GB1278806A - Improvements in and relating to the production of octadienes - Google Patents

Improvements in and relating to the production of octadienes

Info

Publication number
GB1278806A
GB1278806A GB5115169A GB5115169A GB1278806A GB 1278806 A GB1278806 A GB 1278806A GB 5115169 A GB5115169 A GB 5115169A GB 5115169 A GB5115169 A GB 5115169A GB 1278806 A GB1278806 A GB 1278806A
Authority
GB
United Kingdom
Prior art keywords
octadienes
octadiene
solvent
butadiene
oct
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5115169A
Inventor
Donald Wright
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB5115169A priority Critical patent/GB1278806A/en
Priority to US00079323A priority patent/US3732328A/en
Priority to DE19702050774 priority patent/DE2050774A1/en
Priority to FR7037502A priority patent/FR2066111A1/fr
Priority to JP45091550A priority patent/JPS508043B1/ja
Publication of GB1278806A publication Critical patent/GB1278806A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/74—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition with simultaneous hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/128—Compounds comprising a halogen and an iron group metal or a platinum group metal
    • C07C2527/13—Platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1278806 Octadienes IMPERIAL CHEMICAL INDUSTRIES Ltd 5 Oct 1970 [17 Oct 1969 28 April 1970 27 July 1970] 51151/69 20368/70 and 36198/70 Heading C5E 1,6- and/or 1,7-octadienes are prepared by contacting one or more acylic conjugated diolefins with Pt, Pd, Rh, Ru, Os or a compound thereof in a polar solvent in the presence of a reducing agent. The reaction, presumably a dimerization and selective hydrogenation, may be effected at 20-200‹ C. The reducing agent may be gaseous H 2 but is preferably a liquid miscible with the solvent such as hydrazine, formaldehyde, a lower alcohol or, preferably, formic acid. Suitable catalysts are the chlorides, carboxylates and complexes of Pt and Pd. The preferred solvent is DMF. Examples describe the preparation of 1,6- and 1,7-octadiene from butadiene; 3,7-dimethyl octadiene-1,6 from isoprene; and 3-methyl octadiene-1,6 from a mixture of butadiene and isoprene Vinyl cyclohexane is formed as a by-product in some of the examples. When effected in a stainless steel reactor a copper salt or a phosphine may be added as catalyst promoter.
GB5115169A 1969-10-17 1969-10-17 Improvements in and relating to the production of octadienes Expired GB1278806A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
GB5115169A GB1278806A (en) 1969-10-17 1969-10-17 Improvements in and relating to the production of octadienes
US00079323A US3732328A (en) 1969-10-17 1970-10-08 Process for the production of octadienes
DE19702050774 DE2050774A1 (en) 1969-10-17 1970-10-15 Process for the production of olefins
FR7037502A FR2066111A1 (en) 1969-10-17 1970-10-16
JP45091550A JPS508043B1 (en) 1969-10-17 1970-10-17

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB5115169A GB1278806A (en) 1969-10-17 1969-10-17 Improvements in and relating to the production of octadienes

Publications (1)

Publication Number Publication Date
GB1278806A true GB1278806A (en) 1972-06-21

Family

ID=10458855

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5115169A Expired GB1278806A (en) 1969-10-17 1969-10-17 Improvements in and relating to the production of octadienes

Country Status (1)

Country Link
GB (1) GB1278806A (en)

Similar Documents

Publication Publication Date Title
Halpern Oxidative-addition reactions of transition metal complexes
DE2034908C2 (en) Adduct of a ruthenium (II) carboxylate and a stabilizing donor ligand
Stern Reactions of Unsaturated Ligands in Pd (II) Complexes
Bruner et al. Heterogeneous selective catalysis of the hydrogenation of olefins by polymeric palladium (II) and platinum (II) complexes
JPH09937A (en) Novel catalyst composition based on transition metal complexand hydrogenation method for unsaturated compound
Brown et al. Reaction of sodium borohydride with platinum metal salts in the presence of decolorizing carbon-a supported platinum catalyst of markedly enhanced activity for hydrogenations
US3857900A (en) Hydrogenation of aldehydes using triarylphosphine rhodium halogenoid catalysts
GB1344887A (en) Production of olefines
JPS6111145A (en) Hydrogenation catalyst of diolefins
US3274286A (en) Process for the removal of acetylenic hydrocarbons from hydrocarbon mixtures containing diolefines
GB1278806A (en) Improvements in and relating to the production of octadienes
GB1491898A (en) Catalyst for hydrogenation isomerization and hydrosilylation of alkenes and a method of preparation of the catalyst
GB1478232A (en) Selective hydrogenation of cyclopentadiene
US3488400A (en) Hydrogenation process
GB1139210A (en) Preparation of unsaturated organic esters
Nakamura et al. Homogeneous hydrogenation of alkenes by the complex of polyacrylic acid with rhodium (III)
Takagi et al. The hydroxide-blacks of ruthenium and rhodium as catalysts for the hydrogenation of organic compounds. I. Their catalytic activity and selectivity in the hydrogenation of some aromatic compounds
DE1800371A1 (en) Process for carrying out organic reactions catalyzed by a heterogeneous catalyst
IE38478L (en) Hydrogenation of diolefinic hydrocarbons
ES424370A1 (en) Process for purifying butadiene and isoprene by selective hydrogenation of the acetylenic impurities contained therein
GB871401A (en) A process for the preparation of polybutadienes and catalysts therefor
Gullotti et al. Homogeneous catalysis by transition-metal complexes. Part II. An investigation of the hydrogen-transfer reaction catalysed by the henbest system
EP0042097B1 (en) Process for the reactivation of support catalysts that contain palladium or platinum, copper and tellurium
Nakamura et al. HYDROGENATION OF ALKENES BY THE COMPLEX OF CROSS-LINKED POLYACRYLIC ACID WITH RHODIUM (111)
GB1515401A (en) Manufacture of hydroquinone

Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees