GB1233858A - - Google Patents
Info
- Publication number
- GB1233858A GB1233858A GB1233858DA GB1233858A GB 1233858 A GB1233858 A GB 1233858A GB 1233858D A GB1233858D A GB 1233858DA GB 1233858 A GB1233858 A GB 1233858A
- Authority
- GB
- United Kingdom
- Prior art keywords
- benzoquinone
- methyl
- formula
- phytyl
- geranyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 abstract 2
- -1 Isoprenoid quinones Chemical class 0.000 abstract 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 2
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 abstract 1
- SJPDQAGAIQSHOW-MRIFWDATSA-N 2,3,5-trimethyl-6-[(e,7r,11r)-3,7,11,15-tetramethylhexadec-2-enyl]cyclohexa-2,5-diene-1,4-dione Chemical compound CC(C)CCC[C@@H](C)CCC[C@@H](C)CCC\C(C)=C\CC1=C(C)C(=O)C(C)=C(C)C1=O SJPDQAGAIQSHOW-MRIFWDATSA-N 0.000 abstract 1
- KMBWCXAUPFWDKK-MRIFWDATSA-N 2,3-dimethoxy-5-methyl-6-[(e,7r,11r)-3,7,11,15-tetramethylhexadec-2-enyl]cyclohexa-2,5-diene-1,4-dione Chemical compound COC1=C(OC)C(=O)C(C\C=C(/C)CCC[C@H](C)CCC[C@H](C)CCCC(C)C)=C(C)C1=O KMBWCXAUPFWDKK-MRIFWDATSA-N 0.000 abstract 1
- WAGFVZIDVBHCMN-JLHYYAGUSA-N 2-[(2e)-3,7-dimethylocta-2,6-dienyl]-3,5,6-trimethylcyclohexa-2,5-diene-1,4-dione Chemical compound CC(C)=CCC\C(C)=C\CC1=C(C)C(=O)C(C)=C(C)C1=O WAGFVZIDVBHCMN-JLHYYAGUSA-N 0.000 abstract 1
- PTWSIIUEOFZCHW-NTCAYCPXSA-N 2-[(2e)-3,7-dimethylocta-2,6-dienyl]-3-methylnaphthalene-1,4-dione Chemical compound C1=CC=C2C(=O)C(C/C=C(C)/CCC=C(C)C)=C(C)C(=O)C2=C1 PTWSIIUEOFZCHW-NTCAYCPXSA-N 0.000 abstract 1
- 229910000497 Amalgam Inorganic materials 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000007859 condensation product Substances 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- MBWXNTAXLNYFJB-LKUDQCMESA-N phylloquinone Chemical compound C1=CC=C2C(=O)C(C/C=C(C)/CCCC(C)CCCC(C)CCCC(C)C)=C(C)C(=O)C2=C1 MBWXNTAXLNYFJB-LKUDQCMESA-N 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 239000000741 silica gel Substances 0.000 abstract 1
- 229910002027 silica gel Inorganic materials 0.000 abstract 1
- 150000003505 terpenes Chemical class 0.000 abstract 1
- SQQWBSBBCSFQGC-JLHYYAGUSA-N ubiquinone-2 Chemical compound COC1=C(OC)C(=O)C(C\C=C(/C)CCC=C(C)C)=C(C)C1=O SQQWBSBBCSFQGC-JLHYYAGUSA-N 0.000 abstract 1
- 229940088594 vitamin Drugs 0.000 abstract 1
- 229930003231 vitamin Natural products 0.000 abstract 1
- 235000013343 vitamin Nutrition 0.000 abstract 1
- 239000011782 vitamin Substances 0.000 abstract 1
- 239000011701 zinc Substances 0.000 abstract 1
- 229910052725 zinc Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C50/00—Quinones
- C07C50/26—Quinones containing groups having oxygen atoms singly bound to carbon atoms
- C07C50/28—Quinones containing groups having oxygen atoms singly bound to carbon atoms with monocyclic quinoid structure
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C46/00—Preparation of quinones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C46/00—Preparation of quinones
- C07C46/02—Preparation of quinones by oxidation giving rise to quinoid structures
- C07C46/06—Preparation of quinones by oxidation giving rise to quinoid structures of at least one hydroxy group on a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C46/00—Preparation of quinones
- C07C46/02—Preparation of quinones by oxidation giving rise to quinoid structures
- C07C46/06—Preparation of quinones by oxidation giving rise to quinoid structures of at least one hydroxy group on a six-membered aromatic ring
- C07C46/08—Preparation of quinones by oxidation giving rise to quinoid structures of at least one hydroxy group on a six-membered aromatic ring with molecular oxygen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C46/00—Preparation of quinones
- C07C46/10—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C50/00—Quinones
- C07C50/02—Quinones with monocyclic quinoid structure
- C07C50/06—Quinones with monocyclic quinoid structure with unsaturation outside the quinoid structure
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C50/00—Quinones
- C07C50/10—Quinones the quinoid structure being part of a condensed ring system containing two rings
- C07C50/14—Quinones the quinoid structure being part of a condensed ring system containing two rings with unsaturation outside the ring system, e.g. vitamin K1
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7536568 | 1968-10-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1233858A true GB1233858A (enExample) | 1971-06-03 |
Family
ID=13574105
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1233858D Expired GB1233858A (enExample) | 1968-10-16 | 1969-10-15 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3657287A (enExample) |
| CH (1) | CH519458A (enExample) |
| DE (1) | DE1951928A1 (enExample) |
| FR (1) | FR2020840A1 (enExample) |
| GB (1) | GB1233858A (enExample) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5245698B2 (enExample) * | 1973-04-06 | 1977-11-17 | ||
| US4057568A (en) * | 1974-11-22 | 1977-11-08 | Eisai Co., Ltd. | Process for synthesis of boric acid ester |
| US3998858A (en) * | 1975-12-12 | 1976-12-21 | Eisai Co., Ltd. | Process for synthesis of coenzymes q |
| ATE46315T1 (de) * | 1984-10-11 | 1989-09-15 | Hoffmann La Roche | Verfahren zur herstellung optisch aktiver chinonderivate. |
| CN114276225B (zh) * | 2021-10-29 | 2024-03-19 | 太阳树(莆田)生物医药有限公司 | 一种维生素k1的有机锌试剂合成方法 |
-
1969
- 1969-10-15 FR FR6935375A patent/FR2020840A1/fr not_active Withdrawn
- 1969-10-15 CH CH1543869A patent/CH519458A/de not_active IP Right Cessation
- 1969-10-15 GB GB1233858D patent/GB1233858A/en not_active Expired
- 1969-10-15 DE DE19691951928 patent/DE1951928A1/de active Pending
- 1969-10-15 US US866735A patent/US3657287A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CH519458A (de) | 1972-02-29 |
| US3657287A (en) | 1972-04-18 |
| FR2020840A1 (enExample) | 1970-07-17 |
| DE1951928A1 (de) | 1970-04-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |