GB1250877A - - Google Patents
Info
- Publication number
- GB1250877A GB1250877A GB1250877DA GB1250877A GB 1250877 A GB1250877 A GB 1250877A GB 1250877D A GB1250877D A GB 1250877DA GB 1250877 A GB1250877 A GB 1250877A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- iso
- stated
- stabilizers
- examples
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/36—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino acids, polyamines and polycarboxylic acids
Abstract
1,250,877. Copolyamides. B.P. CHEMICALS (UK) Ltd. 15 Nov., 1968 [9 Dec., 1907], No. 56095/67. Heading C3R. At least 80 mol. per cent of the units of a copolyamide are derivable from (a) 6-aminohexanoic acid (b) m- or m/p-xylylene diamine containing not more than 30% p-isomer and (c) an aromatic or araliphatic dicarboxylic acid. The selection of the particular combination of (a), (b) and (c) is stated to give transparent amorphous polyamides of advantageous tensile strength. (c) may be one or more of iso- and tere-phthalic acids and phenylene diacetic acid. Optional comonomers mentioned are laurolactam or 12-aminododecanoic acid; adipic, azelaic, sebacic or dodecanedioic acid; and 2,2,4- or 2,4,4-trimethyl hexamethylene diamine or 3-aminomethyl-3,5,5-trimethyl cyclohexylamine. The components may be meltcondensed directly or with a precondensation step in the presence of 20 to 150 wt. of water under reflux conditions; alternatively an intermediate amide may be prepared by (b) or (c) with (a) at 200‹ to 250‹ C. in the presence of a catalyst before reaction with the remaining component(s). The process may be continuous. Monobasic acids or monoamines may be used as viscosity stabilizers with precautions to avoid discolouration. A colour stabilizer such as an inorganic, e.g. NH 4 , hypophosphite or a trihydrocarbyl phosphite may be added as may heat, oxidation and U.V. stabilizers. The polymers may have an inherent viscosity (0.15% solution in H 2 SO 4 at 25‹ C.) above 0.7. In examples the physical properties of copolymers of the invention wherein (c) is iso- and/or terephthalated acid are compared with those of nylons 6, 12 and 66. In some examples, the polymer is insoluble in H 2 SO 4 . The copolymer is stated to be suitable for various moulding techniques; coating, especially on metals, being applied as a powder with subsequent heating to form a coherent film; rigid foams; and fibres. Reference is made to Specifications 1,250,878 and 1,049,987.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB5609567 | 1967-12-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1250877A true GB1250877A (en) | 1971-10-20 |
Family
ID=10475713
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1250877D Expired GB1250877A (en) | 1967-12-09 | 1967-12-09 |
Country Status (5)
Country | Link |
---|---|
BE (1) | BE725177A (en) |
DE (1) | DE1813018A1 (en) |
FR (1) | FR1594163A (en) |
GB (1) | GB1250877A (en) |
NL (1) | NL6817106A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4826955A (en) * | 1988-01-21 | 1989-05-02 | Allied-Signal Inc. | Amorphous copolyamide article of manufacture with moisture-insensitive oxygen barrier properties |
US4902749A (en) * | 1987-08-24 | 1990-02-20 | Allied-Signal Inc. | High impact, styrenic polymer/thermoplastic polymer grafted blends |
US5210134A (en) * | 1987-08-24 | 1993-05-11 | Allied Signal | High impact, styrenic polymer/thermoplastic polymer grafted blends |
WO2002090421A2 (en) * | 2001-05-08 | 2002-11-14 | Ems-Chemie Ag | Polyamide moulding compounds for producing optical lenses |
US6500559B2 (en) | 1998-05-04 | 2002-12-31 | Cryovac, Inc. | Multiple layer film with amorphous polyamide layer |
US7726398B2 (en) | 2005-06-16 | 2010-06-01 | Bp Exploration Operating Company Limited | Water flooding method |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE792063A (en) * | 1971-12-02 | 1973-05-29 | Bayer Ag | TRANSPARENT COPOLYAMIDES |
-
1967
- 1967-12-09 GB GB1250877D patent/GB1250877A/en not_active Expired
-
1968
- 1968-11-29 NL NL6817106A patent/NL6817106A/xx unknown
- 1968-12-06 DE DE19681813018 patent/DE1813018A1/en active Pending
- 1968-12-06 FR FR1594163D patent/FR1594163A/fr not_active Expired
- 1968-12-09 BE BE725177D patent/BE725177A/xx unknown
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4902749A (en) * | 1987-08-24 | 1990-02-20 | Allied-Signal Inc. | High impact, styrenic polymer/thermoplastic polymer grafted blends |
US5210134A (en) * | 1987-08-24 | 1993-05-11 | Allied Signal | High impact, styrenic polymer/thermoplastic polymer grafted blends |
US4826955A (en) * | 1988-01-21 | 1989-05-02 | Allied-Signal Inc. | Amorphous copolyamide article of manufacture with moisture-insensitive oxygen barrier properties |
AU629200B2 (en) * | 1988-01-21 | 1992-10-01 | Allied-Signal Inc. | Article with moisture-insensitive oxygen barrier properties |
US6500559B2 (en) | 1998-05-04 | 2002-12-31 | Cryovac, Inc. | Multiple layer film with amorphous polyamide layer |
US6858313B2 (en) | 1998-05-04 | 2005-02-22 | Cryovac, Inc. | Multiple layer film with amorphous polyamide layer |
WO2002090421A2 (en) * | 2001-05-08 | 2002-11-14 | Ems-Chemie Ag | Polyamide moulding compounds for producing optical lenses |
WO2002090421A3 (en) * | 2001-05-08 | 2003-02-27 | Ems Chemie Ag | Polyamide moulding compounds for producing optical lenses |
US7726398B2 (en) | 2005-06-16 | 2010-06-01 | Bp Exploration Operating Company Limited | Water flooding method |
Also Published As
Publication number | Publication date |
---|---|
FR1594163A (en) | 1970-06-01 |
BE725177A (en) | 1969-06-09 |
NL6817106A (en) | 1969-06-11 |
DE1813018A1 (en) | 1969-12-11 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PLNP | Patent lapsed through nonpayment of renewal fees |