GB1184318A - Carbamic Acid Chlorides of Thiadiazolinones and process for their preparation - Google Patents
Carbamic Acid Chlorides of Thiadiazolinones and process for their preparationInfo
- Publication number
- GB1184318A GB1184318A GB53591/68A GB5359168A GB1184318A GB 1184318 A GB1184318 A GB 1184318A GB 53591/68 A GB53591/68 A GB 53591/68A GB 5359168 A GB5359168 A GB 5359168A GB 1184318 A GB1184318 A GB 1184318A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkyl
- alkoxy
- substituted
- carbon atoms
- cycloalkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D285/00—Heterocyclic compounds containing rings having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by groups C07D275/00 - C07D283/00
- C07D285/01—Five-membered rings
- C07D285/02—Thiadiazoles; Hydrogenated thiadiazoles
- C07D285/04—Thiadiazoles; Hydrogenated thiadiazoles not condensed with other rings
- C07D285/12—1,3,4-Thiadiazoles; Hydrogenated 1,3,4-thiadiazoles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Nitrogen- Or Sulfur-Containing Heterocyclic Ring Compounds With Rings Of Six Or More Members (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1,184,318. 1,3,4 - Thiadiazoline - 5 - one - 2 - carbamoyl chlorides; thiosemicarbazides. FARBENFABRIKEN BAYER A.G. 12 Nov., 1968 [6 Dec., 1967], No. 53591/68. Heading C2C. The invention comprises compounds of the general formula wherein R is (i) an alkyl or alkenyl radical with up to 8 carbon atoms, which may be substituted by alkoxy, cycloalkyl, cycloalkenyl or phenyl (which phenyl may itself be substituted by halogen, alkyl, alkoxy and/or haloalkyl), (ii) a cycloalkyl radical with up to 10 carbon atoms, or (iii) an aryl radical which may be substituted by alkyl, halogen, haloalkyl, nitro and/or alkoxy, and R<SP>1</SP> is (i) an alkyl or alkenyl radical with up to 12 carbon atoms which may be substituted by alkoxy, aryl, alkylaryl, haloaryl or cycloalkyl, or (ii) a cycloalkyl radical with up to 10 carbon atoms. The compounds are prepared by reacting a compound of the general formula with phosgene in an inert organic solvent or diluent using at least 2 moles of phosgene per mole of thiosemicarbazide. The thiosemicarbazide starting materials may be prepared by (i) reaction of a monosubstituted hydrazine R-NH-NH 2 with an isothiocyanate R<SP>1</SP>-NCS, (ii) reaction of a monosubstituted hydrazine R-NH-NH 2 with CS 2 and an alkylating agent to give a compound where R<SP>2</SP> is alkyl, which is then reacted with a primary amine R<SP>1</SP>-NH 2 in an organic solvent at 0-120 C., or (iii) reduction of an appropriate thiosemicarbazone.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19671670956 DE1670956A1 (en) | 1967-12-06 | 1967-12-06 | Carbamic acid chlorides of thiadiazolinones and processes for their preparation |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1184318A true GB1184318A (en) | 1970-03-11 |
Family
ID=5686353
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB53591/68A Expired GB1184318A (en) | 1967-12-06 | 1968-11-12 | Carbamic Acid Chlorides of Thiadiazolinones and process for their preparation |
Country Status (6)
Country | Link |
---|---|
BE (1) | BE725051A (en) |
CH (1) | CH509338A (en) |
ES (1) | ES361137A1 (en) |
FR (1) | FR1594943A (en) |
GB (1) | GB1184318A (en) |
IL (1) | IL30984A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6490175A (en) * | 1987-07-24 | 1989-04-06 | Ici America Inc | Novel 2-(substituted imino)-1,3,4-dihydrothiadiazoles |
-
1968
- 1968-10-30 CH CH1621768A patent/CH509338A/en not_active IP Right Cessation
- 1968-10-31 IL IL30984A patent/IL30984A/en unknown
- 1968-11-12 GB GB53591/68A patent/GB1184318A/en not_active Expired
- 1968-12-06 ES ES361137A patent/ES361137A1/en not_active Expired
- 1968-12-06 BE BE725051D patent/BE725051A/xx unknown
- 1968-12-06 FR FR1594943D patent/FR1594943A/fr not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6490175A (en) * | 1987-07-24 | 1989-04-06 | Ici America Inc | Novel 2-(substituted imino)-1,3,4-dihydrothiadiazoles |
JP2849390B2 (en) | 1987-07-24 | 1999-01-20 | アイ シーアイ アメリカズ インコーポレイテツド | New 2- (substituted imino) -1,3,4-dihydrothiadiazoles |
Also Published As
Publication number | Publication date |
---|---|
IL30984A0 (en) | 1969-01-29 |
ES361137A1 (en) | 1970-12-16 |
FR1594943A (en) | 1970-06-08 |
BE725051A (en) | 1969-06-06 |
IL30984A (en) | 1972-02-29 |
CH509338A (en) | 1971-06-30 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
PLNP | Patent lapsed through nonpayment of renewal fees |