GB1228985A - - Google Patents
Info
- Publication number
- GB1228985A GB1228985A GB3311368A GB1228985DA GB1228985A GB 1228985 A GB1228985 A GB 1228985A GB 3311368 A GB3311368 A GB 3311368A GB 1228985D A GB1228985D A GB 1228985DA GB 1228985 A GB1228985 A GB 1228985A
- Authority
- GB
- United Kingdom
- Prior art keywords
- feed
- oils
- hydrocracking
- catalyst
- basic nitrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 4
- 238000004517 catalytic hydrocracking Methods 0.000 abstract 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 3
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical compound C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 3
- 238000000034 method Methods 0.000 abstract 3
- 239000003921 oil Substances 0.000 abstract 3
- KDCGOANMDULRCW-UHFFFAOYSA-N 7H-purine Chemical compound N1=CNC2=NC=NC2=C1 KDCGOANMDULRCW-UHFFFAOYSA-N 0.000 abstract 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 abstract 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 abstract 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 abstract 2
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 abstract 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 abstract 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 abstract 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 229910021536 Zeolite Inorganic materials 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 229910052751 metal Inorganic materials 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- 229910017464 nitrogen compound Inorganic materials 0.000 abstract 2
- 150000002830 nitrogen compounds Chemical class 0.000 abstract 2
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 abstract 2
- -1 pyridiazines Chemical compound 0.000 abstract 2
- 239000010457 zeolite Substances 0.000 abstract 2
- VLRSADZEDXVUPG-UHFFFAOYSA-N 2-naphthalen-1-ylpyridine Chemical compound N1=CC=CC=C1C1=CC=CC2=CC=CC=C12 VLRSADZEDXVUPG-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 abstract 1
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 abstract 1
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910000323 aluminium silicate Inorganic materials 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- WCZVZNOTHYJIEI-UHFFFAOYSA-N cinnoline Chemical compound N1=NC=CC2=CC=CC=C21 WCZVZNOTHYJIEI-UHFFFAOYSA-N 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000012013 faujasite Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052680 mordenite Inorganic materials 0.000 abstract 1
- XLEMRIJDZGESRG-UHFFFAOYSA-N n,n-diethylnaphthalen-1-amine Chemical compound C1=CC=C2C(N(CC)CC)=CC=CC2=C1 XLEMRIJDZGESRG-UHFFFAOYSA-N 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 abstract 1
- 150000002923 oximes Chemical class 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 239000003208 petroleum Substances 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract 1
- JWVCLYRUEFBMGU-UHFFFAOYSA-N quinazoline Chemical compound N1=CN=CC2=CC=CC=C21 JWVCLYRUEFBMGU-UHFFFAOYSA-N 0.000 abstract 1
- 239000003079 shale oil Substances 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 239000011269 tar Substances 0.000 abstract 1
- 150000003918 triazines Chemical class 0.000 abstract 1
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C10G47/16—Crystalline alumino-silicate carriers
- C10G47/18—Crystalline alumino-silicate carriers the catalyst containing platinum group metals or compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/084—Y-type faujasite
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline
Abstract
1,228,985. Hydrocracking. ESSO RESEARCH & ENG. CO. 11 July, 1968, No. 33113/68. Heading C5E In a hydrocracking process, a petroleum derived feedstock is contacted under hydrocracking conditions with a catalyst comprising a crystalline aluminosilicate zeolite having uniform pore openings of between 6 and 15 Angstrom units and containing a metallic hydrogenation component in the presence of 500 to 30,000 p.p.m. based on the weight of feed of a basic nitrogen compound, this amount of basic nitrogen compound being maintained at a substantially constant level throughout the hydrocracking process, the process conditions including a temperature exceeding 875 F. and up to 1000 F., a pressure of 200 to 3000 p.s.i.g., a feed rate of 0À5 to 5À0 volumes of feed per volume of catalyst per hour and an exit hydrogen rate of 1000 to 10,000 SCF per barrel of feed, and a high octane naphtha product is recovered. A part of the basic nitrogen may be present naturally; it is preferred to hydrofine the feed to reduce the amount of nitrogen below the desired level then add controlled amounts of ammonia, aniline, methylamine, propylamine, dimethylaniline, diethylnaphthylamine, pyridine, piperidine, quinoline, pyrrolidine, pyrrol, pyridiazines, pyrimidine, pyrazine, triazines, cinnoline, quinazoline, naphthylpyridine, purine, oximes or nitriles. The catalyst may be faujasite, mordenite or a synthetic zeolite baseexchanged with a metal, e.g. magnesium or ammonium or hydrogen ion and impregnated with a compound of Cu, Ni, Co, Mo, Pt or Pd, compounds of platinum group metals being subsequently reduced to elemental state. There may be a preliminary hydrofining over Co or Ni molybdate or tungstate on alumina or silica. Suitable feedstocks include virgin and coker gas oils, cycle oils, heating oils, shale oils, and steam cracked tars.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US575949A US3404085A (en) | 1966-08-30 | 1966-08-30 | Hydrocracking process for high octane product |
| DE19681770824 DE1770824A1 (en) | 1966-08-30 | 1968-07-09 | Process for the production of a high octane naphtha |
| GB3311368 | 1968-07-11 | ||
| FR159539 | 1968-07-17 | ||
| NL6810089A NL6810089A (en) | 1966-08-30 | 1968-07-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1228985A true GB1228985A (en) | 1971-04-21 |
Family
ID=33163179
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3311368A Expired GB1228985A (en) | 1966-08-30 | 1968-07-11 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3404085A (en) |
| DE (1) | DE1770824A1 (en) |
| FR (1) | FR1572051A (en) |
| GB (1) | GB1228985A (en) |
| NL (1) | NL6810089A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8329029B2 (en) | 2009-09-11 | 2012-12-11 | Exxonmobil Research And Engineering Company | Selective desulfurization of naphtha using reaction inhibitors |
| CN108097329A (en) * | 2016-11-25 | 2018-06-01 | 中国石油化工股份有限公司 | A kind of hydrocracking catalyst and preparation method thereof and start-up method |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3528908A (en) * | 1967-11-17 | 1970-09-15 | Mobil Oil Corp | Catalytic hydrocracking process employing ascending reaction temperatures |
| US3644200A (en) * | 1968-12-23 | 1972-02-22 | Union Oil Co | Ammoniated zeolite catalysts |
| IT967655B (en) * | 1972-09-20 | 1974-03-11 | Sir Soc Italiana Resine Spa | PROCEDURE FOR THE DIMERIZATION OF OLEFINS AND RELATIVE CATALYST |
| US5141909A (en) * | 1991-01-22 | 1992-08-25 | Chevron Research And Technology Company | Zeolitic catalyst having selectivity for jet fuel |
| US8066867B2 (en) * | 2008-11-10 | 2011-11-29 | Uop Llc | Combination of mild hydrotreating and hydrocracking for making low sulfur diesel and high octane naphtha |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3213013A (en) * | 1962-07-25 | 1965-10-19 | Exxon Research Engineering Co | Regulating a hydrocracking process, with a crystalline zeolite catalyst, containing a platinum group metal, to obtain a constant octane gasoline |
| US3269934A (en) * | 1963-12-24 | 1966-08-30 | Union Oil Co | Hydrocracking process with the use of a y type crystalline zeolite and a nitrogen containing hydrocarbon oil |
-
1966
- 1966-08-30 US US575949A patent/US3404085A/en not_active Expired - Lifetime
-
1968
- 1968-07-09 DE DE19681770824 patent/DE1770824A1/en active Pending
- 1968-07-11 GB GB3311368A patent/GB1228985A/en not_active Expired
- 1968-07-17 FR FR159539A patent/FR1572051A/fr not_active Expired
- 1968-07-17 NL NL6810089A patent/NL6810089A/xx unknown
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8329029B2 (en) | 2009-09-11 | 2012-12-11 | Exxonmobil Research And Engineering Company | Selective desulfurization of naphtha using reaction inhibitors |
| CN108097329A (en) * | 2016-11-25 | 2018-06-01 | 中国石油化工股份有限公司 | A kind of hydrocracking catalyst and preparation method thereof and start-up method |
| CN108097329B (en) * | 2016-11-25 | 2020-04-14 | 中国石油化工股份有限公司 | Hydrocracking catalyst, preparation method and start-up method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| US3404085A (en) | 1968-10-01 |
| FR1572051A (en) | 1969-06-20 |
| DE1770824A1 (en) | 1972-01-20 |
| NL6810089A (en) | 1970-01-20 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] |