GB1243591A - Process for carbonylating amines - Google Patents

Process for carbonylating amines

Info

Publication number
GB1243591A
GB1243591A GB340969A GB340969A GB1243591A GB 1243591 A GB1243591 A GB 1243591A GB 340969 A GB340969 A GB 340969A GB 340969 A GB340969 A GB 340969A GB 1243591 A GB1243591 A GB 1243591A
Authority
GB
United Kingdom
Prior art keywords
atom
catalyst
jan
hydrogen
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB340969A
Inventor
Christian Lassau
Yves Chauvin
Gilles Lefebvre
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Publication of GB1243591A publication Critical patent/GB1243591A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C273/00—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups
    • C07C273/18—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas
    • C07C273/1809—Preparation of urea or its derivatives, i.e. compounds containing any of the groups, the nitrogen atoms not being part of nitro or nitroso groups of substituted ureas with formation of the N-C(O)-N moiety
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/20—Carbonyls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/827—Iridium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

1,243,591. Catalyst system. INSTITUT FRANCAIS DU PETROLE DES CARBURANTS ET LUBRIFIANTS. 21 Jan., 1969 [22 Jan., 1968; 21 June, 1968], No. 3409/69. Heading B1E. [Also in Division C2] A catalyst system comprises (i) a rhodium complex of formula RhXY p (CO) m and (ii) at least one compound of formula AR'R"R"', wherein X is halogen or hydrogen, Y is a C 20 -C 10 , hydrocarbon containing at least one double bond, p and m are 0, 1, 2, 3 or 4 at least one being greater than zero, A is an atom of Group VB and R', R" and R"' taken separately each represent a monovalent hydrocarbon radical or a pair of these radicals may form a divalent hydrocarbon radical forming a ring with atom A, these radicals optionally containing, in addition to hydrogen and carbon, at least one atom of an element of Group VB. The catalyst may be used in solution, solvents specified being aromatic hydrocarbons, saturated hydrocarbons, alcohols or ethers. Catalyst systems specified are (Examples 7 to 14) Rh 2 Cl 2 (C 2 H 4 ) 4 , plus one of triethylphosphine, phenyldiethylphosphine, tricyclohexylphosphine, triphenylphosphine, ethyl bis dimethylphosphine and trimethylphosphine.
GB340969A 1968-01-22 1969-01-21 Process for carbonylating amines Expired GB1243591A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR136943 1968-01-22
FR156205 1968-06-21

Publications (1)

Publication Number Publication Date
GB1243591A true GB1243591A (en) 1971-08-18

Family

ID=26181745

Family Applications (1)

Application Number Title Priority Date Filing Date
GB340969A Expired GB1243591A (en) 1968-01-22 1969-01-21 Process for carbonylating amines

Country Status (4)

Country Link
CA (1) CA966847A (en)
DE (1) DE1902560A1 (en)
GB (1) GB1243591A (en)
NL (1) NL6901001A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4782071A (en) * 1986-11-03 1988-11-01 Warner-Lambert Company Tetrasubstituted urea cholinergic agents
GB2279347A (en) * 1993-06-22 1995-01-04 Roger Liddle Jefferson Urea derivatives and their use in treating water

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4556734A (en) * 1983-11-04 1985-12-03 Texaco Inc. Process for synthesizing formamides from synthesis gas plus ammonia

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4782071A (en) * 1986-11-03 1988-11-01 Warner-Lambert Company Tetrasubstituted urea cholinergic agents
GB2279347A (en) * 1993-06-22 1995-01-04 Roger Liddle Jefferson Urea derivatives and their use in treating water

Also Published As

Publication number Publication date
CA966847A (en) 1975-04-29
DE1902560A1 (en) 1969-08-28
NL6901001A (en) 1969-07-24

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