GB1115453A - Internally coated metal container - Google Patents
Internally coated metal containerInfo
- Publication number
- GB1115453A GB1115453A GB2799165A GB2799165A GB1115453A GB 1115453 A GB1115453 A GB 1115453A GB 2799165 A GB2799165 A GB 2799165A GB 2799165 A GB2799165 A GB 2799165A GB 1115453 A GB1115453 A GB 1115453A
- Authority
- GB
- United Kingdom
- Prior art keywords
- parts
- interpolymer
- ethylenically unsaturated
- acid
- alpha
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/52—Amides or imides
- C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F20/58—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-acryloylmorpholine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D25/00—Details of other kinds or types of rigid or semi-rigid containers
- B65D25/14—Linings or internal coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Paints Or Removers (AREA)
Abstract
A substantially mercaptan-free composition comprises an interpolymer of 2 to 20% by weight of an ethylenically unsaturated carboxylic acid amide and 50 to 98% by weight of a vinyl aromatic monomer and/or an alkyl ester of an ethylenically unsaturated carboxylic acid, the interpolymer having at least some of the hydrogen atoms attached to the amido groups from the amide replaced by the structure R.CH.OR1 where R is hydrogen or a hydrocarbon radical, and R1 is a radical derived by removing the hydroxyl group from a monohydric alcohol. An ethylenically unsaturated nitrile, an ethylenically unsaturated carboxylic acid, an epoxy resin may also be included in the interpolymer. The interpolymer may be produced from a mercaptan-free reaction mixture containing a catalytic amount of alpha, alpha-azobis (isobutyronitrile). The included polyepoxide should have an epoxide equivalent of 100 to 1000 and may be polyglycidyl ether of a polyhydric compound, e.g. the condensation product of bisphenol A and epichlorohydrin, or epoxylated novolacs. Other polyhydric compounds which may be used to produce the polyepoxide are bis-4-hydroxy-phenyl-2,2-butane and pentaerythritol, and other oxirano compounds such as 1-chloro-2,3-epoxy butane may be used. The coating compositions used in the examples include colorants such as those certified for beverage liners by the Food and Drug Administration. Compositions disclosed comprise (a) 575 parts of an interpolymer of acrylamide, methacrylic acid, styrene, ethyl acrylate, 34 parts of a Bisphenol A-epichlorohydrin condensation product having an epoxide equivalent of 450 to 525, 48 parts toluene; (b) 222.5 parts of the interpolymer of (a), 2 parts of a thermoplastic hydrocarbon resin based on cyclo-pentadiene, 12 parts toluene, (c) 575 parts of an interpolymer of acrylamide, methacrylic acid, styrene, 34 parts of the polyepoxide of (a), 48 parts toluene; in the interpolymers used, the amide groups were reacted with formaldehyde and butanol. The interpolymers were prepared by polymerizing the corresponding monomers in a mixture of butanol and aromatic hydrocarbons using azobis-isobutyronitrile as catalyst.ALSO:A metal container suitable for packaging beverages or food has its internal surface coated with a single cured layer of a substantially mercaptan-free composition comprising an interpolymer of 2 to 20 per cent by weight of an ethylenically unsaturated carboxylic acid amide and 50 to 98 per cent by weight of a vinyl aromatic monomer and/or an alkyl ester of an ethylenically unsaturated carboxylic acid, the interpolymer having at least some of the hydrogen atoms attached to the amido groups from the amide replaced by the structure: R.CH.OR1 where R is hydrogen or a hydrocarbon radical, and R1 is a radical derived by removing the hydroxyl group from a monohydric alcohol. An ethylenically unsaturated nitrile, an ethylenically unsaturated carboxylic acid, an epoxy resin may also be included in the interpolymer. The amide may be acrylamide, methacrylamide, itaconic acid diamine, alpha-ethyl acrylamide, crotonamide, fumaric acid diamide, maleic acid diamide and other amides of alpha, beta-ethylenically unsaturated carboxcylic acids containing up to 10 carbon atoms, maleuric acid and esters, and imide derivatives such as N - carbamyl maleimide. The alkyl esters of an ethylenically unsaturated carboxylic acid may be esters of "acrylic acid", maleic and fumaric acid, and examples of various esters are given. By "acrylic acid" is meant acrylic acid, methacrylic and similar alpha-substituted acrylic acids. The vinyl aromatic monomer may be styrene, vinyl toluene, mono- and di-substituted chlorostyrenes, alpha-methyl styrene. The included ethylenically unsaturated carboxylic acids may be acrylic, methacrylic, maleic, crotonic and ethacrylic acid and monoesters of dicarboxylic acids. The included ethylenically unsaturated nitrile may be acrylonitile, methacrylonitrile, ethacrylonitrile. Methods of making the interpolymers are described. The interpolymer may be produced from a mercapton-free reaction mixture containing a catalytic amount of alpha, alpha-azobis (iso butyronitrile). The included polyepoxide should have an epoxide equivalent of 100 to 1000 and may be a polyglycidyl ether of a polyhydric compound, e.g. the condensation product of bisphenol A and epichlorohydrin, or epoxylated novolacs. Other polyhydric compounds which may be used to produce the polyepoxide are bis - 4 - hydroxy - phenyl - 2,2 - butane and pentacrythritol, and other oxirano compounds such as 1 - chloro - 2,3 - epoxy butane may be used. The metal may be steel, aluminium, tin plate. The compositions may be applied by spraying, roll coating, brushing, or dipping. In spray application, two spray coatings may be applied, either wet on wet or with a short drying interval. After application the coatings are cured by heating. The coating compositions used in the Examples include one containing a colourant comprising a hydrocarbon resin based on cyclopentadiene. Other colourants such as those certified for beverage liners by the Food and Drug Administration may be used. Compositions disclosed comprise (a) 575 parts of an interpolymer of acrylamide, methacrylic acid, styrene, ethyl acrylate, 34 parts of a Bisphenol A-epichlorohydrin condensation product having an epoxide equivalent of 450 to 525, 48 parts toluene; (b) 222.5 parts of the interpolymer of (a), 2 parts of a thermoplastic hydrocarbon resin based on cyclo-penadiene, 12 parts toluene, (c) 575 parts of an interpolymer of acrylamide, methacrylic acid, styrene, 34 parts of the polyepoxide of (a), 48 parts toluene.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US38579064A | 1964-07-28 | 1964-07-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1115453A true GB1115453A (en) | 1968-05-29 |
Family
ID=23522891
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB2799165A Expired GB1115453A (en) | 1964-07-28 | 1965-07-01 | Internally coated metal container |
Country Status (6)
Country | Link |
---|---|
AT (1) | AT281226B (en) |
BE (1) | BE667267A (en) |
CH (1) | CH475860A (en) |
GB (1) | GB1115453A (en) |
NL (1) | NL6509366A (en) |
SE (1) | SE319113B (en) |
-
1965
- 1965-07-01 GB GB2799165A patent/GB1115453A/en not_active Expired
- 1965-07-14 AT AT06467/65A patent/AT281226B/en not_active IP Right Cessation
- 1965-07-15 CH CH995265A patent/CH475860A/en not_active IP Right Cessation
- 1965-07-20 NL NL6509366A patent/NL6509366A/xx unknown
- 1965-07-22 BE BE667267D patent/BE667267A/xx unknown
- 1965-07-23 SE SE975465A patent/SE319113B/xx unknown
Also Published As
Publication number | Publication date |
---|---|
CH475860A (en) | 1969-07-31 |
SE319113B (en) | 1969-12-22 |
BE667267A (en) | 1966-01-24 |
NL6509366A (en) | 1966-01-31 |
AT281226B (en) | 1970-05-25 |
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