GB1163369A - Process for the preparation of Curable Binders - Google Patents

Process for the preparation of Curable Binders

Info

Publication number
GB1163369A
GB1163369A GB57352/67A GB5735267A GB1163369A GB 1163369 A GB1163369 A GB 1163369A GB 57352/67 A GB57352/67 A GB 57352/67A GB 5735267 A GB5735267 A GB 5735267A GB 1163369 A GB1163369 A GB 1163369A
Authority
GB
United Kingdom
Prior art keywords
adduct
etherified
trimethylolpropane
melamine
neutralized
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB57352/67A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Reichhold Albert Chemie AG
Original Assignee
Reichhold Albert Chemie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Reichhold Albert Chemie AG filed Critical Reichhold Albert Chemie AG
Publication of GB1163369A publication Critical patent/GB1163369A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C09D161/32—Modified amine-aldehyde condensates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
    • C08G12/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
    • C08G12/34—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds and acyclic or carbocyclic compounds
    • C08G12/36—Ureas; Thioureas
    • C08G12/38—Ureas; Thioureas and melamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
    • C08G12/40—Chemically modified polycondensates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
    • C08G12/40—Chemically modified polycondensates
    • C08G12/42—Chemically modified polycondensates by etherifying
    • C08G12/421—Chemically modified polycondensates by etherifying of polycondensates based on acyclic or carbocyclic compounds
    • C08G12/422—Chemically modified polycondensates by etherifying of polycondensates based on acyclic or carbocyclic compounds based on urea or thiourea
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
    • C08G12/40—Chemically modified polycondensates
    • C08G12/42—Chemically modified polycondensates by etherifying
    • C08G12/424—Chemically modified polycondensates by etherifying of polycondensates based on heterocyclic compounds
    • C08G12/425—Chemically modified polycondensates by etherifying of polycondensates based on heterocyclic compounds based on triazines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
    • C08G12/40—Chemically modified polycondensates
    • C08G12/42—Chemically modified polycondensates by etherifying
    • C08G12/428—Chemically modified polycondensates by etherifying of polycondensates based on heterocyclic and acyclic or carbocyclic compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/685—Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen
    • C08G63/6854—Polyesters containing atoms other than carbon, hydrogen and oxygen containing nitrogen derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/6858—Polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/06—Unsaturated polyesters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4419—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
    • C09D5/4469—Phenoplasts; Aminoplasts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Molecular Biology (AREA)
  • Paints Or Removers (AREA)

Abstract

1,163,369. Carboxyl-containing aminoplast resins; electrocoating compositions. REICHHOLD-ALBEKT-CHEMIE A.G. 18 Dec., 1967 [29 Dec., 1966], No. 57352/67. Heading C3R. [Also in Division C7] A curable resin is prepared by heating a methylolaminotriazine and/or methylolurea, the methylol groups of which have been etherified with a C 1-8 monohydric alcohol and with a C 2-4 alkylene glycol, with an adduct of an ethylenically unsaturated α,#-dicarboxylic acid and/or anhydride with a drying oil. Suitable methylol compounds are those of melamine and guanamines having a benzyl, ethyl, allyl, or cyclohexyl pendant group, and of urea; they may be etherified with methanol, ethanol, propanol, isopropanol, butanol, isobutanol or amyl, hexyl, octyl or cyclohexyl alcohols, and with ethylene, propylene or butylene or diethylene glycols or glycerol monomethyl ether. Suitable acids are maleic, fumaric, itaconic and citraconic acids; suitable oils are linseed, soya, Perilla, dehydrated castor, wood, oiticica, safflower, sunflower, and isomerized soya oils. The products may be neutralized with ammonia, triethylamine, triethanolamine and dimethyl ethanolamine to give water-soluble resins. A polyol, e.g. trimethylolethane, trimethylolpropane or glycerol, may be added during the reaction, up to 30 wt. per cent of the adduct. In examples, hexamethoxymethyl-melamine is condensed with 1: 2-propylene glycol, then with a linseed oil/ maleic anhydride adduct, with and without trimethylolpropane, and the product is neutralized with triethylamine. The viscosity of the products (50-100 DIN seconds, preferably) is measured as a 50% solution in butoxyethanol; 10% aqueous solutions are used for electrophoretic coating.
GB57352/67A 1966-12-29 1967-12-18 Process for the preparation of Curable Binders Expired GB1163369A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DER0044936 1966-12-29
FR120219A FR1541164A (en) 1966-12-29 1967-09-07 Process for preparing water-dilutable binders

Publications (1)

Publication Number Publication Date
GB1163369A true GB1163369A (en) 1969-09-04

Family

ID=29216776

Family Applications (1)

Application Number Title Priority Date Filing Date
GB57352/67A Expired GB1163369A (en) 1966-12-29 1967-12-18 Process for the preparation of Curable Binders

Country Status (2)

Country Link
FR (1) FR1541164A (en)
GB (1) GB1163369A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007090679A1 (en) * 2006-02-10 2007-08-16 Basf Coatings Ag Polyols based on modified amino resins, process for their preparation and their use
WO2016173805A1 (en) * 2015-04-30 2016-11-03 Bernhard Sandner Hydrophobizing compound and fluorocarbon polymer-free preparations based on water and/or organic solvents, the use thereof as a finish on sheet materials, and substrates obtained thereby

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007090679A1 (en) * 2006-02-10 2007-08-16 Basf Coatings Ag Polyols based on modified amino resins, process for their preparation and their use
JP2009526106A (en) * 2006-02-10 2009-07-16 ビーエーエスエフ コーティングス アクチェンゲゼルシャフト Polyols based on modified aminoplast resins, processes for their production and their use
CN101384635B (en) * 2006-02-10 2011-08-17 巴斯夫涂料有限公司 Polyols based on modified amino resins, process for their preparation and their use
US8153752B2 (en) 2006-02-10 2012-04-10 Basf Coatings Gmbh Polyols based on modified amino resins, process for their preparation and their use
WO2016173805A1 (en) * 2015-04-30 2016-11-03 Bernhard Sandner Hydrophobizing compound and fluorocarbon polymer-free preparations based on water and/or organic solvents, the use thereof as a finish on sheet materials, and substrates obtained thereby
CN107592890A (en) * 2015-04-30 2018-01-16 伯恩哈德·萨德内 The compound of hydrophobic property and the preparation without fluorocarbon polymer, its purposes as finishing agent on flat material and thus obtained base material based on water and/or organic solvent
CN107592890B (en) * 2015-04-30 2020-05-19 特克萨帕特有限公司 Hydrophobic compounds and formulations containing them and their use

Also Published As

Publication number Publication date
FR1541164A (en) 1968-10-04

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PLNP Patent lapsed through nonpayment of renewal fees