GB1281301A - Fire retardant, polyurethane foam compositions - Google Patents
Fire retardant, polyurethane foam compositionsInfo
- Publication number
- GB1281301A GB1281301A GB54161/70A GB5416170A GB1281301A GB 1281301 A GB1281301 A GB 1281301A GB 54161/70 A GB54161/70 A GB 54161/70A GB 5416170 A GB5416170 A GB 5416170A GB 1281301 A GB1281301 A GB 1281301A
- Authority
- GB
- United Kingdom
- Prior art keywords
- mixture
- tris
- fire retardant
- phosphate
- foam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0014—Use of organic additives
- C08J9/0038—Use of organic additives containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/487—Polyethers containing cyclic groups
- C08G18/4883—Polyethers containing cyclic groups containing cyclic groups having at least one oxygen atom in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0025—Foam properties rigid
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0033—Foam properties having integral skins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/0058—≥50 and <150kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/0066—≥ 150kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
1281301 Fire retardant rigid polyurethane foams CINCINNATI MILACRON Inc 13 Nov 1970 [13 Nov 1969] 54161/70 Headings C3C and C3R Fire retardant rigid polyurethane foams are prepared by reacting a composition comprising (1) an isocyanate terminated adduct obtained by reacting an aromatic polyisocyanate with a difunctional organic compound, (2) at least one polyether polyol having a functionality of at least 4 and which is the reaction product of an alkylene oxide with an alkyl, aryl, aralkyl, cycloalkyl and/or heterocyclic compound, (3) at least one organic compound having a M.W. of at least 500 which does not contain zerewitinoff active H atoms and which contains halogen and/or phosphorus atoms, at least one halogen atom being a bromine atom, or a mixture of halogen and/or phosphorus containing organic compounds, the mixture having an average M.W. of at least 500, which does not contain zerewitinoff active hydrogen atoms and comprising at least one bromine containing compound and (4) a blowing agent. The reaction may also take place in the presence of a urethane polymerization catalyst and/or a surfactant. The difunctional organic compound used to form the component (1) is suitably a polyether diol. Typical compounds (3) which may be used either alone or in specific combinations are tris-(2,3- dibromopropyl)phosphate, a commercial chloroethyl ester of phosphorous acid, tris(1-bromo, 3- chloroisopropyl)phosphate and hexabromocyclododecane. The reaction suitably takes place in a closed mould using an amount of foam-forming components at least twice that which would be required to completely fill the mould cavity if the foam was allowed to freeblow. In a typical example a prepolymer is prepared from polymethylene polyphenyl isocyanate and a polyoxypropylene diol and mixed with a chloroethyl ester of phosphorous acid, the mixture being mixed with a polyol blend comprising tris(2,3- dibromopropyl)phosphate, poly(oxypropylated α-methyl glycoside-glycerol mixture, N,N,N<SP>1</SP>,N<SP>1</SP>-tetramethyl-1,3-butane diamine. The diacetate salt of N,N,N<SP>1</SP>,N<SP>1</SP>-tetramethyl- 1,3-butane diamine, a dimethyl silicone-alkylene oxide copolymer, monofluorotrichloromethane and dichlorodifluoromethane to form a rigid foam.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US87660169A | 1969-11-13 | 1969-11-13 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1281301A true GB1281301A (en) | 1972-07-12 |
Family
ID=25368115
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB54161/70A Expired GB1281301A (en) | 1969-11-13 | 1970-11-13 | Fire retardant, polyurethane foam compositions |
Country Status (5)
Country | Link |
---|---|
DE (1) | DE2055041A1 (en) |
FR (1) | FR2069356A5 (en) |
GB (1) | GB1281301A (en) |
NL (1) | NL7016528A (en) |
ZA (1) | ZA707687B (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4019306A1 (en) * | 1990-06-16 | 1991-12-19 | Bayer Ag | METHOD FOR THE PRODUCTION OF URETHANE, UREA AND BIURET GROUPS IN THE ESSENTIAL CLOSED CELLS WITH EXCELLENT ADHESION TO SOLID SURFACES AND THE USE THEREOF |
-
1970
- 1970-11-09 DE DE19702055041 patent/DE2055041A1/en active Pending
- 1970-11-11 NL NL7016528A patent/NL7016528A/xx unknown
- 1970-11-13 GB GB54161/70A patent/GB1281301A/en not_active Expired
- 1970-11-13 ZA ZA707687A patent/ZA707687B/en unknown
- 1970-11-13 FR FR7040689A patent/FR2069356A5/fr not_active Expired
Also Published As
Publication number | Publication date |
---|---|
ZA707687B (en) | 1971-09-29 |
DE2055041A1 (en) | 1971-05-27 |
NL7016528A (en) | 1971-05-17 |
FR2069356A5 (en) | 1971-09-03 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
429A | Application made for amendment of specification (sect. 29/1949) | ||
429H | Application (made) for amendment of specification now open to opposition (sect. 29/1949) | ||
429D | Case decided by the comptroller ** specification amended (sect. 29/1949) | ||
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |