GB1206866A - Phenazine derivatives - Google Patents
Phenazine derivativesInfo
- Publication number
- GB1206866A GB1206866A GB2795968A GB2795968A GB1206866A GB 1206866 A GB1206866 A GB 1206866A GB 2795968 A GB2795968 A GB 2795968A GB 2795968 A GB2795968 A GB 2795968A GB 1206866 A GB1206866 A GB 1206866A
- Authority
- GB
- United Kingdom
- Prior art keywords
- formula
- prepared
- compound
- iii
- formula iii
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D241/00—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings
- C07D241/36—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings condensed with carbocyclic rings or ring systems
- C07D241/38—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings condensed with carbocyclic rings or ring systems with only hydrogen or carbon atoms directly attached to the ring nitrogen atoms
- C07D241/46—Phenazines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
Abstract
1,206,866. Phenazine derivatives. SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ N.V. 29 April, 1969 [12 June, 1968], No. 27959/68. Heading C2C. [Also in Division A5] Novel phenazine derivatives of Formula I and II wherein X is halogen, n is 1, 2 or 3 and the dotted bonds α and # represent alternative positions for a double bond, are prepared as follows: (a) for compounds of Formula I, by (i) dealkylating a compound of Formula III. wherein R is alkyl, by treatment with a base, or (ii) reducing a compound of Formula II; (b) for compounds of Formula II, by (i) oxidizing a compound of Formula I or III, or (ii) simultaneously oxidizing and halogenating a 1- alkoxyphenazine of Formula III in which n is 0, 1 or 2, preferably by the use of a mixture of a hydrohalic acid and an oxidizing agent in which the oxidizing agent is present in excess of that needed for halogenation alone. 1 - Alkoxy - halophenazines of Formula III are prepared by halogenating a 1-alkoxyphenazine of Formula III in which n is 0, 1 or 2. 1-Methoxy-2-chlorophenazine is also prepared by reacting 2-nitrophenazine with sodium hypochlorite and methanol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2795968A GB1206866A (en) | 1968-06-12 | 1968-06-12 | Phenazine derivatives |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2795968A GB1206866A (en) | 1968-06-12 | 1968-06-12 | Phenazine derivatives |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1206866A true GB1206866A (en) | 1970-09-30 |
Family
ID=10268027
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2795968A Expired GB1206866A (en) | 1968-06-12 | 1968-06-12 | Phenazine derivatives |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1206866A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11053205B2 (en) | 2017-02-17 | 2021-07-06 | University Of Florida Research Foundation, Incorporated | Phenazine derivatives as antimicrobial agents |
| US12060334B2 (en) | 2021-03-12 | 2024-08-13 | University Of Florida Research Foundation, Incorporated | 3-substituted phenazine derivatives as antimicrobial agents |
-
1968
- 1968-06-12 GB GB2795968A patent/GB1206866A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11053205B2 (en) | 2017-02-17 | 2021-07-06 | University Of Florida Research Foundation, Incorporated | Phenazine derivatives as antimicrobial agents |
| US12060334B2 (en) | 2021-03-12 | 2024-08-13 | University Of Florida Research Foundation, Incorporated | 3-substituted phenazine derivatives as antimicrobial agents |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |