GB1272572A - Process for polymerising lactones - Google Patents

Process for polymerising lactones

Info

Publication number
GB1272572A
GB1272572A GB1381368A GB1381368A GB1272572A GB 1272572 A GB1272572 A GB 1272572A GB 1381368 A GB1381368 A GB 1381368A GB 1381368 A GB1381368 A GB 1381368A GB 1272572 A GB1272572 A GB 1272572A
Authority
GB
United Kingdom
Prior art keywords
clay
catalyst
lactones
chain initiator
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1381368A
Inventor
Victor Frederick Jenkins
David Frederick Jenkins
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik LCL Ltd
Original Assignee
Laporte Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Laporte Chemicals Ltd filed Critical Laporte Chemicals Ltd
Priority to GB1381368A priority Critical patent/GB1272572A/en
Publication of GB1272572A publication Critical patent/GB1272572A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/823—Preparation processes characterised by the catalyst used for the preparation of polylactones or polylactides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4266—Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from hydroxycarboxylic acids and/or lactones
    • C08G18/4269—Lactones

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

1,272,572. Polymerizing lactones. LAPORTE CHEMICALS Ltd. 23 June, 1969 [21 March, 1968], No. 13813/69. Addition to 1,210,496. Heading C3R. A polyester is produced by reacting at least one lactone of the Formula I where each R, which may be the same or different, is methyl, ethyl, n-propyl, isopropyl, hydrogen, chlorine or bromine, provided that the total number of carbon atoms in the (CR 2 ) n-1 group does not exceed 12 and that the (CR 2 ) n-1 group contains not more than 2 halogen atoms, and n is an integer from 5 to 12, with a chain initiator, in the presence of an acidactivated clay mineral as catalyst. Preferably n is 5, 6 or 7. The chain initiator may be an alcohol, a mono- or dialkylamine or an aminoalcohol. The catalyst may be derived from a montmorillonite clay having calcium, sodium or magnesium in base exchange positions, or from illite, a clay of the kaoline family or attapulgite. Reference has been directed by the Comptroller to Specification 859,642.
GB1381368A 1968-03-21 1968-03-21 Process for polymerising lactones Expired GB1272572A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB1381368A GB1272572A (en) 1968-03-21 1968-03-21 Process for polymerising lactones

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB1381368A GB1272572A (en) 1968-03-21 1968-03-21 Process for polymerising lactones

Publications (1)

Publication Number Publication Date
GB1272572A true GB1272572A (en) 1972-05-03

Family

ID=10029858

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1381368A Expired GB1272572A (en) 1968-03-21 1968-03-21 Process for polymerising lactones

Country Status (1)

Country Link
GB (1) GB1272572A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58219224A (en) * 1982-06-09 1983-12-20 バスフ　アクチエンゲゼルシヤフト Manufacture of polycaprolactone
EP0962470A1 (en) * 1998-06-01 1999-12-08 Nippon Shokubai Co., Ltd. Production process for polyvinyl ether and catalyst used for the process
WO2006069128A1 (en) * 2004-12-22 2006-06-29 E. I. Du Pont De Nemours And Company Compositions of polyesters and sepiolite-type clays

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS58219224A (en) * 1982-06-09 1983-12-20 バスフ　アクチエンゲゼルシヤフト Manufacture of polycaprolactone
EP0096321A2 (en) * 1982-06-09 1983-12-21 BASF Aktiengesellschaft Process for preparing polycaprolactone
US4464526A (en) * 1982-06-09 1984-08-07 Basf Aktiengesellschaft Preparation of polycaprolactone
EP0096321A3 (en) * 1982-06-09 1986-09-03 Basf Aktiengesellschaft Process for preparing polycaprolactone
JPH0368891B2 (en) * 1982-06-09 1991-10-30 Basf Ag
EP0962470A1 (en) * 1998-06-01 1999-12-08 Nippon Shokubai Co., Ltd. Production process for polyvinyl ether and catalyst used for the process
US6235859B1 (en) 1998-06-01 2001-05-22 Nippon Shokubah Co Ltd Production process for polyvinyl ether and catalyst used for the process
WO2006069128A1 (en) * 2004-12-22 2006-06-29 E. I. Du Pont De Nemours And Company Compositions of polyesters and sepiolite-type clays

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Legal Events

Date Code Title Description
PS Patent sealed
PLNP Patent lapsed through nonpayment of renewal fees