GB1107166A - Chlorine-stable detergent compositions and process for the preparation thereof - Google Patents
Chlorine-stable detergent compositions and process for the preparation thereofInfo
- Publication number
- GB1107166A GB1107166A GB27290/66A GB2729066A GB1107166A GB 1107166 A GB1107166 A GB 1107166A GB 27290/66 A GB27290/66 A GB 27290/66A GB 2729066 A GB2729066 A GB 2729066A GB 1107166 A GB1107166 A GB 1107166A
- Authority
- GB
- United Kingdom
- Prior art keywords
- mixture
- chlorine
- sodium
- tetrasodium pyrophosphate
- hydrated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 7
- 239000003599 detergent Substances 0.000 title abstract 3
- -1 aliphatic alcohols Chemical class 0.000 abstract 3
- 239000002736 nonionic surfactant Substances 0.000 abstract 3
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 abstract 3
- 235000019818 tetrasodium diphosphate Nutrition 0.000 abstract 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 2
- 229910019142 PO4 Inorganic materials 0.000 abstract 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract 2
- 239000000460 chlorine Substances 0.000 abstract 2
- 229910052801 chlorine Inorganic materials 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 2
- 239000010452 phosphate Substances 0.000 abstract 2
- YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 abstract 1
- KEQGZUUPPQEDPF-UHFFFAOYSA-N 1,3-dichloro-5,5-dimethylimidazolidine-2,4-dione Chemical compound CC1(C)N(Cl)C(=O)N(Cl)C1=O KEQGZUUPPQEDPF-UHFFFAOYSA-N 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 241000695274 Processa Species 0.000 abstract 1
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- 239000005708 Sodium hypochlorite Substances 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000007513 acids Chemical class 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 abstract 1
- CEJLBZWIKQJOAT-UHFFFAOYSA-N dichloroisocyanuric acid Chemical compound ClN1C(=O)NC(=O)N(Cl)C1=O CEJLBZWIKQJOAT-UHFFFAOYSA-N 0.000 abstract 1
- 230000036571 hydration Effects 0.000 abstract 1
- 238000006703 hydration reaction Methods 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 229910017053 inorganic salt Inorganic materials 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 abstract 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000011734 sodium Substances 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 abstract 1
- 235000019795 sodium metasilicate Nutrition 0.000 abstract 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract 1
- 235000011152 sodium sulphate Nutrition 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical class [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3958—Bleaching agents combined with phosphates
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Chlorine-stable detergent compositions containing a non-ionic surfactant are prepared by adding an aqueous solution of a non-ionic surfactant to tetrasodium pyrophosphate or a mixture of tetrasodium pyrophosphate and at least one other inorganic salt, the mixture containing at least 50% by weight of tetrasodium pyrophosphate, whereby hydration of the condensed phosphate and simultaneous absorption of the surfactant occurs, adding a hydrated sodium metasilicate to the hydrated condensed phosphate with mixing, before or after reducing the size of the mixture to a desired particle size, and thereafter adding an active chlorine containing compound to the mixture whereby a dry, free-flowing granular product is obtained, and a detergent composition comprising the above ingredients whenever prepared by a processas described. Non-ionic surfactants mentioned are condensates of polyalkylene oxides with aliphatic alcohols, alkyl phenols, acids, amines, amides and alkyl mercaptans, inorganic salts specified are sodium carbonate and sodium sulphate and chlorine active compounds include chlorinated trisodium phosphate, trichloro-cyanuric acid, the sodium or potassium salt of dichlorocyanuric acid, sodium hypochlorite and 1,3-dichloro-5,5-dimethyl hydantoin.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US465197A US3359207A (en) | 1965-06-18 | 1965-06-18 | Chlorine-stable detergent compositions and process for the preparation thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1107166A true GB1107166A (en) | 1968-03-20 |
Family
ID=23846840
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB27290/66A Expired GB1107166A (en) | 1965-06-18 | 1966-06-17 | Chlorine-stable detergent compositions and process for the preparation thereof |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3359207A (en) |
| BE (1) | BE682739A (en) |
| GB (1) | GB1107166A (en) |
| NL (2) | NL6608107A (en) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA672909B (en) * | 1966-05-18 | |||
| US3625902A (en) * | 1968-10-11 | 1971-12-07 | Stauffer Chemical Co | Method of preparing agglomerated detergent composition |
| US3518201A (en) * | 1969-09-04 | 1970-06-30 | Grace W R & Co | Chlorine release detergent composition with improved defoamer stability |
| US3520815A (en) * | 1969-09-04 | 1970-07-21 | Grace W R & Co | Process of preparing stable detergent composition |
| US3741904A (en) * | 1971-05-05 | 1973-06-26 | Miles Lab | Process for preparation of a protected granule and dishwashing composition formed therewith |
| US3888781A (en) * | 1972-09-05 | 1975-06-10 | Procter & Gamble | Process for preparing a granular automatic dishwashing detergent composition |
| US4078099A (en) * | 1976-08-25 | 1978-03-07 | Lever Brothers Company | Encapsulated bleaches and methods for their preparation |
| US4244832A (en) * | 1979-07-27 | 1981-01-13 | Basf Wyandotte Corporation | Phosphate-free machine dishwashing detergents useful at low temperatures |
| US4306987A (en) * | 1979-11-19 | 1981-12-22 | Basf Wyandotte Corporation | Low-foaming nonionic surfactant for machine dishwashing detergent |
| US4272394A (en) * | 1979-11-19 | 1981-06-09 | Basf Wyandotte Corporation | Machine dishwashing detergents containing low-foaming nonionic surfactants |
| US4836951A (en) * | 1986-02-19 | 1989-06-06 | Union Carbide Corporation | Random polyether foam control agents |
| DE3818660A1 (en) * | 1987-06-05 | 1988-12-15 | Colgate Palmolive Co | FREE-FLOWING, POWDERY DISHWASHING DETERGENT AND METHOD FOR PRODUCING THE SAME |
| US4931203A (en) * | 1987-06-05 | 1990-06-05 | Colgate-Palmolive Company | Method for making an automatic dishwashing detergent powder by spraying drying and post-adding nonionic detergent |
| US4973419A (en) * | 1988-12-30 | 1990-11-27 | Lever Brothers Company, Division Of Conopco, Inc. | Hydrated alkali metal phosphate and silicated salt compositions |
| DE69108922T2 (en) * | 1990-07-10 | 1995-12-14 | Procter & Gamble | METHOD FOR PRODUCING A CLEANING AGENT WITH HIGH BULK DENSITY. |
| CA2115425C (en) * | 1991-08-13 | 1997-12-16 | Mary E. Raleigh | Process for making granular automatic dishwashing detergent |
| US5612305A (en) * | 1995-01-12 | 1997-03-18 | Huntsman Petrochemical Corporation | Mixed surfactant systems for low foam applications |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL217279A (en) * | 1956-05-15 | |||
| US3154497A (en) * | 1962-03-21 | 1964-10-27 | Mankowich Abraham | Method of improving the storage properties of alkaline detergent compositions |
| CA712126A (en) * | 1963-02-25 | 1965-06-22 | Unilever Limited | Method for preparing detergent compositions |
| US3306858A (en) * | 1965-06-17 | 1967-02-28 | Economics Lab | Process for the preparation of storage stable detergent composition |
-
0
- NL NL132419D patent/NL132419C/xx active
-
1965
- 1965-06-18 US US465197A patent/US3359207A/en not_active Expired - Lifetime
-
1966
- 1966-06-10 NL NL6608107A patent/NL6608107A/xx unknown
- 1966-06-17 GB GB27290/66A patent/GB1107166A/en not_active Expired
- 1966-06-17 BE BE682739D patent/BE682739A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| NL6608107A (en) | 1966-12-19 |
| US3359207A (en) | 1967-12-19 |
| BE682739A (en) | 1966-12-01 |
| NL132419C (en) |
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