GB1258893A - - Google Patents
Info
- Publication number
- GB1258893A GB1258893A GB1258893DA GB1258893A GB 1258893 A GB1258893 A GB 1258893A GB 1258893D A GB1258893D A GB 1258893DA GB 1258893 A GB1258893 A GB 1258893A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalyst
- butyl lithium
- trichloropyrimidine
- reacted
- lithium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 abstract 8
- 239000003054 catalyst Substances 0.000 abstract 6
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 4
- DPVIABCMTHHTGB-UHFFFAOYSA-N 2,4,6-trichloropyrimidine Chemical compound ClC1=CC(Cl)=NC(Cl)=N1 DPVIABCMTHHTGB-UHFFFAOYSA-N 0.000 abstract 3
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 abstract 3
- 150000002390 heteroarenes Chemical class 0.000 abstract 3
- 229920000642 polymer Polymers 0.000 abstract 3
- VQAIMPOVHMXDIQ-UHFFFAOYSA-N 2,3,5-triethoxypyrazine Chemical compound C(C)OC1=NC(=CN=C1OCC)OCC VQAIMPOVHMXDIQ-UHFFFAOYSA-N 0.000 abstract 2
- ICETWLGKJXCIDX-UHFFFAOYSA-N 2,4-dichloro-1,3-thiazole Chemical compound ClC1=CSC(Cl)=N1 ICETWLGKJXCIDX-UHFFFAOYSA-N 0.000 abstract 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- 150000001993 dienes Chemical class 0.000 abstract 2
- 125000002524 organometallic group Chemical group 0.000 abstract 2
- BMZLYVIMZWOTDW-UHFFFAOYSA-N 1,3,6-tribromoisoquinoline Chemical compound BrC1=NC(Br)=CC2=CC(Br)=CC=C21 BMZLYVIMZWOTDW-UHFFFAOYSA-N 0.000 abstract 1
- GTGCDFWERLBBEK-UHFFFAOYSA-N 2,3,4-triethoxypyridine Chemical compound C(C)OC1=C(C(=NC=C1)OCC)OCC GTGCDFWERLBBEK-UHFFFAOYSA-N 0.000 abstract 1
- AFFKMXRQXKBNNL-UHFFFAOYSA-N 2,3,5-tribromopyrazine Chemical compound BrC1=CN=C(Br)C(Br)=N1 AFFKMXRQXKBNNL-UHFFFAOYSA-N 0.000 abstract 1
- GZEGFNCRZUGIOB-UHFFFAOYSA-N 2,3,6-trichloroquinoxaline Chemical compound N1=C(Cl)C(Cl)=NC2=CC(Cl)=CC=C21 GZEGFNCRZUGIOB-UHFFFAOYSA-N 0.000 abstract 1
- FPYRBZZBSHBJIH-UHFFFAOYSA-N 2,3-diiodofuran Chemical compound IC=1C=COC=1I FPYRBZZBSHBJIH-UHFFFAOYSA-N 0.000 abstract 1
- YRWXPZFGIPWZMC-UHFFFAOYSA-N 2,4,5-tribromoquinoline Chemical compound BrC1=NC2=CC=CC(=C2C(=C1)Br)Br YRWXPZFGIPWZMC-UHFFFAOYSA-N 0.000 abstract 1
- KCUCKJJLMMZKBV-UHFFFAOYSA-N 2,4,5-trichloro-1h-imidazole Chemical compound ClC1=NC(Cl)=C(Cl)N1 KCUCKJJLMMZKBV-UHFFFAOYSA-N 0.000 abstract 1
- QEPXACTUQNGGHW-UHFFFAOYSA-N 2,4,6-trichloro-1h-triazine Chemical compound ClN1NC(Cl)=CC(Cl)=N1 QEPXACTUQNGGHW-UHFFFAOYSA-N 0.000 abstract 1
- FJNNGKMAGDPVIU-UHFFFAOYSA-N 2,4,6-trichloropyridine Chemical compound ClC1=CC(Cl)=NC(Cl)=C1 FJNNGKMAGDPVIU-UHFFFAOYSA-N 0.000 abstract 1
- QDCRUUCTUWPAJE-UHFFFAOYSA-N 2,5-diiodofuran Chemical compound IC1=CC=C(I)O1 QDCRUUCTUWPAJE-UHFFFAOYSA-N 0.000 abstract 1
- WGFCNCNTGOFBBF-UHFFFAOYSA-N 2-bromopyrazine Chemical compound BrC1=CN=CC=N1 WGFCNCNTGOFBBF-UHFFFAOYSA-N 0.000 abstract 1
- QKJAZPHKNWSXDF-UHFFFAOYSA-N 2-bromoquinoline Chemical compound C1=CC=CC2=NC(Br)=CC=C21 QKJAZPHKNWSXDF-UHFFFAOYSA-N 0.000 abstract 1
- UNCQVRBWJWWJBF-UHFFFAOYSA-N 2-chloropyrimidine Chemical compound ClC1=NC=CC=N1 UNCQVRBWJWWJBF-UHFFFAOYSA-N 0.000 abstract 1
- KLEYVGWAORGTIT-UHFFFAOYSA-N 2-chlorothiazole Chemical compound ClC1=NC=CS1 KLEYVGWAORGTIT-UHFFFAOYSA-N 0.000 abstract 1
- GBAOOJAWDCNOGO-UHFFFAOYSA-N 3,4,5-trichloropyridazine Chemical compound ClC1=CN=NC(Cl)=C1Cl GBAOOJAWDCNOGO-UHFFFAOYSA-N 0.000 abstract 1
- BQRBAXFOPZRMCU-UHFFFAOYSA-N 5-chloro-1h-imidazole Chemical compound ClC1=CN=CN1 BQRBAXFOPZRMCU-UHFFFAOYSA-N 0.000 abstract 1
- DFGLZFZXSHRQEA-UHFFFAOYSA-N CC(C)[K] Chemical compound CC(C)[K] DFGLZFZXSHRQEA-UHFFFAOYSA-N 0.000 abstract 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000004104 aryloxy group Chemical group 0.000 abstract 1
- VRWRYXRXVZEJKF-UHFFFAOYSA-N beryllium;ethane Chemical compound [Be+2].[CH2-]C.[CH2-]C VRWRYXRXVZEJKF-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 abstract 1
- -1 dilithium naphthyl Chemical compound 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 229920001519 homopolymer Polymers 0.000 abstract 1
- 239000012535 impurity Substances 0.000 abstract 1
- YNXURHRFIMQACJ-UHFFFAOYSA-N lithium;methanidylbenzene Chemical compound [Li+].[CH2-]C1=CC=CC=C1 YNXURHRFIMQACJ-UHFFFAOYSA-N 0.000 abstract 1
- DLPASUVGCQPFFO-UHFFFAOYSA-N magnesium;ethane Chemical compound [Mg+2].[CH2-]C.[CH2-]C DLPASUVGCQPFFO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- NHKJPPKXDNZFBJ-UHFFFAOYSA-N phenyllithium Chemical compound [Li]C1=CC=CC=C1 NHKJPPKXDNZFBJ-UHFFFAOYSA-N 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- KSMWLICLECSXMI-UHFFFAOYSA-N sodium;benzene Chemical compound [Na+].C1=CC=[C-]C=C1 KSMWLICLECSXMI-UHFFFAOYSA-N 0.000 abstract 1
- 229920003051 synthetic elastomer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
- C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
- C08C19/44—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB205468 | 1968-01-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1258893A true GB1258893A (cg-RX-API-DMAC10.html) | 1971-12-30 |
Family
ID=9732795
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1258893D Expired GB1258893A (cg-RX-API-DMAC10.html) | 1968-01-15 | 1968-01-15 |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE1901900A1 (cg-RX-API-DMAC10.html) |
| GB (1) | GB1258893A (cg-RX-API-DMAC10.html) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7723440B2 (en) | 2002-08-30 | 2010-05-25 | Bridgestone Corporation | Functionalized polymers and improved vulcanizates therefrom |
| CN113831512A (zh) * | 2021-09-22 | 2021-12-24 | 中山大学 | 一种多氮共轭微孔聚合物及其制备方法与应用 |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4935471A (en) * | 1987-10-15 | 1990-06-19 | The Goodyear Tire & Rubber Company | Capped polydienes |
-
1968
- 1968-01-15 GB GB1258893D patent/GB1258893A/en not_active Expired
-
1969
- 1969-01-15 DE DE19691901900 patent/DE1901900A1/de active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7723440B2 (en) | 2002-08-30 | 2010-05-25 | Bridgestone Corporation | Functionalized polymers and improved vulcanizates therefrom |
| US8207275B2 (en) | 2002-08-30 | 2012-06-26 | Bridgestone Corporation | Functionalized polymers and improved vulcanizates therefrom |
| CN113831512A (zh) * | 2021-09-22 | 2021-12-24 | 中山大学 | 一种多氮共轭微孔聚合物及其制备方法与应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1901900A1 (de) | 1969-09-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |