GB1240742A - Dyed textiles resistant to ozone fading - Google Patents
Dyed textiles resistant to ozone fadingInfo
- Publication number
- GB1240742A GB1240742A GB5434369A GB5434369A GB1240742A GB 1240742 A GB1240742 A GB 1240742A GB 5434369 A GB5434369 A GB 5434369A GB 5434369 A GB5434369 A GB 5434369A GB 1240742 A GB1240742 A GB 1240742A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polyamide
- tertiary amine
- cresol
- nov
- butyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 title abstract 2
- 238000005562 fading Methods 0.000 title abstract 2
- 239000004753 textile Substances 0.000 title 1
- 239000004952 Polyamide Substances 0.000 abstract 5
- 229920002647 polyamide Polymers 0.000 abstract 5
- 150000003512 tertiary amines Chemical class 0.000 abstract 3
- 239000004677 Nylon Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 229920001778 nylon Polymers 0.000 abstract 2
- 238000009987 spinning Methods 0.000 abstract 2
- BHIIOLWIZLICII-UHFFFAOYSA-N 2-butyl-5-methylphenol Chemical compound CCCCC1=CC=C(C)C=C1O BHIIOLWIZLICII-UHFFFAOYSA-N 0.000 abstract 1
- KGCQNRKGLJTDKT-UHFFFAOYSA-N 4-[[3,5-bis[(3,5-dibutyl-4-hydroxyphenyl)methyl]-2,4,6-trimethylphenyl]methyl]-2,6-dibutylphenol Chemical compound CCCCC1=C(O)C(CCCC)=CC(CC=2C(=C(CC=3C=C(CCCC)C(O)=C(CCCC)C=3)C(C)=C(CC=3C=C(CCCC)C(O)=C(CCCC)C=3)C=2C)C)=C1 KGCQNRKGLJTDKT-UHFFFAOYSA-N 0.000 abstract 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N 4-nonylphenol Chemical compound CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 241001082241 Lythrum hyssopifolia Species 0.000 abstract 1
- 229920002302 Nylon 6,6 Polymers 0.000 abstract 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 238000004043 dyeing Methods 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/607—Nitrogen-containing polyethers or their quaternary derivatives
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/607—Nitrogen-containing polyethers or their quaternary derivatives
- D06P1/6076—Nitrogen-containing polyethers or their quaternary derivatives addition products of amines and alkylene oxides or oxiranes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/645—Aliphatic, araliphatic or cycloaliphatic compounds containing amino groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65118—Compounds containing hydroxyl groups
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyamides (AREA)
Abstract
1,240,742. Dyeing polyamides. ALLIED CHEMICAL CORP. 5 Nov., 1969 [7 Nov., 1968], No. 54343/69. Heading D1B. Dyed polyamides e.g. poly #-caproamide and polyhexamethylene adipamide are rendered more resistant to ozone fading by incorporating into the polyamide (a) an ethylene oxy-substituted tertiary amine of the formulae: wherein R is an alkyl or aralkyl radical containing 4 to 25 carbon atoms and x, y and z are integers so that in compounds of the first formula above x+y is not more than 10 and in the second formula x+y+z is not more than 10 and (b) a hindered phenol. The tertiary amine is preferably N, N-di-(2-hydroxymethyl) octadecylamine or N, N, N'-tri-(2- hydroxyethyl)-N'-octadecyl-1, 3-propylene diamine and the hindered phenols are 4, 4'- butyldene bis-(6-butyl-m-cresol), p-nonylphenol, 1, 3, 5-trimethyl-2, 4, 6-tris-(3, 5-dibutyl-4- hydroxybenzyl)-benzene or 6-butyl-m-cresol. The compounds (a) and (b) may be added together or separately during the polyamide polymerisation, coated onto nylon chips before spinning or injected into the nylon melt during spinning. The tertiary amine may also be applied from an aqueous bath e.g. the dyebath and amounts of 0.1% to 5% based on the weight of polyamide of each component may be used.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US77417568A | 1968-11-07 | 1968-11-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1240742A true GB1240742A (en) | 1971-07-28 |
Family
ID=25100469
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB5434369A Expired GB1240742A (en) | 1968-11-07 | 1969-11-05 | Dyed textiles resistant to ozone fading |
Country Status (5)
| Country | Link |
|---|---|
| BE (1) | BE741324A (en) |
| CH (1) | CH492035A (en) |
| DE (1) | DE1955694A1 (en) |
| FR (1) | FR2022765A1 (en) |
| GB (1) | GB1240742A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3248329A1 (en) * | 1982-12-28 | 1984-06-28 | Bayer Ag, 5090 Leverkusen | POLYAMIDE WITH REDUCED WATER ABSORPTION |
-
1969
- 1969-11-05 DE DE19691955694 patent/DE1955694A1/en active Pending
- 1969-11-05 GB GB5434369A patent/GB1240742A/en not_active Expired
- 1969-11-05 CH CH1649069A patent/CH492035A/en not_active IP Right Cessation
- 1969-11-05 BE BE741324D patent/BE741324A/xx unknown
- 1969-11-05 FR FR6937975A patent/FR2022765A1/fr not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| CH492035A (en) | 1970-06-15 |
| FR2022765A1 (en) | 1970-08-07 |
| BE741324A (en) | 1970-04-16 |
| DE1955694A1 (en) | 1970-06-04 |
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