GB1292839A - Improvements in and relating to selective separation of metals by pyrolysis - Google Patents

Improvements in and relating to selective separation of metals by pyrolysis

Info

Publication number
GB1292839A
GB1292839A GB58114/69A GB5811469A GB1292839A GB 1292839 A GB1292839 A GB 1292839A GB 58114/69 A GB58114/69 A GB 58114/69A GB 5811469 A GB5811469 A GB 5811469A GB 1292839 A GB1292839 A GB 1292839A
Authority
GB
United Kingdom
Prior art keywords
solution
recovered
anions
separated
metals
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB58114/69A
Inventor
Andreas Hake
Edouard Debie
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ruthner Industrieplannungs AG
METTALURGIE HOBOKEN
Original Assignee
Ruthner Industrieplannungs AG
METTALURGIE HOBOKEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ruthner Industrieplannungs AG, METTALURGIE HOBOKEN filed Critical Ruthner Industrieplannungs AG
Priority to GB58114/69A priority Critical patent/GB1292839A/en
Priority to DE19691963198 priority patent/DE1963198B2/en
Publication of GB1292839A publication Critical patent/GB1292839A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/14Methods for preparing oxides or hydroxides in general
    • C01B13/34Methods for preparing oxides or hydroxides in general by oxidation or hydrolysis of sprayed or atomised solutions
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22BPRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/22Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Abstract

1292839 Pyrolytic separation of metal values RUTHNER INDUSTRIEPLANUNGS AG and METALLURGIE HOBOKEN 27 Nov 1969 58114/69 Headings C1A and C1N Metal values in solution are separated pyrolytically by atomizing and spraying the solution which has been treated to convert ions in a lower valency state to a higher valency state, in cocurrent with a gas into a heated reactor to dehydrate the solution and pyrolyse the solute, whereby the temperature of the reactor is selected so as to render some of the anions insoluble whilst the others remain soluble and are extracted by leaching. The preferred anions are Cl-, NO 3 -, and SO 4 --. In the case of Clthe reaction is carried out at 2-400‹ C. and the Clis recovered as HCl; with NO 3 - the reaction temperature is 125-150‹ C. and the NO 3 - is recovered as HNO 3 and with SO 4 -- anions the reaction temperature is 600-650‹ C. and the SO 4 -- is recovered as H 2 SO 4 . The cations should be in their higher valency states before separation and this may be achieved by oxidizing the solution with Cl 2 , O 2 or air. Metals whose compounds are pyrolysed are Fe, Cr, Al, As, Sb, Sn, Mo, W, Ti, Ta and Nb, and may be separated from Ni, Co, Cu, Mn, Zn, Ca, Pb and Mg, whose compounds remain soluble.
GB58114/69A 1969-11-27 1969-11-27 Improvements in and relating to selective separation of metals by pyrolysis Expired GB1292839A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB58114/69A GB1292839A (en) 1969-11-27 1969-11-27 Improvements in and relating to selective separation of metals by pyrolysis
DE19691963198 DE1963198B2 (en) 1969-11-27 1969-12-17 PROCESS FOR SEPARATING DIVALENT CATIONS OF NI, CO, CU, MN, ZN, PB, CA AND / OR MG FROM HIGH VALUE CATIONS OF FE, CR, AL, AS, TI, SB, SN, MO, W, TA AND / OR NB FROM CHLORIDE SOLUTIONS

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB58114/69A GB1292839A (en) 1969-11-27 1969-11-27 Improvements in and relating to selective separation of metals by pyrolysis
DE19691963198 DE1963198B2 (en) 1969-11-27 1969-12-17 PROCESS FOR SEPARATING DIVALENT CATIONS OF NI, CO, CU, MN, ZN, PB, CA AND / OR MG FROM HIGH VALUE CATIONS OF FE, CR, AL, AS, TI, SB, SN, MO, W, TA AND / OR NB FROM CHLORIDE SOLUTIONS

Publications (1)

Publication Number Publication Date
GB1292839A true GB1292839A (en) 1972-10-11

Family

ID=25758252

Family Applications (1)

Application Number Title Priority Date Filing Date
GB58114/69A Expired GB1292839A (en) 1969-11-27 1969-11-27 Improvements in and relating to selective separation of metals by pyrolysis

Country Status (2)

Country Link
DE (1) DE1963198B2 (en)
GB (1) GB1292839A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5036037A (en) * 1989-05-09 1991-07-30 Maschinenfabrik Andritz Aktiengesellschaft Process of making catalysts and catalysts made by the process

Also Published As

Publication number Publication date
DE1963198B2 (en) 1976-11-11
DE1963198A1 (en) 1971-06-24

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Legal Events

Date Code Title Description
PS Patent sealed