GB1170765A - Glass Compositions - Google Patents
Glass CompositionsInfo
- Publication number
- GB1170765A GB1170765A GB4008866A GB4008866A GB1170765A GB 1170765 A GB1170765 A GB 1170765A GB 4008866 A GB4008866 A GB 4008866A GB 4008866 A GB4008866 A GB 4008866A GB 1170765 A GB1170765 A GB 1170765A
- Authority
- GB
- United Kingdom
- Prior art keywords
- glass
- phosphor
- colour
- crystalline
- situ
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/078—Glass compositions containing silica with 40% to 90% silica, by weight containing an oxide of a divalent metal, e.g. an oxide of zinc
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
- C03C10/0009—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing silica as main constituent
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/12—Compositions for glass with special properties for luminescent glass; for fluorescent glass
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
1,170,765. Luminescent material. OWENSILLINOIS Inc. 8 Sept., 1966 [9 Sept., 1965], No. 40088/66. Heading C4S. [Also in Division C1] In situ surface crystallizable glass compositions having a coefficient of linear thermal expansion of from 45 to 100 + 10<SP>-7</SP> per ‹C. consist of the following oxides in weight percentage SiO 2 45-65, MgO 10-20, ZnO 0-30, Na 2 O 0-17, K 2 O 0-20, Li 2 O 0-3, CaO 0-10, TiO 2 0-5, ZrO 2 0-5, MnO 0-2, Cn 2 O 0-2, CuO 0-2 and Sh 2 O 3 0-2, wherein the amount of Na 2 O + K 2 O + Li 2 O is at least 10 weight per cent. Cathodoluminescent in situ surface crystallized glass bodies are prepared by heating the above compositions through the annealing point range of the glass composition to a higher temperature approaching but not substantially above its Littleton softening point (e.g. from 200‹ to 20‹ F. below its Littleton softening point) and holding the composition at this temperature until the desired degree of surface crystallization has been obtained. Luminescent glass articles containing a multicolour phosphor combination grown in the surface of the glass comprise the above cathodoluminescent in situ surface-crystallized glass body upon the surface of which has been deposited and subsequently heat-treated in situ at least one layer containing an activator for the crystalline phosphor contained in the surface layer of the glass composition, the heat treatment being effected into and at a temperature not substantially exceeding the Littleton softening point of the glass composition until there has been formed at least one layer of a crystalline activated phosphor, the phosphor combination causing the luminescent article to luminesce one colour at one voltage and a different colour at a different voltage. Thus a luminescent glass article containing a two-colour phosphor combination grown in the surface of the glass comprises the above cathodoluminescent, in situ surfacecrystallized glass body which contains from 1 to 5 weight per cent TiO 2 but no ZrO 2 , MnO, Cn 2 O, CnO or Sb 2 O 3 and upon the surface of which has been deposited and subsequently heat-treated in situ a layer comprising a manganese (M 2 <SP>++</SP>)-containing activator for the crystalline MgSiO 3 -type phosphor in the surface layer of the glass composition, the heat-treatment being effected up to and at a temperature approaching but below the Littleton softening point of the glass composition until there has been formed a layer of a crystalline manganeseactivated MgSiO 3 -type phosphor which when subjected to low-voltage electron bombardment luminesces the red colour of the crystalline manganese-activated MgSiO 3 -type phosphor and to luminesce the blue colour of the underlying crystalline Ti-modified MgSiO 3 -type phosphor when subjected to high-voltage electron bombardment. Instead of two-colour a higher number of colour-phosphor combinations may be built up in a similar manner. Oxides, sulphides and halides of metals may be included as colourants or to improve the working properties e.g. oxides of cobalt, nickel or chromium in amount up to 3% by wt. Activators other than TiO 2 , ZrO 2 , MnO, Cu 2 O and CuO may be employed. Applications instanced include lamp bulbs, light screens and c.r.t's.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US48621565A | 1965-09-09 | 1965-09-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1170765A true GB1170765A (en) | 1969-11-19 |
Family
ID=23931044
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4008866A Expired GB1170765A (en) | 1965-09-09 | 1966-09-08 | Glass Compositions |
Country Status (2)
Country | Link |
---|---|
GB (1) | GB1170765A (en) |
NL (1) | NL6612690A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2172282A (en) * | 1985-03-11 | 1986-09-17 | English Electric Co Ltd | Toughened glass-ceramics |
-
1966
- 1966-09-08 NL NL6612690A patent/NL6612690A/xx unknown
- 1966-09-08 GB GB4008866A patent/GB1170765A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2172282A (en) * | 1985-03-11 | 1986-09-17 | English Electric Co Ltd | Toughened glass-ceramics |
Also Published As
Publication number | Publication date |
---|---|
NL6612690A (en) | 1967-03-10 |
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