GB1181617A - Process and Apparatus for Continuous Production of Homogeneous Polyamide Foams. - Google Patents

Process and Apparatus for Continuous Production of Homogeneous Polyamide Foams.

Info

Publication number
GB1181617A
GB1181617A GB4479668A GB4479668A GB1181617A GB 1181617 A GB1181617 A GB 1181617A GB 4479668 A GB4479668 A GB 4479668A GB 4479668 A GB4479668 A GB 4479668A GB 1181617 A GB1181617 A GB 1181617A
Authority
GB
United Kingdom
Prior art keywords
prepolymer
continuous production
polymerizing
foaming
mould
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB4479668A
Inventor
Walter Damsky
Heinrich Gilch
Hermann Schnell
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of GB1181617A publication Critical patent/GB1181617A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/08Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino-carboxylic acids
    • C08G69/14Lactams
    • C08G69/16Preparatory processes
    • C08G69/18Anionic polymerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2377/00Characterised by the use of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Derivatives of such polymers
    • C08J2377/02Polyamides derived from omega-amino carboxylic acids or from lactams thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyamides (AREA)

Abstract

1,181,617. Continuous production of polyamide foams. FARBENFABRIKEN BAYER A.G. 20 Sept., 1968 [20 Oct., 1967], No. 44796/68. Headings C3C and C3R. Polyamide foam is continuously produced by melting a mixture of a lactam, e.g. caprolactam, with a catalyst, e.g. an alkali metal or alkaline earth metal formate, and an activator and an expanding or a compound which functions as both, e.g. an isocyanate, polymerizing the melt with vigorous stirring to form a prepolymer having a relative viscosity of 1À15-2À5 (as a solution of 1 g. of prepolymer in 100 ml. mcresol at 20‹ C.), transferring the prepolymer to a mould and polymerizing to completion with shaping and foaming. In the example caprolactam, sodium formate and a silica gel are heated, the melt is cooled and hexamethylene diisocyanate and an alkylene oxide-silicone block copolymer (as pore regulator) are added, the mixture is melted, fed to a reactor, stirred and the prepolymer produced is then fed to a mould where it is polymerized to completion with foaming. An apparatus is illustrated (not shown).
GB4479668A 1967-10-20 1968-09-20 Process and Apparatus for Continuous Production of Homogeneous Polyamide Foams. Expired GB1181617A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEF0053844 1967-10-20

Publications (1)

Publication Number Publication Date
GB1181617A true GB1181617A (en) 1970-02-18

Family

ID=7106639

Family Applications (1)

Application Number Title Priority Date Filing Date
GB4479668A Expired GB1181617A (en) 1967-10-20 1968-09-20 Process and Apparatus for Continuous Production of Homogeneous Polyamide Foams.

Country Status (8)

Country Link
BE (1) BE722515A (en)
CH (1) CH503079A (en)
DE (1) DE1720736A1 (en)
ES (1) ES359331A1 (en)
FR (1) FR1588711A (en)
GB (1) GB1181617A (en)
NL (1) NL6814880A (en)
SU (1) SU402227A3 (en)

Also Published As

Publication number Publication date
NL6814880A (en) 1969-04-22
CH503079A (en) 1971-02-15
BE722515A (en) 1969-04-01
FR1588711A (en) 1970-04-17
DE1720736A1 (en) 1971-07-15
SU402227A3 (en) 1973-10-12
ES359331A1 (en) 1970-06-01

Similar Documents

Publication Publication Date Title
SU572206A3 (en) Method of preparing copolyamides
ES2000915A6 (en) Methods of preparing rigid polyurethane foams, and precursor compositions therefor.
GB1266273A (en)
US3121768A (en) Method of casting
GB1222803A (en) Production of shaped articles from polycaproamide
US4022719A (en) Process for producing polyamide foam
GB1181617A (en) Process and Apparatus for Continuous Production of Homogeneous Polyamide Foams.
GB1352409A (en) Process for the anionic polymerisation of lactams
US3562221A (en) Accelerating anionic polymerization of lactams
US3232892A (en) Process for the preparation of foamed polycaprolactam
US3728292A (en) Polyamides foamed with n-substituted carbamic ester blowing agents
US3214415A (en) Polymerization of lactams with the beta-lactone of 2, 2, 4-trimethyl-3-hydroxy-3-pentenoic acid as activator
FI58786C (en) FREQUENCY PROCESSING OF POLYAMIDE PRODUCTS WITH INTEGRAL SKUMSTRUKTUR
US3547836A (en) Manufacture of expanded polyamides
GB1147707A (en) A process for the production of polyamide foams
US3679613A (en) Process for the production of polyamide foams
US3682847A (en) Process for the production of polyamide foam
US3804813A (en) Continuous process for forming polylactams
US3605183A (en) Mixing and casting lactam compositions
US3274132A (en) Process of polymerizing and foaming caprolactam
GB1238941A (en)
US3645928A (en) Process for the preparation of polylactam foams
US3300422A (en) Production of expanded polyamides
GB1536721A (en) Manufacture of polyamide foams
US4464491A (en) Nylon foam