorescein
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/72—Photosensitive compositions not covered by the groups G03C1/005 - G03C1/705
- G03C1/73—Photosensitive compositions not covered by the groups G03C1/005 - G03C1/705 containing organic compounds
-
- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06K—GRAPHICAL DATA READING; PRESENTATION OF DATA; RECORD CARRIERS; HANDLING RECORD CARRIERS
- G06K19/00—Record carriers for use with machines and with at least a part designed to carry digital markings
- G06K19/02—Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the selection of materials, e.g. to avoid wear during transport through the machine
-
- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06K—GRAPHICAL DATA READING; PRESENTATION OF DATA; RECORD CARRIERS; HANDLING RECORD CARRIERS
- G06K19/00—Record carriers for use with machines and with at least a part designed to carry digital markings
- G06K19/06—Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code
- G06K19/06009—Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code with optically detectable marking
-
- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06K—GRAPHICAL DATA READING; PRESENTATION OF DATA; RECORD CARRIERS; HANDLING RECORD CARRIERS
- G06K7/00—Methods or arrangements for sensing record carriers, e.g. for reading patterns
- G06K7/10—Methods or arrangements for sensing record carriers, e.g. for reading patterns by electromagnetic radiation, e.g. optical sensing; by corpuscular radiation
- G06K7/12—Methods or arrangements for sensing record carriers, e.g. for reading patterns by electromagnetic radiation, e.g. optical sensing; by corpuscular radiation using a selected wavelength, e.g. to sense red marks and ignore blue marks
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11C—STATIC STORES
- G11C13/00—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00
- G11C13/04—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using optical elements ; using other beam accessed elements, e.g. electron or ion beam
- G11C13/048—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using optical elements ; using other beam accessed elements, e.g. electron or ion beam using other optical storage elements
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2603/00—Systems containing at least three condensed rings
- C07C2603/02—Ortho- or ortho- and peri-condensed systems
- C07C2603/04—Ortho- or ortho- and peri-condensed systems containing three rings
- C07C2603/22—Ortho- or ortho- and peri-condensed systems containing three rings containing only six-membered rings
- C07C2603/24—Anthracenes; Hydrogenated anthracenes
-
- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06K—GRAPHICAL DATA READING; PRESENTATION OF DATA; RECORD CARRIERS; HANDLING RECORD CARRIERS
- G06K19/00—Record carriers for use with machines and with at least a part designed to carry digital markings
- G06K19/06—Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code
- G06K2019/06215—Aspects not covered by other subgroups
- G06K2019/06225—Aspects not covered by other subgroups using wavelength selection, e.g. colour code
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- General Physics & Mathematics (AREA)
- Theoretical Computer Science (AREA)
- Electromagnetism (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Artificial Intelligence (AREA)
- Computer Vision & Pattern Recognition (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
- Plural Heterocyclic Compounds (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
- Luminescent Compositions (AREA)
Abstract
1298462 Luminescent materials and uses thereof; polycyclic aromatic hydrocarbons AMERICAN CYANAMID CO 30 Sept 1969 [1 Oct 1968 (3)] 48043/69 Headings C4S and C5E [Also in Division C2] A method of recording information on a substrate comprises providing a substrate carrying a substantially non-fluorescent substance as defined but which is convertible to a chemically different fluorescent substance on being heated and/or on the application of ultraviolet radiation, and heating or applying the above radiant energy in a pattern to effect conversion to a fluorescent substance capable of fluorescing under U.V. or visible radiation. The precursor is preferably completely non-fluorescent but may be a substance weakly fluorescent under U.V. or visible radiation and convertible to a fluorescent substance which fluoresces so much more strongly that an image pattern may be read out against the background. The converted fluorescent substance, which may be reversible on light application, may also be coloured and immediately visible or may be colourless like the precursor, and the information may be alphanumeric, code markings, e.g. dots or lines, or pictorial information, and in preferred embodiments no fixing is required. Applications include electronic storage and replay of sound and pictures, phonograph discs, numerical data collection and retrieval, production and validation of cards, stamps and passes, which may include superimposed information layers over part or all the card. Preferably the read out wavelength does not effect further conversion, but may be of the same wavelength as the information input radiation if of sufficiently short duration. Imaging duration may be as low as a millisecond, and with a laser, a nanosecond. The precursor may be coated on a substrate or incorporated in transparent or opaque plastics films, and sheets, belts, discs, drums, bottles or boxes. Many examples of precursor and fluorescent substances are given. For example, uranine and Rhodamine B and a wide range of chromere compounds are disclosed which being of differing spectral properties may be included in a coded alphabet and preparations of precursors are described. Other examples include o - chlorophenyl - 1 - naphthyl ether, polycyclic aromatic anhydrides undergoing photochemical decarbonylation, or the same reaction on heating to the melting point (specified m.p. disclosed), e.g. 9, 10 anhydride of 9, 10 diphenylanthracene, (others being disclosed); endoperoxides, e.g. 9,10-diphenyl anthracene endoperoxide, and halogen anthracene (others being disclosed), some of which may be initially weakly fluorescent, and undergo a chemical conversion, e.g. oxidation @rreduction, e.g. to quinone, under thermal contact, infrared or short wave U.V. and are reversible under U.V. and air or oxygen. Polycyclic aromatic hydrocarbons are formed by photochemical conversion of anhydrides or heating of the corresponding endoperoxides, e.g. 9,10-diphenylanthracene is prepared from 9,10-diphenyl-9,10- dihydro anthracene 9,10-anhydride. Other compounds prepared in examples include anthracene, diphenylphenylenenaphthacene 9,10-bis- (phenylethynyl) anthracene, 5,12-bis-(phenylethynyl) tetracene; 1,2,8,9 - dibenzpentacene. A hot die (e.g. keys, metal with raised letters) at 20‹ to 200‹ C. or higher may be applied and U.V. or infra-red input may be from lamps, arcs, or U.V. or infra-red lasers and the image may be by projecting a beam through a stencil, or by moving mirrors with lasers, specific examples being disclosed. A fluorescent material image formed from endoperoxide on paper was transferred to the substrate at higher conversion temperatures. Other combinations include polyethylmethacrylate containing a dibromo compound, plastic films containing DPA.O 2 (e.g. 40 mg./gm. of polymer) cast with various solvents on a microscope slide, e.g. PEMA, cellulose acetate butyrate, vinyl chloride-acetate copolymer, P.V.C., P.V.A., acrylite, and may include infra-red absorbers, such as charcoal, specific precursors being disclosed. The initial endoperoxide may be prepared by U.V. light in the presence of air or oxygen, with or without sensitizer, chemical synthesis or with active oxygen prepared by electrodeless discharge, other preparations being described (see Division C2). The amount of detectable fluorescence may be proportional to the input radiation, enabling tone variations to be achieved. Examples 1 to 26 disclose also conversions to fluorescent compounds by multistep chemical synthesis (e.g. Examples 3, 18, 19) and irradiation in solvents (e.g. Examples 1, 16, 19-22, 25) which are disclosed as not corresponding to the method of recording as claimed.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US76431168A | 1968-10-01 | 1968-10-01 | |
US76431268A | 1968-10-01 | 1968-10-01 | |
US76431368A | 1968-10-01 | 1968-10-01 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1298462A true GB1298462A (en) | 1972-12-06 |
Family
ID=27419588
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB48043/69A Expired GB1298462A (en) | 1968-10-01 | 1969-09-30 | Recording information by forming fluorescent material images |
Country Status (8)
Country | Link |
---|---|
JP (1) | JPS4943818B1 (en) |
BE (1) | BE739632A (en) |
CH (1) | CH552829A (en) |
DE (1) | DE1949605A1 (en) |
FR (1) | FR2019585A1 (en) |
GB (1) | GB1298462A (en) |
NL (1) | NL6914847A (en) |
SE (1) | SE361374B (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000048197A1 (en) * | 1999-02-12 | 2000-08-17 | Tri D Store Ip, L.L.C. | Electroluminescent multilayer optical information storage medium with integrated readout and composition of matter for use therein |
WO2004078874A2 (en) * | 2003-02-28 | 2004-09-16 | Polaroid Corporation | Novel dye complexes and use thereof in imaging members and methods |
US6819649B1 (en) | 1999-02-12 | 2004-11-16 | D Data Inc. | Electroluminescent multilayer optical information storage medium with integrated readout and compositions of matter for use therein |
US7704667B2 (en) | 2003-02-28 | 2010-04-27 | Zink Imaging, Inc. | Dyes and use thereof in imaging members and methods |
US7807607B2 (en) | 2006-05-12 | 2010-10-05 | Zink Imaging, Inc. | Color-forming compounds and use thereof in imaging members and methods |
US7825945B2 (en) | 2006-09-18 | 2010-11-02 | Zink Imaging, Inc. | Thermal printer with auxiliary heat sink and methods for printing using same |
US7829497B2 (en) | 2005-05-12 | 2010-11-09 | Zink Imaging, Inc. | Thermal imaging members and methods |
US8372782B2 (en) | 2003-02-28 | 2013-02-12 | Zink Imaging, Inc. | Imaging system |
CN114700631A (en) * | 2022-04-24 | 2022-07-05 | 上海大学 | Information encryption method of perovskite-polymer composite film and application thereof |
-
1969
- 1969-09-30 FR FR6933336A patent/FR2019585A1/fr not_active Withdrawn
- 1969-09-30 CH CH1473969A patent/CH552829A/en not_active IP Right Cessation
- 1969-09-30 GB GB48043/69A patent/GB1298462A/en not_active Expired
- 1969-09-30 SE SE13477/69A patent/SE361374B/xx unknown
- 1969-09-30 BE BE739632D patent/BE739632A/xx unknown
- 1969-10-01 NL NL6914847A patent/NL6914847A/xx not_active Application Discontinuation
- 1969-10-01 JP JP44078493A patent/JPS4943818B1/ja active Pending
- 1969-10-01 DE DE19691949605 patent/DE1949605A1/en active Pending
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6819649B1 (en) | 1999-02-12 | 2004-11-16 | D Data Inc. | Electroluminescent multilayer optical information storage medium with integrated readout and compositions of matter for use therein |
US6522616B1 (en) | 1999-02-12 | 2003-02-18 | Tridstore Ip Llc | Multilayer optical information storage medium based on incoherent signal |
US7406021B2 (en) | 1999-02-12 | 2008-07-29 | D Data Inc. | Electroluminescent multilayer optical information storage medium with integrated readout and composition of matter for use therein |
WO2000048197A1 (en) * | 1999-02-12 | 2000-08-17 | Tri D Store Ip, L.L.C. | Electroluminescent multilayer optical information storage medium with integrated readout and composition of matter for use therein |
US7116628B2 (en) | 1999-02-12 | 2006-10-03 | D Data Inc. | Electroluminescent multilayer optical information storage medium with integrated readout and composition of matter for use therein |
US7282317B2 (en) | 2003-02-28 | 2007-10-16 | Zink Imaging, Llc | Dye complexes and use thereof in imaging members and methods |
WO2004078874A3 (en) * | 2003-02-28 | 2004-11-04 | Polaroid Corp | Novel dye complexes and use thereof in imaging members and methods |
US7279264B2 (en) | 2003-02-28 | 2007-10-09 | Zink Imaging, Llc | Dyes and use thereof in thermal imaging members and methods |
WO2004078851A1 (en) * | 2003-02-28 | 2004-09-16 | Polaroid Corporation | Novel dyes and use thereof in thermal imaging members and methods |
WO2004078874A2 (en) * | 2003-02-28 | 2004-09-16 | Polaroid Corporation | Novel dye complexes and use thereof in imaging members and methods |
US7704667B2 (en) | 2003-02-28 | 2010-04-27 | Zink Imaging, Inc. | Dyes and use thereof in imaging members and methods |
US8372782B2 (en) | 2003-02-28 | 2013-02-12 | Zink Imaging, Inc. | Imaging system |
US7829497B2 (en) | 2005-05-12 | 2010-11-09 | Zink Imaging, Inc. | Thermal imaging members and methods |
US8722574B2 (en) | 2005-05-12 | 2014-05-13 | Zink Imaging, Inc. | Thermal imaging members and methods |
US7807607B2 (en) | 2006-05-12 | 2010-10-05 | Zink Imaging, Inc. | Color-forming compounds and use thereof in imaging members and methods |
US7825945B2 (en) | 2006-09-18 | 2010-11-02 | Zink Imaging, Inc. | Thermal printer with auxiliary heat sink and methods for printing using same |
CN114700631A (en) * | 2022-04-24 | 2022-07-05 | 上海大学 | Information encryption method of perovskite-polymer composite film and application thereof |
Also Published As
Publication number | Publication date |
---|---|
DE1949605A1 (en) | 1970-04-30 |
SE361374B (en) | 1973-10-29 |
NL6914847A (en) | 1970-04-03 |
BE739632A (en) | 1970-03-31 |
JPS4943818B1 (en) | 1974-11-25 |
FR2019585A1 (en) | 1970-07-03 |
CH552829A (en) | 1974-08-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |