GB1251867A - - Google Patents
Info
- Publication number
- GB1251867A GB1251867A GB1251867DA GB1251867A GB 1251867 A GB1251867 A GB 1251867A GB 1251867D A GB1251867D A GB 1251867DA GB 1251867 A GB1251867 A GB 1251867A
- Authority
- GB
- United Kingdom
- Prior art keywords
- prepared
- reacting
- march
- carbon atoms
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- JLIDBLDQVAYHNE-YKALOCIXSA-N (+)-Abscisic acid Chemical compound OC(=O)/C=C(/C)\C=C\[C@@]1(O)C(C)=CC(=O)CC1(C)C JLIDBLDQVAYHNE-YKALOCIXSA-N 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 2
- 125000004183 alkoxy alkyl group Chemical group 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 abstract 2
- JJRYPZMXNLLZFH-UHFFFAOYSA-N 4-hydroxy-3,5,5-trimethyl-4-(3-oxobut-1-enyl)cyclohex-2-en-1-one Chemical compound CC(=O)C=CC1(O)C(C)=CC(=O)CC1(C)C JJRYPZMXNLLZFH-UHFFFAOYSA-N 0.000 abstract 1
- 150000003529 abscisic acid derivatives Chemical class 0.000 abstract 1
- -1 amine salts Chemical class 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- FCRACOPGPMPSHN-UHFFFAOYSA-N desoxyabscisic acid Natural products OC(=O)C=C(C)C=CC1C(C)=CC(=O)CC1(C)C FCRACOPGPMPSHN-UHFFFAOYSA-N 0.000 abstract 1
- 125000004185 ester group Chemical group 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- VBQCHPIMZGQLAZ-UHFFFAOYSA-N phosphorane Chemical class [PH5] VBQCHPIMZGQLAZ-UHFFFAOYSA-N 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C403/00—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone
- C07C403/20—Derivatives of cyclohexane or of a cyclohexene or of cyclohexadiene, having a side-chain containing an acyclic unsaturated part of at least four carbon atoms, this part being directly attached to the cyclohexane or cyclohexene or cyclohexadiene rings, e.g. vitamin A, beta-carotene, beta-ionone having side-chains substituted by carboxyl groups or halides, anhydrides, or (thio)esters thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/535—Organo-phosphoranes
- C07F9/5352—Phosphoranes containing the structure P=C-
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
1,251,867. Abscisic acid derivative. R. J. REYNOLDS TOBACCO CO. 13 March, 1969 [18 March, 1968], No. 13380/69. Headings C2C and C2P. [Also in Division C1] The invention comprises alkyl and alkoxyalkyl esters of abscisic acid, the ester groups of which contain 6-18 carbon atoms, and watersoluble amine salts of said acid. The esters are prepared by reacting 4-(1-hydroxy-4-oxo-2,6,6- trimethyl - 2 - cyclohexene - 1 - yl) - 3 - butene- 2 - one with a compound of the formula where R is alkyl or alkoxyalkyl of 6-18 carbon atoms. The salts are prepared by reacting the free acid with an amine. The phosphorane compounds are prepared by reacting triphenyl phosphine with a compound of the formula CICH 2 CO 2 R or BrCH 2 CO 2 R.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US71409368A | 1968-03-18 | 1968-03-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1251867A true GB1251867A (en) | 1971-11-03 |
Family
ID=24868724
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1251867D Expired GB1251867A (en) | 1968-03-18 | 1969-03-13 |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE730004A (en) |
| DE (1) | DE1913688A1 (en) |
| FR (1) | FR2004178A1 (en) |
| GB (1) | GB1251867A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008094557A1 (en) | 2007-01-31 | 2008-08-07 | Valent Biosciences Corporation | Salts, aqueous liquid compositions containing salts of s-(+)-abscisic acid and methods of their preparation |
| WO2010011809A1 (en) | 2008-07-24 | 2010-01-28 | Valent Biosciences Corporation | Salts, aqueous liquid compositions containing salts of s-(+)-abscisic acid and methods of their preparation |
| US8288437B2 (en) | 2008-07-24 | 2012-10-16 | Valent Biosciences Corporation | Salts, aqueous liquid compositions containing salts of abscisic acid analogs and methods of their preparation |
| US8722928B2 (en) | 2007-01-31 | 2014-05-13 | Valent Biosciences Corporation | Stable and non-precipitating aqueous compositions containing the potassium salt of (S)-(+)-abscisic acid, and methods of their preparation and use |
| US9161535B2 (en) | 2007-01-31 | 2015-10-20 | Valent Biosciences Corporation | Color stable aqueous formulations containing the potassium salt of (S )-(+)-abscisic acid and methods of their use |
-
1969
- 1969-03-13 GB GB1251867D patent/GB1251867A/en not_active Expired
- 1969-03-18 DE DE19691913688 patent/DE1913688A1/en active Pending
- 1969-03-18 FR FR6907727A patent/FR2004178A1/fr not_active Withdrawn
- 1969-03-18 BE BE730004D patent/BE730004A/xx unknown
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2114140A4 (en) * | 2007-01-31 | 2011-10-19 | Valent Biosciences Corp | Salts, aqueous liquid compositions containing salts of s-(+)-abscisic acid and methods of their preparation |
| US8318976B2 (en) | 2007-01-31 | 2012-11-27 | Valent Biosciences Corporation | Salts, aqueous liquid compositions containing salts of S-(+)-abscisic acid and methods of their preparation |
| US9161535B2 (en) | 2007-01-31 | 2015-10-20 | Valent Biosciences Corporation | Color stable aqueous formulations containing the potassium salt of (S )-(+)-abscisic acid and methods of their use |
| CN101646341A (en) * | 2007-01-31 | 2010-02-10 | 瓦伦特生物科学公司 | Salt, the aqueous liquid composition of salt that contains S-(+)-abscisic acid and their preparation method |
| US9161529B2 (en) | 2007-01-31 | 2015-10-20 | Valent Biosciences Corporation | Stable and non-precipitating aqueous compositions containing the potassium salt of (S)-(+)-abscisic acid, and methods of their preparation and use |
| US8722928B2 (en) | 2007-01-31 | 2014-05-13 | Valent Biosciences Corporation | Stable and non-precipitating aqueous compositions containing the potassium salt of (S)-(+)-abscisic acid, and methods of their preparation and use |
| EP2114140A1 (en) * | 2007-01-31 | 2009-11-11 | Valent Biosciences Corporation | Salts, aqueous liquid compositions containing salts of s-(+)-abscisic acid and methods of their preparation |
| AU2008211154B2 (en) * | 2007-01-31 | 2013-04-04 | Valent Biosciences Corporation | Salts, aqueous liquid compositions containing salts of S-(+)-abscisic acid and methods of their preparation |
| WO2008094557A1 (en) | 2007-01-31 | 2008-08-07 | Valent Biosciences Corporation | Salts, aqueous liquid compositions containing salts of s-(+)-abscisic acid and methods of their preparation |
| EP2320727A1 (en) * | 2008-07-24 | 2011-05-18 | Valent Biosciences Corporation | Salts, aqueous liquid compositions containing salts of s-(+)-abscisic acid and methods of their preparation |
| US8288437B2 (en) | 2008-07-24 | 2012-10-16 | Valent Biosciences Corporation | Salts, aqueous liquid compositions containing salts of abscisic acid analogs and methods of their preparation |
| EP2320727A4 (en) * | 2008-07-24 | 2013-06-12 | Valent Biosciences Corp | Salts, aqueous liquid compositions containing salts of s-(+)-abscisic acid and methods of their preparation |
| CN102164486A (en) * | 2008-07-24 | 2011-08-24 | 瓦伦特生物科学公司 | Salts, aqueous liquid compositions containing salts of s-(+)-abscisic acid and methods of their preparation |
| US8278480B2 (en) | 2008-07-24 | 2012-10-02 | Valent Biosciences Corporation | Salts, aqueous liquid compositions containing salts of S-(+)-abscisic acid and methods of their preparation |
| WO2010011809A1 (en) | 2008-07-24 | 2010-01-28 | Valent Biosciences Corporation | Salts, aqueous liquid compositions containing salts of s-(+)-abscisic acid and methods of their preparation |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2004178A1 (en) | 1969-11-21 |
| DE1913688A1 (en) | 1970-02-19 |
| BE730004A (en) | 1969-09-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |