GB1121877A - Acrylic esters - Google Patents

Acrylic esters

Info

Publication number
GB1121877A
GB1121877A GB5034165A GB5034165A GB1121877A GB 1121877 A GB1121877 A GB 1121877A GB 5034165 A GB5034165 A GB 5034165A GB 5034165 A GB5034165 A GB 5034165A GB 1121877 A GB1121877 A GB 1121877A
Authority
GB
United Kingdom
Prior art keywords
complex
acrolein
methoxymethyl
mercuric salt
alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5034165A
Inventor
Peter Arthur Edward Whincup
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB5034165A priority Critical patent/GB1121877A/en
Priority to NL6616614A priority patent/NL6616614A/xx
Priority to FR85110A priority patent/FR1501637A/en
Priority to BE690251D priority patent/BE690251A/xx
Publication of GB1121877A publication Critical patent/GB1121877A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Esters of acrylic acids are prepared by the oxidation of the corresponding aldehydes by forming a complex of a mercuric salt and acrolein or alkyl-substituted acroleins without applying heat, then heating the complex in contact with a mixture of an aliphatic alcohol (1-5 C) a proportion of water less than 15% by weight of the alcohol, and a mercuric salt. The complex ma or may not be separated from the system and an inert organic solvent such as perchloro-ethylene, tetrachloroethane and chloroform may be present. By-products from acrolein are b -methoxypropionaldehyde and b -methoxymethyl propionate and from methacrolein, b -methoxyisobutyraldehyde and b -methoxymethyl isobutyrate.
GB5034165A 1965-11-26 1965-11-26 Acrylic esters Expired GB1121877A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
GB5034165A GB1121877A (en) 1965-11-26 1965-11-26 Acrylic esters
NL6616614A NL6616614A (en) 1965-11-26 1966-11-25
FR85110A FR1501637A (en) 1965-11-26 1966-11-25 Manufacturing process of acrylic esters
BE690251D BE690251A (en) 1965-11-26 1966-11-25

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB5034165A GB1121877A (en) 1965-11-26 1965-11-26 Acrylic esters

Publications (1)

Publication Number Publication Date
GB1121877A true GB1121877A (en) 1968-07-31

Family

ID=10455552

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5034165A Expired GB1121877A (en) 1965-11-26 1965-11-26 Acrylic esters

Country Status (4)

Country Link
BE (1) BE690251A (en)
FR (1) FR1501637A (en)
GB (1) GB1121877A (en)
NL (1) NL6616614A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4249019A (en) * 1977-11-17 1981-02-03 Asahi Kasei Kogyo Kabushiki Kaisha Process for producing carboxylic esters

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4249019A (en) * 1977-11-17 1981-02-03 Asahi Kasei Kogyo Kabushiki Kaisha Process for producing carboxylic esters

Also Published As

Publication number Publication date
BE690251A (en) 1967-05-25
FR1501637A (en) 1967-11-10
NL6616614A (en) 1967-05-29

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