GB1259950A - Novel acetoacetates - Google Patents
Novel acetoacetatesInfo
- Publication number
- GB1259950A GB1259950A GB42884/69A GB4288469A GB1259950A GB 1259950 A GB1259950 A GB 1259950A GB 42884/69 A GB42884/69 A GB 42884/69A GB 4288469 A GB4288469 A GB 4288469A GB 1259950 A GB1259950 A GB 1259950A
- Authority
- GB
- United Kingdom
- Prior art keywords
- prepared
- nonodien
- acetoacetate
- acetoacetates
- dimethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000004729 acetoacetic acid derivatives Chemical class 0.000 title abstract 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 3
- WDJHALXBUFZDSR-UHFFFAOYSA-M acetoacetate Chemical compound CC(=O)CC([O-])=O WDJHALXBUFZDSR-UHFFFAOYSA-M 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- WASQWSOJHCZDFK-UHFFFAOYSA-N diketene Chemical compound C=C1CC(=O)O1 WASQWSOJHCZDFK-UHFFFAOYSA-N 0.000 abstract 2
- OJXKWJPEGDDDHH-CSKARUKUSA-N (e)-3,7-dimethylnon-6-en-1-yn-3-ol Chemical compound CC\C(C)=C\CCC(C)(O)C#C OJXKWJPEGDDDHH-CSKARUKUSA-N 0.000 abstract 1
- SAXWRVSDVXCTEL-SOFGYWHQSA-N (e)-6-methyloct-5-en-2-one Chemical compound CC\C(C)=C\CCC(C)=O SAXWRVSDVXCTEL-SOFGYWHQSA-N 0.000 abstract 1
- HFYAEUXHCMTPOL-UHFFFAOYSA-N 3-Methyl-1-penten-3-ol Chemical compound CCC(C)(O)C=C HFYAEUXHCMTPOL-UHFFFAOYSA-N 0.000 abstract 1
- WDJHALXBUFZDSR-UHFFFAOYSA-N Acetoacetic acid Natural products CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 abstract 1
- -1 acetoacetic acid ester Chemical class 0.000 abstract 1
- 230000002378 acidificating effect Effects 0.000 abstract 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 abstract 1
- 229940093858 ethyl acetoacetate Drugs 0.000 abstract 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/38—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
- C07D303/40—Compounds containing oxirane rings with hydrocarbon radicals, substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals by ester radicals
- C07D303/42—Acyclic compounds having a chain of seven or more carbon atoms, e.g. epoxidised fats
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/36—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal
- C07C29/38—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones
- C07C29/42—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by reactions with formation of hydroxy groups, which may occur via intermediates being derivatives of hydroxy, e.g. O-metal by reaction with aldehydes or ketones with compounds containing triple carbon-to-carbon bonds, e.g. with metal-alkynes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
- C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
- C07C69/716—Esters of keto-carboxylic acids or aldehydo-carboxylic acids
- C07C69/72—Acetoacetic acid esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
- C07D303/16—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by esterified hydroxyl radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
- C07D303/32—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by aldehydo- or ketonic radicals
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US69124667A | 1967-12-18 | 1967-12-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1259950A true GB1259950A (en) | 1972-01-12 |
Family
ID=24775729
Family Applications (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB42883/69A Expired GB1259949A (en) | 1967-12-18 | 1968-12-12 | Novel epoxy esters |
| GB59073/68A Expired GB1259947A (en) | 1967-12-18 | 1968-12-12 | A process for the manufacture of epoxy carboxylyic acids and derivatives thereof |
| GB42882/69A Expired GB1259948A (en) | 1967-12-18 | 1968-12-12 | Novel epoxy ketones |
| GB42884/69A Expired GB1259950A (en) | 1967-12-18 | 1968-12-12 | Novel acetoacetates |
Family Applications Before (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB42883/69A Expired GB1259949A (en) | 1967-12-18 | 1968-12-12 | Novel epoxy esters |
