GB1107101A - Alkyl aromatic hydrocarbons suitable for preparing oil-solublc sulfonates and processes for preparing the same - Google Patents

Alkyl aromatic hydrocarbons suitable for preparing oil-solublc sulfonates and processes for preparing the same

Info

Publication number
GB1107101A
GB1107101A GB16837/65A GB1683765A GB1107101A GB 1107101 A GB1107101 A GB 1107101A GB 16837/65 A GB16837/65 A GB 16837/65A GB 1683765 A GB1683765 A GB 1683765A GB 1107101 A GB1107101 A GB 1107101A
Authority
GB
United Kingdom
Prior art keywords
olefin
preparing
aromatic hydrocarbon
amount
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB16837/65A
Inventor
Harold Hildenbrandt Eby
Gerald Lee Nield
Kyle Winfield Resh
John Henry Smith
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ConocoPhillips Co
Original Assignee
Continental Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Continental Oil Co filed Critical Continental Oil Co
Publication of GB1107101A publication Critical patent/GB1107101A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/107—Monocyclic hydrocarbons having saturated side-chain containing at least six carbon atoms, e.g. detergent alkylates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/14—Catalytic processes with inorganic acids; with salts or anhydrides of acids
    • C07C2/16—Acids of sulfur; Salts thereof; Sulfur oxides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
    • C07C2/66—Catalytic processes
    • C07C2/68—Catalytic processes with halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/053—Sulfates or other compounds comprising the anion (SnO3n+1)2-
    • C07C2527/054—Sulfuric acid or other acids with the formula H2Sn03n+1
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
    • C07C2527/126—Aluminium chloride

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Alkylate suitable for preparing oil-soluble sulphonates is obtained by polymerizing mainly to dimer a C3-C18 olefin in the presence of an acidic or Friedel-Crafts catalyst, alkylating an aromatic hydrocarbon with the polymer in the presence of a Friedel-Crafts catalyst and recovering from the product an alkylate boiling above 325 DEG F. at 20 mm. Hg. pressure and having a molecular weight above 320 and a "mono" (i.e. neglecting alkyl groups in the aromatic hydrocarbon alkylated) branched chain alkyl aromatic content greater than 50% mol. The olefin may be a C5-C12 gasoline obtained by polymerizing propylene or propylene tetramer and is dimerized with sulphuric acid at -10 DEG to 75 DEG C. or preferably with catalyst sludge from the alkylation step in an amount of 0.25-4 parts per part by wt. of olefin at 15-75 DEG C. In the latter case the entire reaction product passes to the alkylation. The aromatic hydrocarbon may be benzene, toluene, xylene, ethylbenzene or naphthalene or a refinery aviation blending component in an amount of 0.2-10 parts per part by wt. of olefin fed to the dimerization. Preferred catalyst is a promoted aluminium chloride in an amount of 0.02-0.25 part per part by wt. of olefin feed. Reaction is effected at 5-75 DEG C.
GB16837/65A 1964-05-14 1965-04-21 Alkyl aromatic hydrocarbons suitable for preparing oil-solublc sulfonates and processes for preparing the same Expired GB1107101A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US367417A US3410925A (en) 1964-05-14 1964-05-14 Dimerization of c3 to c18 olefins

Publications (1)

Publication Number Publication Date
GB1107101A true GB1107101A (en) 1968-03-20

Family

ID=23447083

Family Applications (1)

Application Number Title Priority Date Filing Date
GB16837/65A Expired GB1107101A (en) 1964-05-14 1965-04-21 Alkyl aromatic hydrocarbons suitable for preparing oil-solublc sulfonates and processes for preparing the same

Country Status (5)

Country Link
US (1) US3410925A (en)
BE (1) BE679896A (en)
CH (1) CH458309A (en)
GB (1) GB1107101A (en)
NL (1) NL6506214A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2541079A1 (en) * 1975-06-11 1976-12-23 Liquichimica Spa PROCESS FOR THE PRODUCTION OF ALKYLBENZENE
DE2803420A1 (en) * 1977-01-28 1978-08-31 Exxon Research Engineering Co IMPROVED ALKYLATES AND SULPHONIC ACIDS, AND SULPHONATES MANUFACTURED THEREFORE
EP0017457A1 (en) * 1979-04-05 1980-10-15 Mobil Oil Corporation The use of a synthetic oil as a lubricating oil
DE3122078A1 (en) * 1980-06-03 1982-03-04 Nippon Petrochemical Co., Ltd., Tokyo Liquid which can be used as lubricant oil, process for the preparation thereof, and the use thereof
WO2011075523A3 (en) * 2009-12-18 2011-11-03 Exxonmobil Research And Engineering Company Process and system to convert light olefins to diesel and other distillates

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0001318B1 (en) * 1977-08-04 1981-12-02 Exxon Research And Engineering Company Overbased monoalkyl orthoxylene and monoalkyl toluene sulfonates and use as lubricant additives
DE2966026D1 (en) * 1978-10-26 1983-09-08 Gulf Research Development Co Insulation of electrical apparatus with a synthetic transformer oil
DE10039995A1 (en) * 2000-08-11 2002-02-21 Basf Ag Process for the preparation of alkylarylsulfonates

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2637750A (en) * 1949-07-14 1953-05-05 Phillips Petroleum Co Production of monoalkyl aromatic hydrocarbons
US2813917A (en) * 1954-07-06 1957-11-19 Continental Oil Co Preparation of alkaryl sulfonates
US3109869A (en) * 1958-04-09 1963-11-05 Sinclair Research Inc Process for dimerizing olefins
US3070636A (en) * 1959-11-25 1962-12-25 Atlantic Refining Co Process for the preparation of position isomers of c to c monochloro straight-chain paraffins
BE616990A (en) * 1960-09-23

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2541079A1 (en) * 1975-06-11 1976-12-23 Liquichimica Spa PROCESS FOR THE PRODUCTION OF ALKYLBENZENE
DE2803420A1 (en) * 1977-01-28 1978-08-31 Exxon Research Engineering Co IMPROVED ALKYLATES AND SULPHONIC ACIDS, AND SULPHONATES MANUFACTURED THEREFORE
EP0017457A1 (en) * 1979-04-05 1980-10-15 Mobil Oil Corporation The use of a synthetic oil as a lubricating oil
DE3122078A1 (en) * 1980-06-03 1982-03-04 Nippon Petrochemical Co., Ltd., Tokyo Liquid which can be used as lubricant oil, process for the preparation thereof, and the use thereof
WO2011075523A3 (en) * 2009-12-18 2011-11-03 Exxonmobil Research And Engineering Company Process and system to convert light olefins to diesel and other distillates

Also Published As

Publication number Publication date
US3410925A (en) 1968-11-12
DE1518650A1 (en) 1969-04-10
CH458309A (en) 1968-06-30
BE679896A (en) 1966-10-03
NL6506214A (en) 1965-11-15

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