GB1219852A - Production of thioamides - Google Patents

Production of thioamides

Info

Publication number
GB1219852A
GB1219852A GB1232568A GB1232568A GB1219852A GB 1219852 A GB1219852 A GB 1219852A GB 1232568 A GB1232568 A GB 1232568A GB 1232568 A GB1232568 A GB 1232568A GB 1219852 A GB1219852 A GB 1219852A
Authority
GB
United Kingdom
Prior art keywords
halomethyl group
haloalkane
terminal
thioamides
march
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB1232568A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE, Badische Anilin and Sodafabrik AG filed Critical BASF SE
Publication of GB1219852A publication Critical patent/GB1219852A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D295/00Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
    • C07D295/04Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms
    • C07D295/10Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with substituted hydrocarbon radicals attached to ring nitrogen atoms substituted by doubly bound oxygen or sulphur atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogenated Pyridines (AREA)

Abstract

1,219,852. Thioamides. BADISCHE ANILIN- & SODA-FABRIK A.G. 14 March, 1968 [18 March, 1967], No. 12325/68. Heading C2C. N-substituted thioamides are prepared by reacting a haloalkane having at least one terminal halomethyl group with S and a primary or secondary amine, the S being used in about the stoichiometric amount per halomethyl group. The process may involve a haloalkane having more than one terminal halomethyl group and a monoamine or a haloalkane having one terminal halomethyl group and a polyamine. An acid binding agent such as an amine, amide and other organic and inorganic bases may be present. In the examples cyclohexylamine, di-n-butylamine and piperidine are converted to (a) N-cyclohexylthioformamide; (b) N,N-dibutylthioformamide; and (c) thioacetylpiperidine respectively using methylene chloride in (a) and (b), and 1,1-dichloroethane in (c).
GB1232568A 1967-03-18 1968-03-14 Production of thioamides Expired GB1219852A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE1967B0091670 DE1272286C2 (en) 1967-03-18 1967-03-18 Process for the preparation of N-substituted aliphatic thiocarboxamides

Publications (1)

Publication Number Publication Date
GB1219852A true GB1219852A (en) 1971-01-20

Family

ID=6985973

Family Applications (1)

Application Number Title Priority Date Filing Date
GB1232568A Expired GB1219852A (en) 1967-03-18 1968-03-14 Production of thioamides

Country Status (6)

Country Link
BE (1) BE712266A (en)
CH (1) CH485684A (en)
DE (1) DE1272286C2 (en)
FR (1) FR1556715A (en)
GB (1) GB1219852A (en)
NL (1) NL6803574A (en)

Also Published As

Publication number Publication date
DE1272286C2 (en) 1969-03-06
NL6803574A (en) 1968-09-19
DE1272286B (en) 1968-07-11
FR1556715A (en) 1969-02-07
BE712266A (en) 1968-09-16
CH485684A (en) 1970-02-15

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