| GB59073/68A Expired GB1259947A (en) | 1967-12-18 | 1968-12-12 | A process for the manufacture of epoxy carboxylyic acids and derivatives thereof |
| GB42882/69A Expired GB1259948A (en) | 1967-12-18 | 1968-12-12 | Novel epoxy ketones |
Country Status (16)
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3563982A (en) * | 1969-01-02 | 1971-02-16 | Us Agriculture | Insect control process with synthetic hormones |
| BE734904A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1969-04-10 | 1969-12-22 | ||
| US3671551A (en) * | 1969-12-08 | 1972-06-20 | Scm Corp | Myrcene epoxide diels-alder adducts |
| US3810989A (en) * | 1970-11-16 | 1974-05-14 | Stauffer Chemical Co | Control of confused flour beetles using geranyl phenyl ethers |
| US3886148A (en) * | 1971-08-16 | 1975-05-27 | Stauffer Chemical Co | Insecticidal active geranyl and citronyl amine derivatives and their epoxides |
| US3888888A (en) * | 1971-08-16 | 1975-06-10 | Stauffer Chemical Co | Insecticidal active geranyl and citronyl amine derivatives and their epoxides |
| US3972928A (en) * | 1971-11-15 | 1976-08-03 | Baychem Corporation | Regulating plant growth with quaternary phosphonium aliphatic carboxamide salts |
| US4179579A (en) * | 1975-12-02 | 1979-12-18 | Kuraray Co., Ltd. | Substituted propargyl alcohols, allylic alcohols and unsaturated ketones, and methods for the production thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL247826A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1959-01-29 |
-
1967
- 1967-12-18 US US691246A patent/US3513176A/en not_active Expired - Lifetime
-
1968
- 1968-11-26 CH CH1756868A patent/CH511826A/de not_active IP Right Cessation
- 1968-12-02 IL IL40629A patent/IL40629A/xx unknown
- 1968-12-02 IL IL31197A patent/IL31197A/en unknown
- 1968-12-12 GB GB42883/69A patent/GB1259949A/en not_active Expired
- 1968-12-12 GB GB59073/68A patent/GB1259947A/en not_active Expired
- 1968-12-12 GB GB42882/69A patent/GB1259948A/en not_active Expired
- 1968-12-12 GB GB42884/69A patent/GB1259950A/en not_active Expired
- 1968-12-16 IE IE1522/68A patent/IE33079B1/xx unknown
- 1968-12-16 DE DE19681814874 patent/DE1814874A1/de active Pending
- 1968-12-17 BE BE725577D patent/BE725577A/xx unknown
- 1968-12-17 SE SE17270/68A patent/SE367188B/xx unknown
- 1968-12-17 NO NO05052/68A patent/NO129794B/no unknown
- 1968-12-17 AT AT1225768A patent/AT286953B/de not_active IP Right Cessation
- 1968-12-17 ES ES361555A patent/ES361555A1/es not_active Expired
- 1968-12-17 CS CS8560A patent/CS172862B2/cs unknown
- 1968-12-17 BR BR204900/68A patent/BR6804900D0/pt unknown
- 1968-12-17 IT IT25224/68A patent/IT1001459B/it active
- 1968-12-18 FR FR1595340D patent/FR1595340A/fr not_active Expired
- 1968-12-18 NL NL6818163A patent/NL6818163A/xx unknown
-
1969
- 1969-09-26 US US861503A patent/US3573299A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| US3513176A (en) | 1970-05-19 |
| NO129794B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1974-05-27 |
| IE33079B1 (en) | 1974-03-20 |
| AT286953B (de) | 1971-01-11 |
| FR1595340A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1970-06-08 |
| ES361555A1 (es) | 1971-06-16 |
| US3573299A (en) | 1971-03-30 |
| GB1259949A (en) | 1972-01-12 |
| GB1259948A (en) | 1972-01-12 |
| IL31197A0 (en) | 1969-02-27 |
| CH511826A (de) | 1971-08-31 |
| DE1814874A1 (de) | 1969-07-10 |
| IL31197A (en) | 1973-02-28 |
| GB1259947A (en) | 1972-01-12 |
| IE33079L (en) | 1969-06-18 |
| IT1001459B (it) | 1976-04-20 |
| IL40629A (en) | 1973-02-28 |
| CS172862B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1977-01-28 |
| SE367188B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1974-05-20 |
| NL6818163A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1969-06-20 |
| BR6804900D0 (pt) | 1973-03-08 |
| BE725577A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1969-06-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |