GB1171793A - Aliphatic Nitrile Sulfites and Carbonates and Methods of Preparation and use thereof - Google Patents
Aliphatic Nitrile Sulfites and Carbonates and Methods of Preparation and use thereofInfo
- Publication number
- GB1171793A GB1171793A GB47151/66A GB4715166A GB1171793A GB 1171793 A GB1171793 A GB 1171793A GB 47151/66 A GB47151/66 A GB 47151/66A GB 4715166 A GB4715166 A GB 4715166A GB 1171793 A GB1171793 A GB 1171793A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aliphatic
- phosgene
- thionyl chloride
- carbonates
- oct
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D291/00—Heterocyclic compounds containing rings having nitrogen, oxygen and sulfur atoms as the only ring hetero atoms
- C07D291/02—Heterocyclic compounds containing rings having nitrogen, oxygen and sulfur atoms as the only ring hetero atoms not condensed with other rings
- C07D291/04—Five-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C263/00—Preparation of derivatives of isocyanic acid
- C07C263/08—Preparation of derivatives of isocyanic acid from or via heterocyclic compounds, e.g. pyrolysis of furoxans
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D273/00—Heterocyclic compounds containing rings having nitrogen and oxygen atoms as the only ring hetero atoms, not provided for by groups C07D261/00 - C07D271/00
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
- C10B49/16—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form
- C10B49/20—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form
- C10B49/22—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with moving solid heat-carriers in divided form in dispersed form according to the "fluidised bed" technique
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2602/00—Systems containing two condensed rings
- C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
- C07C2602/14—All rings being cycloaliphatic
- C07C2602/26—All rings being cycloaliphatic the ring system containing ten carbon atoms
- C07C2602/28—Hydrogenated naphthalenes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1,171,793. Aliphatic nitrile sulphites and carbonates and their conversion to isocyanates. SINCLAIR RESEARCH Inc. 21 Oct., 1966 [22 Oct., 1965 (8)], No. 47151/66. Heading C2C. Compounds of the formula wherein R<SP>1</SP> is an aliphatic hydrocarbon radical of 1 to 50 carbon atoms, at least one of the cyclic groups being attached to an aliphatic carbon atom of R<SP>1</SP>, unsubstituted or substituted by groups which are devoid of isocyanate-reactive hydrogen atoms, X is S or C and m is 0, 1, 2 or 3, may be obtained by reacting the appropriate aliphatic mono- or poly-hydroxamic acid with thionyl chloride (to produce the sulphite) or phosgene (to produce the carbonate) at a temperature below the decomposition temperature of the product, generally at atmospheric pressure and preferably in an oxygencontaining organic solvent or in the presence of an excess of the thionyl chloride or phosgene reactant. Compounds of the above formula wherein X is S and provided that R<SP>1</SP> is cycloaliphatic when m is 0 are claimed to be novel. All the above products may be thermally decomposed to yield isocyanates, the decomposition suitably being effected by heating the compound to a temperature below the degradation temperature of the isocyanate product, preferably in the presence of an inert solvent, e.g. xylene, toluene, chlorobenzene, thionyl chloride or phosgene.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB47151/66A GB1171793A (en) | 1965-10-22 | 1966-10-21 | Aliphatic Nitrile Sulfites and Carbonates and Methods of Preparation and use thereof |
NL6615003A NL6615003A (en) | 1965-10-22 | 1966-10-22 | |
US714004A US3507900A (en) | 1965-10-22 | 1968-03-18 | Process for preparing organic isocyanates |
Applications Claiming Priority (12)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US50238165A | 1965-10-22 | 1965-10-22 | |
US50232765A | 1965-10-22 | 1965-10-22 | |
US50260465A | 1965-10-22 | 1965-10-22 | |
US50234665A | 1965-10-22 | 1965-10-22 | |
US50246465A | 1965-10-22 | 1965-10-22 | |
US50238265A | 1965-10-22 | 1965-10-22 | |
US50232865A | 1965-10-22 | 1965-10-22 | |
US50261965A | 1965-10-22 | 1965-10-22 | |
US503381A US3335831A (en) | 1965-10-23 | 1965-10-23 | Bi-directional no-back drive device |
BE688747 | 1966-10-21 | ||
GB47151/66A GB1171793A (en) | 1965-10-22 | 1966-10-21 | Aliphatic Nitrile Sulfites and Carbonates and Methods of Preparation and use thereof |
DES0106654 | 1966-10-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1171793A true GB1171793A (en) | 1969-11-26 |
Family
ID=27582852
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB47151/66A Expired GB1171793A (en) | 1965-10-22 | 1966-10-21 | Aliphatic Nitrile Sulfites and Carbonates and Methods of Preparation and use thereof |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1171793A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2230778A (en) * | 1989-04-21 | 1990-10-31 | American Home Prod | Substituted and unsubstituted naphthalenyl-3h-1,2,3,5-oxathiadiazole-2-oxides. |
-
1966
- 1966-10-21 GB GB47151/66A patent/GB1171793A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2230778A (en) * | 1989-04-21 | 1990-10-31 | American Home Prod | Substituted and unsubstituted naphthalenyl-3h-1,2,3,5-oxathiadiazole-2-oxides. |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PCNP | Patent ceased through non-payment of renewal fee |