GB1252878A - - Google Patents
Info
- Publication number
- GB1252878A GB1252878A GB1252878DA GB1252878A GB 1252878 A GB1252878 A GB 1252878A GB 1252878D A GB1252878D A GB 1252878DA GB 1252878 A GB1252878 A GB 1252878A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- emulsion
- wax
- carbon atoms
- amine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000839 emulsion Substances 0.000 abstract 7
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract 5
- 125000004432 carbon atom Chemical group C* 0.000 abstract 5
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 abstract 4
- -1 amine salt Chemical class 0.000 abstract 4
- 150000001412 amines Chemical class 0.000 abstract 4
- 239000003995 emulsifying agent Substances 0.000 abstract 4
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 abstract 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- 239000002253 acid Substances 0.000 abstract 3
- 125000002091 cationic group Chemical group 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 239000003607 modifier Substances 0.000 abstract 3
- 239000012169 petroleum derived wax Substances 0.000 abstract 3
- 235000019381 petroleum wax Nutrition 0.000 abstract 3
- 239000001993 wax Substances 0.000 abstract 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 abstract 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 abstract 2
- 125000000129 anionic group Chemical group 0.000 abstract 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 abstract 2
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 abstract 2
- 150000007524 organic acids Chemical class 0.000 abstract 2
- 238000004513 sizing Methods 0.000 abstract 2
- BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical compound CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 abstract 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 abstract 1
- BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 abstract 1
- XBPCUCUWBYBCDP-UHFFFAOYSA-N Dicyclohexylamine Chemical compound C1CCCCC1NC1CCCCC1 XBPCUCUWBYBCDP-UHFFFAOYSA-N 0.000 abstract 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical class O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 1
- 229920001131 Pulp (paper) Polymers 0.000 abstract 1
- 235000011054 acetic acid Nutrition 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 150000004985 diamines Chemical class 0.000 abstract 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 abstract 1
- 235000019253 formic acid Nutrition 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000012184 mineral wax Substances 0.000 abstract 1
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 235000019260 propionic acid Nutrition 0.000 abstract 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 abstract 1
- 238000007127 saponification reaction Methods 0.000 abstract 1
- 239000000344 soap Substances 0.000 abstract 1
- 239000012178 vegetable wax Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/21—Macromolecular organic compounds of natural origin; Derivatives thereof
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/34—Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/60—Waxes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/62—Rosin; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paper (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
1,252,878. Size; paper. MOBIL OIL CORP. 23 June, 1970 [17 July, 1969], No. 30370/70. Headings D1P and D2B. A paper sizing composition comprises a mixture of an aqueous cationic wax emulsion and an anionic rosin size. The cationic wax emulsion may include petroleum wax, vegetable wax and mineral wax, and the rosin size, may comprise any anionic rosin which has been saponified (either partially or completely) to form a water soluble soap material, e.g. by saponification of abietic acid with an alkali. The rosin size is employed from 5 to 50% and preferably 10 to 35% by weight. The cationic wax emulsion comprises (a) a dispersed phase comprising a petroleum wax; (b) an emulsifying agent comprising an amine salt of an organic acid having 1 to 18 carbon atoms and preferably 1 to 6 carbon atoms, or an inorganic mineral acid, with an amine having 10 to 40, and preferably 20 to 40 carbon atoms; and, if so desired (c) an emulsion modifier comprising an amine having up to 12 carbon atoms and having a molecular weight lower than that of the amino employed for producing the emulsifying agent. The petroleum wax may be modified with polymers, e.g. polyethylene, ethylene-vinyl acetate copolymers. Examples of the organic acid with 1 to 18 carbon atoms are formic acid, acetic acid, propionic acid and butyric acid, and of the inorganic mineral acids are hydrochloric, sulphuric, phosphoric and nitric acids. The acid is employed in an amount sufficient only to react with all of the amine employed for preparing the emulsifying agent. Propylene diamines are used to produce the emulsifying agent and Examples of amines used as the emulsion modifier are dicyclohexylamine, nheptyl-#-amine, n-octylamine, n-dodecylamine, aniline and N-dodecyl 1, 3 propylene #diamine. The emulsion modifier lowers the viscosity and improves the shear stability of the emulsion. The sizing composition is added to paper pulp prior to it being wet-laid to form paper.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US84272469A | 1969-07-17 | 1969-07-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1252878A true GB1252878A (en) | 1971-11-10 |
Family
ID=25288101
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1252878D Expired GB1252878A (en) | 1969-07-17 | 1970-06-23 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3578477A (en) |
| JP (1) | JPS4929883B1 (en) |
| AT (1) | AT309201B (en) |
| DE (1) | DE2034886A1 (en) |
| FR (1) | FR2055298A5 (en) |
| GB (1) | GB1252878A (en) |
| SE (1) | SE361809B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5213092A (en) * | 1975-07-22 | 1977-02-01 | Toshiba Corp | Monitor device |
| DE2818880C3 (en) * | 1978-04-28 | 1982-05-13 | Mobil Oil Ag In Deutschland, 2000 Hamburg | Process for sizing paper and cardboard using wax dispersions |
| JPS6019940U (en) * | 1983-07-18 | 1985-02-12 | 湯浅 秀明 | earthquake detection alarm |
-
1969
- 1969-07-17 US US842724A patent/US3578477A/en not_active Expired - Lifetime
-
1970
- 1970-06-23 GB GB1252878D patent/GB1252878A/en not_active Expired
- 1970-07-14 DE DE19702034886 patent/DE2034886A1/en active Pending
- 1970-07-16 JP JP45061831A patent/JPS4929883B1/ja active Pending
- 1970-07-16 SE SE09857/70A patent/SE361809B/xx unknown
- 1970-07-17 AT AT656370A patent/AT309201B/en not_active IP Right Cessation
- 1970-07-17 FR FR7026489A patent/FR2055298A5/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| AT309201B (en) | 1973-08-10 |
| JPS4929883B1 (en) | 1974-08-08 |
| FR2055298A5 (en) | 1971-05-07 |
| DE2034886A1 (en) | 1971-01-28 |
| SE361809B (en) | 1973-11-19 |
| US3578477A (en) | 1971-05-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |