GB1292839A - Improvements in and relating to selective separation of metals by pyrolysis - Google Patents
Improvements in and relating to selective separation of metals by pyrolysisInfo
- Publication number
- GB1292839A GB1292839A GB58114/69A GB5811469A GB1292839A GB 1292839 A GB1292839 A GB 1292839A GB 58114/69 A GB58114/69 A GB 58114/69A GB 5811469 A GB5811469 A GB 5811469A GB 1292839 A GB1292839 A GB 1292839A
- Authority
- GB
- United Kingdom
- Prior art keywords
- solution
- recovered
- anions
- separated
- metals
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/14—Methods for preparing oxides or hydroxides in general
- C01B13/34—Methods for preparing oxides or hydroxides in general by oxidation or hydrolysis of sprayed or atomised solutions
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/22—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Abstract
1292839 Pyrolytic separation of metal values RUTHNER INDUSTRIEPLANUNGS AG and METALLURGIE HOBOKEN 27 Nov 1969 58114/69 Headings C1A and C1N Metal values in solution are separated pyrolytically by atomizing and spraying the solution which has been treated to convert ions in a lower valency state to a higher valency state, in cocurrent with a gas into a heated reactor to dehydrate the solution and pyrolyse the solute, whereby the temperature of the reactor is selected so as to render some of the anions insoluble whilst the others remain soluble and are extracted by leaching. The preferred anions are Cl-, NO 3 -, and SO 4 --. In the case of Clthe reaction is carried out at 2-400‹ C. and the Clis recovered as HCl; with NO 3 - the reaction temperature is 125-150‹ C. and the NO 3 - is recovered as HNO 3 and with SO 4 -- anions the reaction temperature is 600-650‹ C. and the SO 4 -- is recovered as H 2 SO 4 . The cations should be in their higher valency states before separation and this may be achieved by oxidizing the solution with Cl 2 , O 2 or air. Metals whose compounds are pyrolysed are Fe, Cr, Al, As, Sb, Sn, Mo, W, Ti, Ta and Nb, and may be separated from Ni, Co, Cu, Mn, Zn, Ca, Pb and Mg, whose compounds remain soluble.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB58114/69A GB1292839A (en) | 1969-11-27 | 1969-11-27 | Improvements in and relating to selective separation of metals by pyrolysis |
DE19691963198 DE1963198B2 (en) | 1969-11-27 | 1969-12-17 | PROCESS FOR SEPARATING DIVALENT CATIONS OF NI, CO, CU, MN, ZN, PB, CA AND / OR MG FROM HIGH VALUE CATIONS OF FE, CR, AL, AS, TI, SB, SN, MO, W, TA AND / OR NB FROM CHLORIDE SOLUTIONS |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB58114/69A GB1292839A (en) | 1969-11-27 | 1969-11-27 | Improvements in and relating to selective separation of metals by pyrolysis |
DE19691963198 DE1963198B2 (en) | 1969-11-27 | 1969-12-17 | PROCESS FOR SEPARATING DIVALENT CATIONS OF NI, CO, CU, MN, ZN, PB, CA AND / OR MG FROM HIGH VALUE CATIONS OF FE, CR, AL, AS, TI, SB, SN, MO, W, TA AND / OR NB FROM CHLORIDE SOLUTIONS |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1292839A true GB1292839A (en) | 1972-10-11 |
Family
ID=25758252
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB58114/69A Expired GB1292839A (en) | 1969-11-27 | 1969-11-27 | Improvements in and relating to selective separation of metals by pyrolysis |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE1963198B2 (en) |
GB (1) | GB1292839A (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5036037A (en) * | 1989-05-09 | 1991-07-30 | Maschinenfabrik Andritz Aktiengesellschaft | Process of making catalysts and catalysts made by the process |
-
1969
- 1969-11-27 GB GB58114/69A patent/GB1292839A/en not_active Expired
- 1969-12-17 DE DE19691963198 patent/DE1963198B2/en active Granted
Also Published As
Publication number | Publication date |
---|---|
DE1963198B2 (en) | 1976-11-11 |
DE1963198A1 (en) | 1971-06-24 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed |