GB1267416A - Hydrotreating catalyst and process - Google Patents

Hydrotreating catalyst and process

Info

Publication number
GB1267416A
GB1267416A GB3898669A GB3898669A GB1267416A GB 1267416 A GB1267416 A GB 1267416A GB 3898669 A GB3898669 A GB 3898669A GB 3898669 A GB3898669 A GB 3898669A GB 1267416 A GB1267416 A GB 1267416A
Authority
GB
United Kingdom
Prior art keywords
metals
aug
lattice
component
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3898669A
Inventor
Joseph Jaffe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chevron USA Inc
Original Assignee
Chevron Research and Technology Co
Chevron Research Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chevron Research and Technology Co, Chevron Research Co filed Critical Chevron Research and Technology Co
Publication of GB1267416A publication Critical patent/GB1267416A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
    • C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/049—Pillared clays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/12—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles

Abstract

1,267,416. Conversion catalyst. CHEVRON RESEARCH CO. 4 Aug., 1969 [5 Aug., 1968; 14 Aug., 1968; 18 Sept., 1968], No. 38986/69. Heading B1E. [Also in Division C5] A catalyst composition comprises (i) a crystalline zeolitic molecular sieve component, (ii) a layered synthetic crystalline aluminosilicate component having, when in the hydrated form, the formula wherein: n is 2.4-3.0; m is 0.2-0.6; A is one equivalent of an exchangeable cation having a valence of not more than 2, and is external to the lattice, e.g. H<SP>+</SP>, NH 4 <SP>+</SP>, Na<SP>+</SP>, Li<SP>+</SP>, K<SP>+</SP>, ¢Ca<SP>2+</SP>, ¢Mg<SP>2+</SP>, ¢Sr<SP>2+</SP>, or ¢Bn<SP>2+</SP>; B is F-, OH- or ¢O<SP>2-</SP> and is internal to the lattice; and x is 2.0 to 3.5 at 50% relative humidity; the mineral having specified lattice parameters, and (iii) at least one hydrogenating component selected from Re, Gp VIII, e.g. metals Ni, Co, Pt, Pd and compounds thereof, and mixtures of Gp. VIII and Gp. VI metals, e.g. W, or compounds. The layered aluminosilicate which may be in the hydrated or dehydrated form, is suitably free of any catalytic loading metals, i.e. is in the hydrogen or ammonia form, and may be dispersed in particulate form in a matrix of a siliceous gel and the hydrogenating component. The composite may also contain (a) 0.1-10% wt. combined fluorine, (b) Ti, Hf, Zr or Th or a mixture thereof, in the form of the metals, oxides or sulphides, and (c) tin or a compound thereof. The catalyst may be sulphided before use.
GB3898669A 1968-08-05 1969-08-04 Hydrotreating catalyst and process Expired GB1267416A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US75028368A 1968-08-05 1968-08-05
US75258868A 1968-08-14 1968-08-14
US76051368A 1968-09-18 1968-09-18

Publications (1)

Publication Number Publication Date
GB1267416A true GB1267416A (en) 1972-03-22

Family

ID=27419400

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3898669A Expired GB1267416A (en) 1968-08-05 1969-08-04 Hydrotreating catalyst and process

Country Status (1)

Country Link
GB (1) GB1267416A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020033483A1 (en) * 2018-08-07 2020-02-13 Chevron U.S.A. Inc. A catalytic remedy for advanced uco bleed reduction in recycle hydrocracking operations
US10968405B2 (en) 2018-08-07 2021-04-06 Chevron U.S.A. Inc. Catalytic remedy for advanced UCO bleed reduction in recycle hydrocracking operations

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2020033483A1 (en) * 2018-08-07 2020-02-13 Chevron U.S.A. Inc. A catalytic remedy for advanced uco bleed reduction in recycle hydrocracking operations
US10968405B2 (en) 2018-08-07 2021-04-06 Chevron U.S.A. Inc. Catalytic remedy for advanced UCO bleed reduction in recycle hydrocracking operations
US11041128B2 (en) 2018-08-07 2021-06-22 Chevron U.S.A. Inc. Catalytic remedy for advanced UCO bleed reduction in recycle hydrocracking operations

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