GB1156251A - Process for Melt-Spinning Fibres and Spinnable Compositions for use therein - Google Patents
Process for Melt-Spinning Fibres and Spinnable Compositions for use thereinInfo
- Publication number
- GB1156251A GB1156251A GB34918/67A GB3491867A GB1156251A GB 1156251 A GB1156251 A GB 1156251A GB 34918/67 A GB34918/67 A GB 34918/67A GB 3491867 A GB3491867 A GB 3491867A GB 1156251 A GB1156251 A GB 1156251A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polyester
- polyamide
- bis
- spinning
- melt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 5
- 238000002074 melt spinning Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 229920000728 polyester Polymers 0.000 abstract 7
- 239000004952 Polyamide Substances 0.000 abstract 4
- 229920002647 polyamide Polymers 0.000 abstract 4
- -1 polyethylene terephthalate Polymers 0.000 abstract 4
- 238000009987 spinning Methods 0.000 abstract 3
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 abstract 2
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 abstract 2
- 229920001410 Microfiber Polymers 0.000 abstract 1
- 229920002292 Nylon 6 Polymers 0.000 abstract 1
- 125000002252 acyl group Chemical group 0.000 abstract 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000000835 fiber Substances 0.000 abstract 1
- 230000009477 glass transition Effects 0.000 abstract 1
- OAKJQQAXSVQMHS-UHFFFAOYSA-N hydrazine Substances NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 abstract 1
- 229940116335 lauramide Drugs 0.000 abstract 1
- 239000000155 melt Substances 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 239000003658 microfiber Substances 0.000 abstract 1
- WNCFYFLYHFIWIL-UHFFFAOYSA-N n-[2-(docosanoylamino)ethyl]docosanamide Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCCCCCC WNCFYFLYHFIWIL-UHFFFAOYSA-N 0.000 abstract 1
- 229920000139 polyethylene terephthalate Polymers 0.000 abstract 1
- 239000005020 polyethylene terephthalate Substances 0.000 abstract 1
- 229940037312 stearamide Drugs 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/90—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
1,156,251. Polyamide-polyester filaments. ALLIED CHEMICAL CORP. 28 July, 1967 [29 July, 1966], No. 34918/67. Heading B5B. [Also in Division C3] A spinnable composition comprises a fibreforming polyamide having dispersed therein, based on the weight of the total composition, up to 50% of a fibre forming polyester and and 0À05 to 0À6% of a spinning aid which is a compound containing a C 12-22 straight chain acyl group and melting above 100‹ C. and which has a mould release index above 25 in pure polycaproamide. In the examples the polyamide and polyester are nylon 6 and polyethylene terephthalate and the spinning aids used are: Na, Ba, Ca, Cu, Li, Mg and Zn stearates; Na polmitate; ethylene-, methylene-, N,N<SP>1</SP>-hydrazine., p-phenylene-, p,p<SP>1</SP>-diphenylmethyl-, and p-p<SP>1</SP>-diphenyl-, -bis(stearamide)s; ethylene bis-(behenamide); 1-stearate-4-stearamidebenzene; p - p<SP>1</SP> - diphenyl - ether - bis-(palmitamide) ; and p,p<SP>1</SP>-diphenylmethyl-bis- (lauramide). In a preferred embodiment 10 to 50 wt per cent of polyester is dispersed as microfibres throughout the polyamide which has a reduced viscosity of 0À9 to 1À4 (being 0À9 to 2 times that of the polyester) and not more than 40% such groups reactive with the polyester in the melt; the polyester has glass transition temperature of at least 50‹ C. and above that of the polyamide. Spinning the Composition. In examples filaments are spun from such compositions at 265‹ or 275‹ C., air-cooled and taken up at speeds of 1130 or 1180 f.m. They are then passed over a 1¢ in. diameter drawpin to a contact surface heated at 185‹ or 135‹ C. and drawn at ratios from 5À23 to 5À72. The products have ultimate elongations from 14À5 to 15À9 and tensile strength from 8À2 to 9À75.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US56872566A | 1966-07-29 | 1966-07-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1156251A true GB1156251A (en) | 1969-06-25 |
Family
ID=24272464
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB34918/67A Expired GB1156251A (en) | 1966-07-29 | 1967-07-28 | Process for Melt-Spinning Fibres and Spinnable Compositions for use therein |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3516956A (en) |
| BE (1) | BE702039A (en) |
| CH (1) | CH499632A (en) |
| DE (1) | DE1669373A1 (en) |
| ES (1) | ES343530A1 (en) |
| GB (1) | GB1156251A (en) |
| NL (1) | NL6710464A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2557599A1 (en) * | 1983-12-30 | 1985-07-05 | Snia Fibre | PROCESS FOR SPINNING SYNTHETIC FIBERS BY EXTRUSION OF THERMOPLASTIC POLYMERS AND FIBERS OBTAINED |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3915912A (en) * | 1970-03-05 | 1975-10-28 | Asahi Chemical Ind | Modified polyamide compositions containing a polyethylene glycol derivative and a fatty acid or fatty acid salt |
| US3887520A (en) * | 1974-01-30 | 1975-06-03 | Allied Chem | Stabilized polyamide composition |
| US4115333A (en) * | 1977-03-18 | 1978-09-19 | General Electric Company | Warp-resistant reinforced thermoplastic compositions comprising polyester resins and zinc stearate |
| US5204396A (en) * | 1991-06-14 | 1993-04-20 | Polyplastics Co., Ltd. | Long fiber-reinforced polyamide resin composition and molded articles therefrom |
| US6005019A (en) * | 1993-07-21 | 1999-12-21 | United States Surgical Corporation | Plasticizers for fibers used to form surgical devices |
| CA2127636C (en) * | 1993-07-21 | 2009-10-20 | Cheng-Kung Liu | Plasticizers for fibers used to form surgical devices |
| US6087427A (en) * | 1995-11-21 | 2000-07-11 | E. I. Du Pont De Nemours And Company | Moldable thermoplastic resin composition |
| US20020193829A1 (en) * | 2001-03-26 | 2002-12-19 | Tyco Healthcare Group Lp | Oil coated sutures |
| EP1372746A2 (en) * | 2001-03-26 | 2004-01-02 | Tyco Healthcare Group Lp | Polyolefin sutures having improved processing and handling characteristics |
| DE102006055384A1 (en) * | 2006-11-22 | 2008-05-29 | Phoenix Contact Gmbh & Co. Kg | Process for improving the wettability and / or adhesion of plastic surfaces, in particular for ease of printability |
| KR102090166B1 (en) * | 2018-01-15 | 2020-03-18 | 한국화학연구원 | A compound having bis phenylene group substituted with alkylamide, Composition for controlling polyphenylene polymer flowability comprising thereof and method of polyphenylene polymer flowability control using the same |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2856373A (en) * | 1956-08-06 | 1958-10-14 | Allied Chemcial Corp | Polycaprolactam molding composition and molded articles |
| NL97477C (en) * | 1956-09-24 | |||
| GB847059A (en) * | 1957-10-19 | 1960-09-07 | Onderzoekings Inst Res | Method for the preparation of pigmented polyesters and articles manufactured from these polyesters |
| NL232181A (en) * | 1957-10-22 | |||
| US3039895A (en) * | 1960-03-29 | 1962-06-19 | Du Pont | Textile |
| US3260689A (en) * | 1960-05-27 | 1966-07-12 | Eastman Kodak Co | Polyester and polyamide compositions having improved dyeing properties and processesfor the production of such compositions |
| GB1050001A (en) * | 1963-06-17 |
-
1966
- 1966-07-29 US US568725A patent/US3516956A/en not_active Expired - Lifetime
-
1967
- 1967-07-25 CH CH1050767A patent/CH499632A/en unknown
- 1967-07-28 DE DE19671669373 patent/DE1669373A1/en active Pending
- 1967-07-28 ES ES343530A patent/ES343530A1/en not_active Expired
- 1967-07-28 NL NL6710464A patent/NL6710464A/xx unknown
- 1967-07-28 GB GB34918/67A patent/GB1156251A/en not_active Expired
- 1967-07-28 BE BE702039D patent/BE702039A/xx unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2557599A1 (en) * | 1983-12-30 | 1985-07-05 | Snia Fibre | PROCESS FOR SPINNING SYNTHETIC FIBERS BY EXTRUSION OF THERMOPLASTIC POLYMERS AND FIBERS OBTAINED |
| GB2152061A (en) * | 1983-12-30 | 1985-07-31 | Snia Fibre | Melt spinning thermoplastic polymers |
Also Published As
| Publication number | Publication date |
|---|---|
| NL6710464A (en) | 1968-01-30 |
| DE1669373A1 (en) | 1971-05-06 |
| CH499632A (en) | 1970-11-30 |
| BE702039A (en) | 1968-01-02 |
| ES343530A1 (en) | 1968-12-16 |
| US3516956A (en) | 1970-06-23 |
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