GB1222133A - Inhibition of corrosion of copper and its alloys using 3-amino-1:2:4-triazole - Google Patents

Inhibition of corrosion of copper and its alloys using 3-amino-1:2:4-triazole

Info

Publication number
GB1222133A
GB1222133A GB2509568A GB2509568A GB1222133A GB 1222133 A GB1222133 A GB 1222133A GB 2509568 A GB2509568 A GB 2509568A GB 2509568 A GB2509568 A GB 2509568A GB 1222133 A GB1222133 A GB 1222133A
Authority
GB
United Kingdom
Prior art keywords
triazole
amino
alkali metal
corrosion
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2509568A
Inventor
Angus John Duke
Alan Francis Popplewell
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Geigy Co Ltd
Original Assignee
Geigy Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Geigy Co Ltd filed Critical Geigy Co Ltd
Priority to GB2509568A priority Critical patent/GB1222133A/en
Priority to CH704669A priority patent/CH495434A/en
Priority to FR6916922A priority patent/FR2009333A1/fr
Publication of GB1222133A publication Critical patent/GB1222133A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • C23F11/14Nitrogen-containing compounds
    • C23F11/149Heterocyclic compounds containing nitrogen as hetero atom

Abstract

1,222,133. Detergents; corrosion inhibitors; polish compositions; anti-freeze. GEIGY (U.K.) Ltd. 22 May, 1969 [25 May, 1968], No. 25095/68. Headings C4X, C5D and C5W. [Also in Division C7] 3 - Amino - 1,2,4 - triazole is added to detergent compositions to inhibit corrosion of Cu alloys in contact therewith. The detergent may contain a polyphosphate sequestering agent, e.g. Na 4 P 2 O 7, Na 5 PaO 10 , Na 2 H 2 P 2 O 7 , K 5 P 3 O 10 , NaPO 3 , KPO 3 , "hexasodium tetraphosphate" and "hexasodium hexametaphosphate", and up to 40% of a surface active agent, which may be a polyalkylene glycol derivative of a long-chain fatty amine, an alkyl pyridinium halide, ROSO 3 M where R is aliphatic hydrocarbon and M is alkali metal or NH 4 , an alkali metal alkylbenzene sulphonate, an alkali metal salt of a secondary alkyl sulphate or an alkali metal or NH 4 salt of an alcohol sulphate. In an example, nickel-silver cutlery is cleaned using a 0.5% solution of the composition: 80 parts Na 5 P 3 O 10 , 19À6 Na dodecyl benzene sulphonate and 0À4 3 - amino - 1,2,4 - triazole. 3 - Amino - 1,2,4 - triazole may also be added to polishes to inhibit corrosion of Cu alloys. The polish may be based on water and alcohol, e.g. iso-propanol, and may contain an abrasive such as α-Al 2 O 3 , Fe 2 O 3 , or SiO 2 , or the polish may be based on water and contain 5-30% of a surface active agent, e.g. an alkanolamine or alkali metal salt of a higher fatty acid, lauryl sulphate, Na dodecyl benzene sulphonate or the condensation product of ethylene oxide with an alkylphenol, fatty acid, or fatty amine, and 0À5 to 5% of a gelling agent such as methylcellulose or polyvinyl pyrrolidone of M.W. about 40,000. An anti-freeze composition contains 3-amino- 1,2,4-triazole as a corrosion inhibitor. The composition typically has an aqueous base and contains methanol, ethanol, ethylene glycol or glycerol, the ratio organic compound: water being 0À1 to 0À7: 1, and the amount of triazole used is 0À01 to 5 wt. per cent. The composition may comprise also one or more of benzotriazole, NaNO 2 , NaNO 3 , sodium silicate, sodium benzoate, triethanolamine phosphate, the Na salt of 2 - mercaptobenzothiazole, or metal phosphates, arsenates, arsenites, molybdates and/or chromates.
GB2509568A 1968-05-25 1968-05-25 Inhibition of corrosion of copper and its alloys using 3-amino-1:2:4-triazole Expired GB1222133A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB2509568A GB1222133A (en) 1968-05-25 1968-05-25 Inhibition of corrosion of copper and its alloys using 3-amino-1:2:4-triazole
CH704669A CH495434A (en) 1968-05-25 1969-05-08 Copper corrosion inhibition process
FR6916922A FR2009333A1 (en) 1968-05-25 1969-05-23

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2509568A GB1222133A (en) 1968-05-25 1968-05-25 Inhibition of corrosion of copper and its alloys using 3-amino-1:2:4-triazole

Publications (1)

