GB1154725A - New Polymers and process for manufacture thereof - Google Patents

New Polymers and process for manufacture thereof

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Publication number
GB1154725A
GB1154725A GB39584/65A GB3958465A GB1154725A GB 1154725 A GB1154725 A GB 1154725A GB 39584/65 A GB39584/65 A GB 39584/65A GB 3958465 A GB3958465 A GB 3958465A GB 1154725 A GB1154725 A GB 1154725A
Authority
GB
United Kingdom
Prior art keywords
groups
reactants
specified
cross
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB39584/65A
Inventor
David John Harper
Edward Jervis Vickers
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB39584/65A priority Critical patent/GB1154725A/en
Priority to GB29883/67A priority patent/GB1154726A/en
Priority to FR76629A priority patent/FR1500262A/en
Publication of GB1154725A publication Critical patent/GB1154725A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/28—Condensation with aldehydes or ketones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
    • C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G14/00—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00
    • C08G14/02—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes
    • C08G14/04—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols
    • C08G14/06—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols and monomers containing hydrogen attached to nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225—Polyamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/46—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen
    • C08G18/4615—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/50—Polyethers having heteroatoms other than oxygen
    • C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/91—Polymers modified by chemical after-treatment
    • C08G63/914—Polymers modified by chemical after-treatment derived from polycarboxylic acids and polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/331—Polymers modified by chemical after-treatment with organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/331—Polymers modified by chemical after-treatment with organic compounds containing oxygen
    • C08G65/332—Polymers modified by chemical after-treatment with organic compounds containing oxygen containing carboxyl groups, or halides, or esters thereof
    • C08G65/3322—Polymers modified by chemical after-treatment with organic compounds containing oxygen containing carboxyl groups, or halides, or esters thereof acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
    • C08G65/32—Polymers modified by chemical after-treatment
    • C08G65/329—Polymers modified by chemical after-treatment with organic compounds
    • C08G65/333—Polymers modified by chemical after-treatment with organic compounds containing nitrogen
    • C08G65/33303—Polymers modified by chemical after-treatment with organic compounds containing nitrogen containing amino group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/48—Polymers modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C08G73/0206—Polyalkylene(poly)amines
    • C08G73/0213—Preparatory process
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

1,154,725. Cross linked polymeric materials. IMPERIAL CHEMICAL INDUSTRIES Ltd. 31 Aug., 1966 [16 Sept., 1965], No. 39584/65. Headings C3B, C3C, C3P and C3R. Cross-linked polymeric materials are obtained by reacting a compound containing a plurality of beta-ketocarboxylic acid or amide groups with at least one H on the alpha carbon with an amine containing a plurality of primary or secondary amino groups under conditions whereby cross-linking with elimination of water takes place, at least one reactant having more than 2 of the specified reactive groups. The reactants may be monomeric or polymeric and modifying co-reactants, foaming agents and additives may be present during the reaction. Extensive lists of starting materials are given; the polyamine may be a polymer containing terminal or substituent amine groups while the acid reactant may be obtained by reacting an acetoacetic ester, diketene or an aldoketene dimer with polyols, polyamines or polymers containing hydroxyl or amino groups. Long lists of addition and condensation polymers which may contain such groups are given. Specified modifying reactants include polyepoxides, polyisocyanates, dialkyl oxalates and polyfunctional lactones or cyclic carbonates. Various foaming agents and surfactants which may be used in conjunction therewith are specified. Additives mentioned are flame retardants, plasticizers, colouring matter, fillers and antioxidants. Reference is made to Specification 1,154,726 which describes and claims some of the acid reactants.
GB39584/65A 1965-09-16 1965-09-16 New Polymers and process for manufacture thereof Expired GB1154725A (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
GB39584/65A GB1154725A (en) 1965-09-16 1965-09-16 New Polymers and process for manufacture thereof
GB29883/67A GB1154726A (en) 1965-09-16 1965-09-16 Esters of Polyethers
FR76629A FR1500262A (en) 1965-09-16 1966-09-16 New crosslinked polymers and their production by reaction of esters or amides with amino compounds

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB39584/65A GB1154725A (en) 1965-09-16 1965-09-16 New Polymers and process for manufacture thereof
GB29883/67A GB1154726A (en) 1965-09-16 1965-09-16 Esters of Polyethers
GB3958466 1966-08-31

Publications (1)

Publication Number Publication Date
GB1154725A true GB1154725A (en) 1969-06-11

Family

ID=62526345

Family Applications (2)

Application Number Title Priority Date Filing Date
GB39584/65A Expired GB1154725A (en) 1965-09-16 1965-09-16 New Polymers and process for manufacture thereof
GB29883/67A Expired GB1154726A (en) 1965-09-16 1965-09-16 Esters of Polyethers

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB29883/67A Expired GB1154726A (en) 1965-09-16 1965-09-16 Esters of Polyethers

Country Status (2)

Country Link
FR (1) FR1500262A (en)
GB (2) GB1154725A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104761718A (en) * 2015-03-09 2015-07-08 深圳市广昌达石油添加剂有限公司 Novel polyetheramine used as a gasoline detergent and a synthetic method thereof
WO2020123287A1 (en) * 2018-12-11 2020-06-18 Eastman Chemical Company Assembly components comprising curable compositions containing acetoacetylated resins
EP3894386A4 (en) * 2018-12-11 2022-10-12 Eastman Chemical Company Curable coating compositions
US11732165B2 (en) 2017-06-13 2023-08-22 Eastman Chemical Company Low-temperature curable compositions
US11920050B2 (en) 2018-12-11 2024-03-05 Eastman Chemical Company Self-curable and low temperature curable coating compositions

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005058745A1 (en) 2005-12-08 2007-06-14 Wacker Chemie Ag Enamine oils and process for their preparation
DE102006020816A1 (en) 2006-05-04 2007-11-08 Wacker Chemie Ag Organosilicon compounds containing beta-ketoamide groups and organic polymers bonded via enamine bonds, and methods for their preparation
WO2014052081A2 (en) * 2012-09-28 2014-04-03 Dow Global Technologies Llc Functionalized oligomers
EP3280756A1 (en) 2015-04-10 2018-02-14 Battelle Memorial Institute Bpa-free coatings
WO2016164869A2 (en) 2015-04-10 2016-10-13 Ohio Soybean Council Bpa-free coatings

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104761718A (en) * 2015-03-09 2015-07-08 深圳市广昌达石油添加剂有限公司 Novel polyetheramine used as a gasoline detergent and a synthetic method thereof
CN104761718B (en) * 2015-03-09 2017-03-15 广昌达新材料技术服务（深圳）股份有限公司 A kind of novel polyether amine and its synthetic method as gasoline cleaning agent
US11732165B2 (en) 2017-06-13 2023-08-22 Eastman Chemical Company Low-temperature curable compositions
US11261359B2 (en) 2018-12-11 2022-03-01 Eastman Chemical Company Flexible substrates comprising curable compositions containing acetoacetylated resins
US11447670B2 (en) 2018-12-11 2022-09-20 Eastman Chemical Company Curable acetoacetylated resin compositions comprising aldehydes and certain basic catalysts
WO2020123282A1 (en) * 2018-12-11 2020-06-18 Eastman Chemical Company Controlled cure for compositions comprising acetoacetylated resins
WO2020123284A1 (en) * 2018-12-11 2020-06-18 Eastman Chemical Company Flexible substrates comprising curable compositions containing acetoacetylated resins
CN113195634A (en) * 2018-12-11 2021-07-30 伊士曼化工公司 Flexible substrate comprising curable composition comprising acetoacetylated resin
CN113195635A (en) * 2018-12-11 2021-07-30 伊士曼化工公司 Curable acetoacetylated resin composition and additive comprising adhesion promoter, initial strength enhancer, or combination thereof
CN113195632A (en) * 2018-12-11 2021-07-30 伊士曼化工公司 Controlled curing of compositions comprising acetoacetylated resins
CN113195633A (en) * 2018-12-11 2021-07-30 伊士曼化工公司 Curable compositions comprising acetoacetylated resins, aldehydes and certain amines
CN113260673A (en) * 2018-12-11 2021-08-13 伊士曼化工公司 Assembly comprising a curable composition comprising an acetoacetylated resin
WO2020123280A1 (en) * 2018-12-11 2020-06-18 Eastman Chemical Company Curable acetoacetylated resin compositions and additives comprising adhesion promoters, green strength enhancers, or combinations thereof
US11434400B2 (en) 2018-12-11 2022-09-06 Eastman Chemical Company Assembly components comprising curable compositions containing acetoacetylated resins
WO2020123283A1 (en) * 2018-12-11 2020-06-18 Eastman Chemical Company Curable compositions comprising acetoacetylated resins, aldehydes and certain amines
US11459493B2 (en) 2018-12-11 2022-10-04 Eastman Chemical Company Curable acetoacetylated resin compositions and additives comprising adhesion promoters, green strength enhancers, or combinations thereof
EP3894386A4 (en) * 2018-12-11 2022-10-12 Eastman Chemical Company Curable coating compositions
US11530342B2 (en) 2018-12-11 2022-12-20 Eastman Chemical Company Curable compositions comprising acetoacetylated resins, aldehydes and certain amines
CN113260673B (en) * 2018-12-11 2023-08-08 伊士曼化工公司 Assembly comprising a curable composition comprising an acetoacetylated resin
WO2020123287A1 (en) * 2018-12-11 2020-06-18 Eastman Chemical Company Assembly components comprising curable compositions containing acetoacetylated resins
CN113195635B (en) * 2018-12-11 2023-10-10 伊士曼化工公司 Curable acetoacetylated resin composition and additive comprising adhesion promoter, initial strength enhancer, or combination thereof
CN113195633B (en) * 2018-12-11 2023-11-07 伊士曼化工公司 Curable compositions comprising acetoacetylated resin, aldehyde, and certain amines
US11820923B2 (en) 2018-12-11 2023-11-21 Eastman Chemical Company Controlled cure for compositions comprising acetoacetylated resins
US11920050B2 (en) 2018-12-11 2024-03-05 Eastman Chemical Company Self-curable and low temperature curable coating compositions

Also Published As

Publication number Publication date
GB1154726A (en) 1969-06-11
FR1500262A (en) 1967-11-03

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