GB1213409A - Metalation of alkyl side chains of alkyl pyridines, alkyl quinolines and alkyl isoquinolines - Google Patents
Metalation of alkyl side chains of alkyl pyridines, alkyl quinolines and alkyl isoquinolinesInfo
- Publication number
- GB1213409A GB1213409A GB28082/68A GB2808268A GB1213409A GB 1213409 A GB1213409 A GB 1213409A GB 28082/68 A GB28082/68 A GB 28082/68A GB 2808268 A GB2808268 A GB 2808268A GB 1213409 A GB1213409 A GB 1213409A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkyl
- isoquinolines
- pyridines
- quinolines
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 alkyl pyridines Chemical class 0.000 title abstract 9
- 125000000217 alkyl group Chemical group 0.000 title abstract 2
- 229940111121 antirheumatic drug quinolines Drugs 0.000 title abstract 2
- 238000006263 metalation reaction Methods 0.000 title 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- BSKHPKMHTQYZBB-UHFFFAOYSA-N 2-methylpyridine Chemical compound CC1=CC=CC=N1 BSKHPKMHTQYZBB-UHFFFAOYSA-N 0.000 abstract 2
- FKNQCJSGGFJEIZ-UHFFFAOYSA-N 4-methylpyridine Chemical compound CC1=CC=NC=C1 FKNQCJSGGFJEIZ-UHFFFAOYSA-N 0.000 abstract 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- AWJUIBRHMBBTKR-UHFFFAOYSA-N isoquinoline Chemical compound C1=NC=CC2=CC=CC=C21 AWJUIBRHMBBTKR-UHFFFAOYSA-N 0.000 abstract 2
- BVFOXQFXMQQDTN-UHFFFAOYSA-N 1,1-diphenyl-2-pyridin-2-ylethanol Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(O)CC1=CC=CC=N1 BVFOXQFXMQQDTN-UHFFFAOYSA-N 0.000 abstract 1
- APMOETXMGRRPIQ-UHFFFAOYSA-N 1,1-diphenyl-2-pyridin-4-ylethanol Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(O)CC1=CC=NC=C1 APMOETXMGRRPIQ-UHFFFAOYSA-N 0.000 abstract 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 abstract 1
- 239000012965 benzophenone Substances 0.000 abstract 1
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- 239000012442 inert solvent Substances 0.000 abstract 1
- 150000002537 isoquinolines Chemical class 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 150000003248 quinolines Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/28—Radicals substituted by singly-bound oxygen or sulphur atoms
- C07D213/30—Oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic Table
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pyridine Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US64620867A | 1967-06-15 | 1967-06-15 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1213409A true GB1213409A (en) | 1970-11-25 |
Family
ID=24592189
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB28082/68A Expired GB1213409A (en) | 1967-06-15 | 1968-06-13 | Metalation of alkyl side chains of alkyl pyridines, alkyl quinolines and alkyl isoquinolines |
Country Status (6)
| Country | Link |
|---|---|
| BE (1) | BE716716A (enExample) |
| CH (1) | CH498868A (enExample) |
| DE (1) | DE1770641B1 (enExample) |
| DK (1) | DK128375B (enExample) |
| GB (1) | GB1213409A (enExample) |
| NL (1) | NL6808408A (enExample) |
-
1968
- 1968-06-13 GB GB28082/68A patent/GB1213409A/en not_active Expired
- 1968-06-14 NL NL6808408A patent/NL6808408A/xx unknown
- 1968-06-14 DE DE19681770641 patent/DE1770641B1/de active Granted
- 1968-06-17 CH CH898268A patent/CH498868A/de not_active IP Right Cessation
- 1968-06-17 DK DK282968AA patent/DK128375B/da unknown
- 1968-06-17 BE BE716716D patent/BE716716A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE1770641C2 (enExample) | 1973-07-19 |
| BE716716A (enExample) | 1968-12-02 |
| DE1770641B1 (de) | 1972-12-21 |
| CH498868A (de) | 1970-11-15 |
| NL6808408A (enExample) | 1968-12-16 |
| DK128375B (da) | 1974-04-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |