GB1119221A - Stabilized peroxy compositions and their use - Google Patents
Stabilized peroxy compositions and their useInfo
- Publication number
- GB1119221A GB1119221A GB23765/65A GB2376565A GB1119221A GB 1119221 A GB1119221 A GB 1119221A GB 23765/65 A GB23765/65 A GB 23765/65A GB 2376565 A GB2376565 A GB 2376565A GB 1119221 A GB1119221 A GB 1119221A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- amino tri
- amino
- solution
- salts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000000864 peroxy group Chemical group O(O*)* 0.000 title abstract 5
- 239000000203 mixture Substances 0.000 title abstract 4
- -1 peroxy compound Chemical class 0.000 abstract 14
- DKPHLYCEFBDQKM-UHFFFAOYSA-H hexapotassium;1-phosphonato-n,n-bis(phosphonatomethyl)methanamine Chemical compound [K+].[K+].[K+].[K+].[K+].[K+].[O-]P([O-])(=O)CN(CP([O-])([O-])=O)CP([O-])([O-])=O DKPHLYCEFBDQKM-UHFFFAOYSA-H 0.000 abstract 12
- 239000000243 solution Substances 0.000 abstract 10
- 239000002253 acid Substances 0.000 abstract 9
- 238000004061 bleaching Methods 0.000 abstract 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 7
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 6
- 229910052700 potassium Inorganic materials 0.000 abstract 6
- 239000011591 potassium Substances 0.000 abstract 6
- 150000003839 salts Chemical class 0.000 abstract 6
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 4
- 125000004432 carbon atom Chemical group C* 0.000 abstract 4
- 239000003381 stabilizer Substances 0.000 abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 2
- 240000000491 Corchorus aestuans Species 0.000 abstract 2
- 235000011777 Corchorus aestuans Nutrition 0.000 abstract 2
- 235000010862 Corchorus capsularis Nutrition 0.000 abstract 2
- 229920000742 Cotton Polymers 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract 2
- 229910019142 PO4 Inorganic materials 0.000 abstract 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 abstract 2
- 229920000297 Rayon Polymers 0.000 abstract 2
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M Superoxide Chemical compound [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000001118 alkylidene group Chemical group 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 239000012141 concentrate Substances 0.000 abstract 2
- 238000010790 dilution Methods 0.000 abstract 2
- 239000012895 dilution Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052744 lithium Inorganic materials 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- ZQAUNTSBAZCVIO-UHFFFAOYSA-N methoxyphosphonamidic acid Chemical compound COP(N)(O)=O ZQAUNTSBAZCVIO-UHFFFAOYSA-N 0.000 abstract 2
- 230000003287 optical effect Effects 0.000 abstract 2
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 abstract 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 2
- 239000010452 phosphate Substances 0.000 abstract 2
- 229910052708 sodium Inorganic materials 0.000 abstract 2
- 239000011734 sodium Substances 0.000 abstract 2
- PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 abstract 2
- 159000000000 sodium salts Chemical class 0.000 abstract 2
- 239000000080 wetting agent Substances 0.000 abstract 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 1
- 229910021529 ammonia Inorganic materials 0.000 abstract 1
- 239000004202 carbamide Substances 0.000 abstract 1
- LXCYSACZTOKNNS-UHFFFAOYSA-N diethoxy(oxo)phosphanium Chemical compound CCO[P+](=O)OCC LXCYSACZTOKNNS-UHFFFAOYSA-N 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- YACKEPLHDIMKIO-UHFFFAOYSA-N methylphosphonic acid Chemical compound CP(O)(O)=O YACKEPLHDIMKIO-UHFFFAOYSA-N 0.000 abstract 1
- 238000010992 reflux Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/34—Organic compounds, e.g. vitamins containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/037—Stabilisation by additives
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
- C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3817—Acids containing the structure (RX)2P(=X)-alk-N...P (X = O, S, Se)
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/364—Organic compounds containing phosphorus containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/30—Organic compounds, e.g. vitamins containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
- D06L4/12—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Geology (AREA)
- Mechanical Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Geochemistry & Mineralogy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Water Supply & Treatment (AREA)
- Textile Engineering (AREA)
- Detergent Compositions (AREA)
- Paper (AREA)
Abstract
A composition suitable for use in the bleaching of cellulosic materials, e.g. cotton, linen, jute, viscose rayon and paper, comprises an aqueous solution containing a peroxy compound, the solution being stabilized by the addition thereto of an amino tri(lower alkylidene phosphonic acid), the lower alkylidene group containing 1-9 carbon atoms or a water soluble salt thereof. The amino tri(lower alkylidene phosphonic acid) may have the formula <FORM:1119221/C1/1> in which X and Y are hydrogen or alkyl groups of 1-4 carbon atoms e.g. amino tri(methyl phosphonic acid), amino tri(ethylidenephosphonic acid), amino tri(isopropylidenephosphonic acid), amino mono(methylphosphonic acid) di(ethylidene phosphonic acid) and amino tri(butylidene phosphonic acid). The salts used are preferably the penta sodium salts although the potassium, lithium, ammonium and amino salts are also suitable. Suitable peroxy compounds are sodium peroxide, the super oxide of potassium (K20), hydrogen peroxide and addition compounds thereof, perborates, persulphates, persulphuric acid, peroxy monophosphoric acid and water soluble salts thereof, e.g. the sodium, potassium, ammonium and organic amine salts. The solution may be adjusted to a pH of 7.5-12.5 by the addition of sodium or potassium hydroxide, carbonate, silicate or phosphate and may also contain optical whiteners and wetting agents. The solution may contain 0.01-5% by weight of peroxy compound and 0.001-5% by weight of stabilizing agent. The stabilizing agent may be mixed with the dry bleaching composition prior to preparing the bleaching solution or added to the bleaching concentrate prior to dilution.ALSO:Amino tri(methylphosphonic acid) is prepared by heating together diethyl phosphite, ammonia and formaldehyde and hydrolysing the hexaethyl amino tri(methylphosphonate) produced by refluxing it with concentrated hydrochloric acid. Pentasodium amino tri-(methylphosphonate) of the formula N-(CH2PO3Na2)2(CH2PO3HNa) is prepared by dissolving the amino tri(methylphophonic acid) in NaOH solution and evaporating the resulting solution to dryness.ALSO:Cellulosic materials, e.g. cotton, linen, jute, viscose rayon and paper, are bleached by treating them with an aqueous solution containing a peroxy compound, the solution being stabilized by the addition thereto of an amino tri (lower alkylidene phosphonic acid), the lower alkylidene group containing 1-9 carbon atoms, or a water soluble salt thereof. The amino tri (lower alkylidene phosphonic acid) may have the formula <FORM:1119221/D1-D2/1> in which X and Y are hydrogen or alkyl groups of 1-4 carbon atoms e.g. amino tri (methyl phosphonic acid), amino tri (ethylidenephosphonic acid), amino tri (isopropylidenephosphonic acid), amino mono (methylphosphonic acid) di (ethylidene phosphonic acid) and amino tri (butylidene phosphonic acid). The salts used are preferable the penta sodium salts although the potassium, lithium, ammonium and amino salts are also suitable. Suitable peroxy compounds are sodium peroxide, the super oxide of potassium (K2O), hydrogen peroxide and addition compounds thereof, urea per compounds, perborates, persulphates, persulphuric acid, peracetic acid, peroxy monophosphoric acid and water soluble salts thereof, e.g. the sodium, potassium, ammonium and organic amine salts. The solution may be adjusted to a pH of p 7.5-12.5 by the addition of sodium or potassium hydroxide, carbonate, silicate or phosphate and may also contain optical whiteners and wetting agents. The solution may contain 0.01-5% by weight of peroxy compound and 0.001-5% by weight of stabilizing agent. The stabilizing agent may be mixed with the dry bleaching composition prior to preparing the bleaching solution or added to the bleaching concentrate prior to dilution.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US373072A US3234140A (en) | 1964-06-05 | 1964-06-05 | Stabilization of peroxy solutions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1119221A true GB1119221A (en) | 1968-07-10 |
Family
ID=23470796
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB23765/65A Expired GB1119221A (en) | 1964-06-05 | 1965-06-03 | Stabilized peroxy compositions and their use |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US3234140A (en) |
| BE (1) | BE665004A (en) |
| DE (1) | DE1519484B2 (en) |
| FR (1) | FR1449711A (en) |
| GB (1) | GB1119221A (en) |
| LU (1) | LU48760A1 (en) |
| NL (1) | NL6507058A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS49577A (en) * | 1972-03-10 | 1974-01-07 | ||
| DE2622458A1 (en) * | 1976-05-20 | 1977-12-08 | Peroxid Chemie Gmbh | PROCESS FOR STABILIZATION OF SODIUM PERCARBONATE |
| EP0496605A2 (en) * | 1991-01-24 | 1992-07-29 | Wako Pure Chemical Industries Ltd | Surface treating solutions and cleaning method |
| EP0839904A2 (en) * | 1996-11-05 | 1998-05-06 | Clariant International Ltd. | Hydrogen peroxide-containing bleach liquor and bleaching method thereby |
| EP0866095A1 (en) * | 1997-03-13 | 1998-09-23 | 3V SIGMA S.p.A | Compositions for bleaching paper |
Families Citing this family (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3474133A (en) * | 1964-09-03 | 1969-10-21 | Monsanto Co | Tris(phosphono-lower alkylidene) amine oxides |
| US3429914A (en) * | 1964-09-03 | 1969-02-25 | Monsanto Co | Organo-phosphono-amine oxides |
| US3470243A (en) * | 1964-09-03 | 1969-09-30 | Monsanto Co | Tetrakis(dihydrogen phosphono methyl)-ethylene diamine,n,n'-dioxide and related compounds |
| US3470244A (en) * | 1964-09-03 | 1969-09-30 | Monsanto Co | Methyl bis(dihydrogen phosphono methyl)-amine oxide and related compounds |
| DE1496917A1 (en) * | 1964-09-22 | 1969-05-22 | Monsanto Co | Electrolytic baths and processes for the production of galvanic coatings |
| DE1217950B (en) * | 1965-02-25 | 1966-06-02 | Henkel & Cie Gmbh | Process for the production of new perhydrates from aminoalkylphosphonic acids |
| DE1264687B (en) * | 1965-11-24 | 1968-03-28 | Therachemie Chem Therapeut | Means for reducing the damage to hair during bleaching and dyeing |
| US3395113A (en) * | 1966-03-29 | 1968-07-30 | Monsanto Co | Polymeric compositions |
| US3387939A (en) * | 1966-07-06 | 1968-06-11 | Du Pont | Stannate stabilizer compositions containing an alkylidene diphosphonic acid, their preparation and hydrogen peroxide solutions stabilized therewith |
| US3455675A (en) * | 1968-06-25 | 1969-07-15 | Monsanto Co | Aminophosphonate herbicides |
| US3645670A (en) * | 1970-03-03 | 1972-02-29 | Monsanto Co | Processes for scouring textiles |
| GB1392284A (en) * | 1971-03-30 | 1975-04-30 | Unilever Ltd | Stabilisation of active oxygen releasing compounds |
| US3766078A (en) * | 1971-06-03 | 1973-10-16 | Monsanto Co | Processes for stabilizing peroxy solutions |
| US3903244A (en) * | 1973-02-02 | 1975-09-02 | Fmc Corp | Stabilized hydrogen peroxide |
| US4059678A (en) * | 1973-02-02 | 1977-11-22 | Fmc Corporation | Stabilization of iron-containing acidic hydrogen peroxide solutions |
| AT352241B (en) * | 1977-04-22 | 1979-09-10 | Henkel Kgaa | POWDERED, PHOSPHATE-FREE TEXTILE DETERGENT |
| US4497725A (en) * | 1980-04-01 | 1985-02-05 | Interox Chemicals Ltd. | Aqueous bleach compositions |
| CA1205275A (en) * | 1982-06-14 | 1986-06-03 | Kenneth J. Radimer | Stabilization of high purity hydrogen peroxide |
| US4401509A (en) * | 1982-09-07 | 1983-08-30 | Fmc Corporation | Composition and process for printed circuit etching using a sulfuric acid solution containing hydrogen peroxide |
| US4534945A (en) * | 1984-05-03 | 1985-08-13 | Fmc Corporation | Stabilization of high purity hydrogen peroxide |
| US4614646A (en) * | 1984-12-24 | 1986-09-30 | The Dow Chemical Company | Stabilization of peroxide systems in the presence of alkaline earth metal ions |
| US4900468A (en) * | 1985-06-17 | 1990-02-13 | The Clorox Company | Stabilized liquid hydrogen peroxide bleach compositions |
| US5180514A (en) * | 1985-06-17 | 1993-01-19 | The Clorox Company | Stabilizing system for liquid hydrogen peroxide compositions |
| US4889689A (en) * | 1986-10-14 | 1989-12-26 | Ciba-Geigy Corporation | Method of disinfecting a soft contact lens with a diethylene triamine penta(methylenephosphonic acid) stabilized hydrogen peroxide solution |
| DE3720277A1 (en) * | 1987-06-19 | 1988-12-29 | Degussa | METHOD FOR REDUCING THE TENSION TO BAKING UP PARTICULATE ACTIVE OXYGEN COMPOUNDS |
| DE3914827C2 (en) * | 1989-05-05 | 1995-06-14 | Schuelke & Mayr Gmbh | Liquid disinfectant concentrate |
| US5023376A (en) * | 1989-07-17 | 1991-06-11 | Interox America | Reduction of nitrosamine formation |
| US5180517A (en) * | 1990-11-05 | 1993-01-19 | United States Borax & Chemical Corporation | Stabilized liquid persalt bleach compositions |
| JP3075290B2 (en) * | 1991-02-28 | 2000-08-14 | 三菱瓦斯化学株式会社 | Cleaning liquid for semiconductor substrates |
| US5324857A (en) * | 1992-04-28 | 1994-06-28 | Solvay Interox | Inhibition of the formation of nitrosamines |
| FR2707896B1 (en) * | 1993-07-22 | 1995-09-01 | Chemoxal Sa | Process for treating an article and new aqueous solution of hydrogen peroxide. |
| US5736256A (en) * | 1995-05-31 | 1998-04-07 | Howard A. Fromson | Lithographic printing plate treated with organo-phosphonic acid chelating compounds and processes relating thereto |
| US5962603A (en) * | 1996-07-23 | 1999-10-05 | Georgia-Pacific Resins, Inc. | Intumescent composition and method |
| US5864003A (en) * | 1996-07-23 | 1999-01-26 | Georgia-Pacific Resins, Inc. | Thermosetting phenolic resin composition |
| US20030095917A1 (en) * | 2001-07-27 | 2003-05-22 | Debra Wilcox | Chemical composition and process |
| DE10146594A1 (en) * | 2001-09-21 | 2003-04-10 | Solvay Interox Gmbh | Stabilized hydrogen peroxide |
| US7459005B2 (en) * | 2002-11-22 | 2008-12-02 | Akzo Nobel N.V. | Chemical composition and method |
| US7087703B2 (en) * | 2004-07-26 | 2006-08-08 | Georgia-Pacific Resins, Inc. | Phenolic resin compositions containing etherified hardeners |
| PL1903081T3 (en) | 2006-09-19 | 2015-05-29 | Poligrat Gmbh | Stabiliser for acid, metallic polishing baths |
| SI2225175T1 (en) * | 2007-12-12 | 2013-04-30 | Akzo Nobel N.V. | Stabilized hydrogen peroxide solutions |
| CN101597305B (en) * | 2009-06-14 | 2012-03-28 | 常州姚氏同德化工有限公司 | Preparation process for a solid aminotrimethylenephosphonic acid (ATMP) or 1-hydoxy ethyidene-1.1-diphosphonic acid |
| EP2662329A1 (en) | 2012-05-11 | 2013-11-13 | Creachem SA | Peroxygen release compositions and method for producing them |
| EP2759518B1 (en) * | 2013-01-24 | 2019-05-22 | MKS-DEVO Kimyevi Mad. San. Tic. A.S. | Bleaching compositions with improved performance and stability and their use |
| US12064732B2 (en) | 2016-02-17 | 2024-08-20 | Zeco, Llc | Methods and related apparatus for providing a processing solution for a food processing application |
| US11350640B1 (en) | 2016-08-12 | 2022-06-07 | Zee Company I, Llc | Methods and related apparatus for increasing antimicrobial efficacy in a poultry chiller tank |
| US10974211B1 (en) | 2016-02-17 | 2021-04-13 | Zee Company, Inc. | Peracetic acid concentration and monitoring and concentration-based dosing system |
| AU2019314454A1 (en) * | 2018-08-02 | 2021-03-18 | Evonik Corporation | Process for preparing a stabilized aqueous hydrogen peroxide solution |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2917528A (en) * | 1956-08-24 | 1959-12-15 | Victor Chemical Works | Alkanolaminealkanephosphonic acids and salts thereof |
| NL130828C (en) * | 1959-06-03 |
-
1964
- 1964-06-05 US US373072A patent/US3234140A/en not_active Expired - Lifetime
-
1965
- 1965-06-01 FR FR19014A patent/FR1449711A/en not_active Expired
- 1965-06-02 DE DE1965M0065443 patent/DE1519484B2/en active Granted
- 1965-06-03 GB GB23765/65A patent/GB1119221A/en not_active Expired
- 1965-06-03 NL NL6507058A patent/NL6507058A/xx unknown
- 1965-06-03 LU LU48760D patent/LU48760A1/xx unknown
- 1965-06-04 BE BE665004A patent/BE665004A/xx unknown
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS49577A (en) * | 1972-03-10 | 1974-01-07 | ||
| DE2622458A1 (en) * | 1976-05-20 | 1977-12-08 | Peroxid Chemie Gmbh | PROCESS FOR STABILIZATION OF SODIUM PERCARBONATE |
| EP0496605A2 (en) * | 1991-01-24 | 1992-07-29 | Wako Pure Chemical Industries Ltd | Surface treating solutions and cleaning method |
| EP0496605A3 (en) * | 1991-01-24 | 1993-02-03 | Wako Pure Chemical Industries Ltd | Surface treating solutions and cleaning method |
| US5290361A (en) * | 1991-01-24 | 1994-03-01 | Wako Pure Chemical Industries, Ltd. | Surface treating cleaning method |
| EP0839904A2 (en) * | 1996-11-05 | 1998-05-06 | Clariant International Ltd. | Hydrogen peroxide-containing bleach liquor and bleaching method thereby |
| EP0839904A3 (en) * | 1996-11-05 | 1999-01-20 | Clariant International Ltd. | Hydrogen peroxide-containing bleach liquor and bleaching method thereby |
| EP0866095A1 (en) * | 1997-03-13 | 1998-09-23 | 3V SIGMA S.p.A | Compositions for bleaching paper |
Also Published As
| Publication number | Publication date |
|---|---|
| BE665004A (en) | 1965-10-01 |
| NL6507058A (en) | 1965-12-06 |
| US3234140A (en) | 1966-02-08 |
| DE1519484A1 (en) | 1970-11-26 |
| DE1519484B2 (en) | 1973-03-15 |
| LU48760A1 (en) | 1965-12-03 |
| FR1449711A (en) | 1966-08-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| GB1119221A (en) | Stabilized peroxy compositions and their use | |
| US2935471A (en) | Flame retardant composition | |
| US4294575A (en) | Peroxide stabilization | |
| GB1354989A (en) | Compositions for stabilizing solutions of peroxy compounds | |
| Nuessle et al. | Some aspects of the cellulose-phosphate-urea reaction | |
| US3542918A (en) | Aminopolyphosphonic acids and polyphosphonic acids and derivatives for the protection of hair | |
| GB2056991A (en) | N - (hydroxymethyl) - aminoalkane-diphosphonic acids and their use as stabililizers in bleaching solutions | |
| US2121952A (en) | Bleaching, washing, and cleansing compositions | |
| ES399763A1 (en) | Bleach-fabric softener compositions | |
| GB1089998A (en) | Improvements in and relating to concentrates containing active oxygen | |
| GB1395990A (en) | Preparation of flame retardant cellulosic materials | |
| US4239643A (en) | Peroxide stabilization | |
| GB1072827A (en) | New perhydrates of phosphonic acids containing nitrogen | |
| GB1370111A (en) | Quaternary ammonium benzimidazole derivatives as their use as textile treatment agents | |
| US4107373A (en) | Flame retardant cellulosic materials | |
| US5013327A (en) | Mercerizing and/or causticizing wetting agent: 2-ethyl-hexyl-sulfate and mixture of alkyl end-blocked polyethers | |
| GB608923A (en) | Stable solid compositions for use in preparing cleansing and disinfecting solutions | |
| US2333916A (en) | Stabilization of bleach baths of high alkalinity | |
| US1501895A (en) | Composition for fireproofing and other purposes | |
| US3890093A (en) | Mercerizing solutions | |
| US1501911A (en) | Fire-resisting or flameproof starching composition | |
| US3035897A (en) | Stable peroxide containing phosphates | |
| GB2226341A (en) | Stabilising hydrogen peroxide bleach | |
| US1720926A (en) | Fireproof composition | |
| JPS5858466B2 (en) | Bleaching of textile materials with hydrogen peroxide |