Publication Number Publication Date
GB1222133A true GB1222133A (en) 1971-02-10

Family

ID=10222150

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2509568A Expired GB1222133A (en) 1968-05-25 1968-05-25 Inhibition of corrosion of copper and its alloys using 3-amino-1:2:4-triazole

Country Status (3)

Country Link
CH (1) CH495434A (en)
FR (1) FR2009333A1 (en)
GB (1) GB1222133A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4298568A (en) 1979-08-25 1981-11-03 Henkel Kommanditgesellschaft Auf Aktien Method and composition for inhibiting corrosion of nonferrous metals in contact with water
US4647429A (en) * 1983-11-14 1987-03-03 Henkel Kommanditgesellschaft Auf Aktien Corrosion inhibitors for aluminum
WO2001048807A1 (en) * 1999-12-28 2001-07-05 Intel Corporation Abrasives for chemical mechanical polishing
CN103205541A (en) * 2013-04-23 2013-07-17 合肥工业大学 Deformed steel bar compound corrosion-inhibited quenching agent and usage method thereof
CN104131288A (en) * 2014-07-01 2014-11-05 安徽拓普森电池有限责任公司 Polishing fluid capable of avoiding metal corrosion and preparation method thereof
CN109234739A (en) * 2018-09-26 2019-01-18 宜兴汉光高新石化有限公司 A kind of water imbibition improves by force the corrosion inhibiter and preparation method thereof of surface coverage and absorption stability
CN112391633A (en) * 2020-11-12 2021-02-23 威海翔泽新材料科技有限公司 Corrosion inhibitor for cooling water of marine diesel engine and preparation method thereof

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2094776B (en) * 1981-03-11 1984-05-16 Dearborn Chemicals Ltd Prevention of corrosion in aqueous systems
FR2513258A1 (en) * 1981-09-21 1983-03-25 Dart Ind Inc Aq. hydrogen per:oxide soln. contg. amino-triazole - as stabiliser against decomposition by metal ions and catalyst for dissolution of metal, esp. copper
DE4039271A1 (en) * 1990-12-08 1992-06-11 Basf Ag METHOD FOR PROTECTING COPPER AND COOL ALLOY SURFACES FROM CORROSION
TW256858B (en) * 1994-08-30 1995-09-11 Mitsui Mining & Smelting Co Copper foil for printed circuit board
FR2729677B1 (en) * 1995-01-24 1997-04-18 Sgs Thomson Microelectronics USE OF AMINO-3,4-H-TRIAZOL-1,2,4 AGAINST CORROSION OF COPPER
US6238621B1 (en) * 1998-05-27 2001-05-29 Solutia Inc. Corrosion inhibiting compositions

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4298568A (en) 1979-08-25 1981-11-03 Henkel Kommanditgesellschaft Auf Aktien Method and composition for inhibiting corrosion of nonferrous metals in contact with water
US4647429A (en) * 1983-11-14 1987-03-03 Henkel Kommanditgesellschaft Auf Aktien Corrosion inhibitors for aluminum
WO2001048807A1 (en) * 1999-12-28 2001-07-05 Intel Corporation Abrasives for chemical mechanical polishing
US6881674B2 (en) 1999-12-28 2005-04-19 Intel Corporation Abrasives for chemical mechanical polishing
US7087188B2 (en) 1999-12-28 2006-08-08 Intel Corporation Abrasives for chemical mechanical polishing
CN103205541A (en) * 2013-04-23 2013-07-17 合肥工业大学 Deformed steel bar compound corrosion-inhibited quenching agent and usage method thereof
CN103205541B (en) * 2013-04-23 2014-08-06 合肥工业大学 Deformed steel bar compound corrosion-inhibited quenching agent and usage method thereof
CN104131288A (en) * 2014-07-01 2014-11-05 安徽拓普森电池有限责任公司 Polishing fluid capable of avoiding metal corrosion and preparation method thereof
CN104131288B (en) * 2014-07-01 2015-09-23 安徽拓普森电池有限责任公司 A kind of can the polishing fluid preventing metallic corrosion and preparation method thereof
CN109234739A (en) * 2018-09-26 2019-01-18 宜兴汉光高新石化有限公司 A kind of water imbibition improves by force the corrosion inhibiter and preparation method thereof of surface coverage and absorption stability
CN112391633A (en) * 2020-11-12 2021-02-23 威海翔泽新材料科技有限公司 Corrosion inhibitor for cooling water of marine diesel engine and preparation method thereof
CN112391633B (en) * 2020-11-12 2022-07-29 威海翔泽新材料科技有限公司 Corrosion inhibitor for cooling water of marine diesel engine and preparation method thereof

Also Published As

Publication number Publication date
CH495434A (en) 1970-08-31
FR2009333A1 (en) 1970-01-30

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