GB1194939A - Hydrocyanation of Olefins - Google Patents

Hydrocyanation of Olefins

Info

Publication number
GB1194939A
GB1194939A GB5164368A GB5164368A GB1194939A GB 1194939 A GB1194939 A GB 1194939A GB 5164368 A GB5164368 A GB 5164368A GB 5164368 A GB5164368 A GB 5164368A GB 1194939 A GB1194939 A GB 1194939A
Authority
GB
United Kingdom
Prior art keywords
catalyst
carbon
carbon atoms
hydrocyanation
olefins
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5164368A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of GB1194939A publication Critical patent/GB1194939A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/08—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
    • C07C253/10—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds to compounds containing carbon-to-carbon double bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

1,194,939. Hydrocyanation of olefins. E. I. DU PONT DE NEMOURS & CO. 31 Oct., 1968 [1 Nov., 1967], No. 51643/68. Heading C2C. Organic cyano compounds are prepared by reacting an unsaturated organic compound having non-conjugated olefinic carbon-carbon unsaturation and containing 2-20 carbon atoms with HCN in the presence of a catalyst of the formula Pd (PX 3 ) 4 , where X is OR or R, R is an alkyl or aryl group having up to 18 carbon atoms and wherein any of the X's may be cojoined. The reaction is suitably carried out in the presence of a catalyst promoter and in a solvent at 0-150‹ C., optionally in the presence of an excess of a ligand present in the catalyst, e.g. an aryl phosphite. The molar ratio of organic starting material to catalyst is generally from 10: 1 to 2000: 1. Specified starting materials are ethylene, propylene, butene-1, pentene-2, hexene-2, dicyclopentadiene, styrene, α-methyl styrene, 2-methyl-3-butenenitrile and 3- and 4-pentenenitriles.
GB5164368A 1967-11-01 1968-10-31 Hydrocyanation of Olefins Expired GB1194939A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US67960867A 1967-11-01 1967-11-01

Publications (1)

Publication Number Publication Date
GB1194939A true GB1194939A (en) 1970-06-17

Family

ID=24727585

Family Applications (2)

Application Number Title Priority Date Filing Date
GB5164368A Expired GB1194939A (en) 1967-11-01 1968-10-31 Hydrocyanation of Olefins
GB631570A Expired GB1194940A (en) 1967-11-01 1968-10-31 Isomerisation of 3-pentenenitriles to 4-pentenenitriles

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB631570A Expired GB1194940A (en) 1967-11-01 1968-10-31 Isomerisation of 3-pentenenitriles to 4-pentenenitriles

Country Status (5)

Country Link
BE (1) BE723128A (en)
DE (1) DE1806098B2 (en)
FR (1) FR1597593A (en)
GB (2) GB1194939A (en)
NL (1) NL166928C (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU499165B2 (en) 1975-10-31 1979-04-05 Ici Limited Dimerisation process
DE3264631D1 (en) * 1981-03-31 1985-08-14 Ciba Geigy Ag 4-halogenostilbene derivatives and process for their preparation

Also Published As

Publication number Publication date
GB1194940A (en) 1970-06-17
DE1806098C3 (en) 1974-03-28
BE723128A (en) 1969-04-01
NL166928B (en) 1981-05-15
FR1597593A (en) 1970-06-29
DE1806098B2 (en) 1973-08-16
NL6815487A (en) 1969-05-05
NL166928C (en) 1981-10-15
DE1806098A1 (en) 1969-06-12

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee