GB1271105A - Improvements in and relating to the production of polycyclic hydrocarbons - Google Patents

Improvements in and relating to the production of polycyclic hydrocarbons

Info

Publication number
GB1271105A
GB1271105A GB36829/69A GB3682969A GB1271105A GB 1271105 A GB1271105 A GB 1271105A GB 36829/69 A GB36829/69 A GB 36829/69A GB 3682969 A GB3682969 A GB 3682969A GB 1271105 A GB1271105 A GB 1271105A
Authority
GB
United Kingdom
Prior art keywords
reacted
acetate
formula
polycyclic hydrocarbons
cyclopentadiene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB36829/69A
Inventor
Richard Gregory Foster
David Richard Joy
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to AU14492/70A priority Critical patent/AU1449270A/en
Priority to BE749762D priority patent/BE749762A/en
Priority to US35276A priority patent/US3642923A/en
Priority to FR7016812A priority patent/FR2047489A5/fr
Priority to CA082,317A priority patent/CA940540A/en
Priority to DE19702022550 priority patent/DE2022550B2/en
Priority to NL7006738A priority patent/NL7006738A/xx
Priority to JP45039232A priority patent/JPS4945864B1/ja
Publication of GB1271105A publication Critical patent/GB1271105A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/62—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with more than three condensed rings
    • C07C13/64—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with more than three condensed rings with a bridged ring system
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/207—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds
    • C07C1/2078—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds by a transformation in which at least one -C(=O)-O- moiety is eliminated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/26—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/26—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms
    • C07C1/30—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms by splitting-off the elements of hydrogen halide from a single molecule
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C13/00—Cyclic hydrocarbons containing rings other than, or in addition to, six-membered aromatic rings
    • C07C13/28—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof
    • C07C13/32—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings
    • C07C13/54—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings
    • C07C13/605—Polycyclic hydrocarbons or acyclic hydrocarbon derivatives thereof with condensed rings with three condensed rings with a bridged ring system
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/50—Diels-Alder conversion
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/08—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/56—Ring systems containing bridged rings
    • C07C2603/58—Ring systems containing bridged rings containing three rings
    • C07C2603/60—Ring systems containing bridged rings containing three rings containing at least one ring with less than six members
    • C07C2603/66—Ring systems containing bridged rings containing three rings containing at least one ring with less than six members containing five-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2603/00—Systems containing at least three condensed rings
    • C07C2603/56—Ring systems containing bridged rings
    • C07C2603/90—Ring systems containing bridged rings containing more than four rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1,271,105. Substituted polycyclic hydrocarbons. IMPERIAL CHEMICAL INDUSTRIES Ltd. 17 April, 1970 [9 May, 1969; 22 July, 1969], Nos. 23778/69 and 23779/69. Heading C2C. [Also in Division C5] A process for making polycyclic hydrocarbons involving intermediates having a basic formula where n = 0 or a whole number produced by an addition reaction between cyclopentadiene and (a) a norbornene of formula (b) an acyclic substituted olefin of formula X-C=C-X<SP>1</SP> where X, X<SP>1</SP> may be the same or different, i.e. H, halogen, OH, acetate, carbonyl, carried out preferably at elevated temperature and pressure, possibly using a catalyst comprising a strong acid, nitrogenous base, transition metal or a complex thereof particularly a rhodium complex. In the examples given: (a) vinyl chloride or acetate is reacted with cyclopentadiene giving norborneyl chloride or acetate which is reacted with isoprene, butadiene, 2,3-dimethylbutadiene, or piperylene to yield intermediates from which HCl or acetic acid can be eliminated to give a polycyclic hydrocarbon. In another example vinyl chloride is reacted with dicyclopentadiene to yield an intermediate containing two 1:4-methylene bridges. Examples are given wherein n = 0, 1 or 2 and X is halogen.
GB36829/69A 1969-05-09 1969-07-22 Improvements in and relating to the production of polycyclic hydrocarbons Expired GB1271105A (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
AU14492/70A AU1449270A (en) 1969-05-09 1970-04-29 Improvements in and relating tothe production of polycyclic hydrocarbons
BE749762D BE749762A (en) 1969-05-09 1970-04-29 POLYCYCLIC HYDROCARBONS PRODUCTION
US35276A US3642923A (en) 1969-05-09 1970-05-06 Production of polycyclic hydrocarbons
FR7016812A FR2047489A5 (en) 1969-05-09 1970-05-08
CA082,317A CA940540A (en) 1969-05-09 1970-05-08 Production of polycyclic hydrocarbons
DE19702022550 DE2022550B2 (en) 1969-05-09 1970-05-08 PROCESS FOR THE PRODUCTION OF POLYCYCLIC HYDROCARBONS
NL7006738A NL7006738A (en) 1969-05-09 1970-05-08
JP45039232A JPS4945864B1 (en) 1969-05-09 1970-05-09

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2377869 1969-05-09

Publications (1)

Publication Number Publication Date
GB1271105A true GB1271105A (en) 1972-04-19

Family

ID=10201174

Family Applications (1)

Application Number Title Priority Date Filing Date
GB36829/69A Expired GB1271105A (en) 1969-05-09 1969-07-22 Improvements in and relating to the production of polycyclic hydrocarbons

Country Status (1)

Country Link
GB (1) GB1271105A (en)

Similar Documents

Publication Publication Date Title
IE41690L (en) Benzothiazine-1,1-dioxide derivatives.
GB1271105A (en) Improvements in and relating to the production of polycyclic hydrocarbons
GB1453906A (en) 3-deoxyglucose derivatives
GB1339457A (en) Chelated sodium compounds and process of preparing them
Larock et al. Mercury in organic chemistry. 27. π-allylpalladium synthesis via organopalladium additions to nonconjugated dienes
GB1498456A (en) Electrochemical process for the preparation of dihaloalkenes
ES424370A1 (en) Process for purifying butadiene and isoprene by selective hydrogenation of the acetylenic impurities contained therein
GB1492257A (en) Hydrogenation of styrene oxide to produce 2-phenylethanol
GB1442946A (en) Cobalt complex and its use in the catalytic hydrogenation of rubbers
GB1326454A (en) Process for the production of unsaturated organic compounds
GB1427902A (en) Process for the preparation of 1,3-dichloro-butene-2
Shirafuji et al. The oxidative ring cleavage of 1, 3, 3-trimethylcyclopropene by transition metal acetates
IE38692L (en) Process for the preparation of alkyl-sulphonate compounds.
GB1283832A (en) Preparation of mercaptans
GB1336860A (en) Process for the preparation of cyclopropyl-methyl-n-alkylamines
GB1324785A (en) Process for hydrogenating sulpholenes to sulpholanes
GB1245593A (en) Formaldehyde production
GB1328074A (en) Process for the production of primary amines
US3265758A (en) Low molecular weight polymers
US2533939A (en) Acetic acid esters of aralkyl alcohols and method for their production
GB1368545A (en) Preparation of dihydrocoumarin and of alkyl derivatives thereof
GB1519476A (en) Process for producing ethylene-propylene-butadiene terpolymers
GB1277157A (en) Production of carboxylic acids
GB1467990A (en) Continuous manufacture of n-alkylated arylamines
GB1398314A (en) Process for the manufacture of hexahydroindane-4-carboxylic acid derivatives