GB1105139A - Production of surface coatings - Google Patents

Production of surface coatings

Info

Publication number
GB1105139A
GB1105139A GB2012164A GB2012164A GB1105139A GB 1105139 A GB1105139 A GB 1105139A GB 2012164 A GB2012164 A GB 2012164A GB 2012164 A GB2012164 A GB 2012164A GB 1105139 A GB1105139 A GB 1105139A
Authority
GB
United Kingdom
Prior art keywords
resin
bath
formaldehyde
coated
paraformaldehyde
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2012164A
Inventor
Stanley Russell Finn
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BLUNDELL PERMOGLAZE Ltd
Original Assignee
BLUNDELL PERMOGLAZE Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BLUNDELL PERMOGLAZE Ltd filed Critical BLUNDELL PERMOGLAZE Ltd
Priority to GB2012164A priority Critical patent/GB1105139A/en
Publication of GB1105139A publication Critical patent/GB1105139A/en
Expired legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • B05D7/26Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials synthetic lacquers or varnishes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4484Anodic paints

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

A coating composition comprises a dispersion of a film-forming resin in an aqueous medium including an aldehyde or a ketone and a component which contains solubilizing groups and has been made water-soluble or water-dispersible by treatment with a base, the base being liberated as free base during formation of a water-insoluble coating, the aldehyde or ketone being capable of reacting with free base to form a non-ionic compound, and the resin being incapable of modification by aldehyde or ketone under the conditions existing in the coating medium. The component made water-soluble or water-dispersible may be the film-forming resin or a dispersing or emulsifying resin for such resin. The base may consist of ammonia, primary, secondary, tertiary amines, hydroxylamine or its amine derivatives and compounds capable of reacting with such bases are formaldehyde, paraformaldehyde, acetaldehyde, or polymers thereof, glyoxal, chloral, acetophenone. The resin deposited e.g. a phenolic resin may react with the non-ionic product e.g. hexamethylene tetramine to effect cross-linking of the resin, and additional hexamethylene tetramine may be dissolved in the bath to maintain an increased concentration sufficient to complete the cross-linking. The film-forming resin may be natural or synthetic e.g. an ammonium salt of a polycarboxylic resin. In the examples, steel panels are coated by electrodeposition using a bath containing an aqueous solution of amine neutralized maleinized copolymer resin oil and (1) paraformaldehyde at an initial pH of 8.8 rising to 8.95, (2) formaldehyde at pH 9.0 rising to 9.05; steel panels are coated and form the anode in a bath of paint comprising a water dispersion of (4) a modified carboxylated oil, iron oxide pigment, talc, hexamethylene tetramine, formaldehyde at pH 7.0, (5) the resin of (1), carbon black, hexamethylene tetramine, paraformaldehyde at pH 9.0; in (6) a solution of a methacrylic acid - ethyl acrylate - 2 ethyl hexyl acrylate-styrene copolymer rendered soluble by the addition of ammonium hydroxide and containing formaldehyde is applied by spraying or electrodeposition at pH 9.7 to zinc; (7) steel panels are coated by electrodeposition using a bath comprising a phenolic-alkyd resin dispersion containing glyoxal; (8) a paint comprising a copolymer as in (6), zinc-coated rutile titanium dioxide, hexamethoxymethyl-melamine, formaldehyde is sprayed at pH 9.0 on to glass and baked; (9) mild steel panels are passed in succession through an electrodeposition bath having the composition described in (5) but omitting paraformaldehyde and replenished by the paint containing formaldehyde; (10) steel panels are coated in an electrodeposition bath comprising the composition described in (1), solid paraformaldehyde being present in the cathode compartment.ALSO:Coatings are produced by the application to the surface to be coated of an aqueous coating medium containing a film-forming resin capable of forming a coherent, paint-like or lacquer coating, such medium including a component which contains solubilizing groups and has been made water-soluble or water-dispersible by treatment with a base which is liberated as free base during formation of a water-insoluble coating of the resin on the surfaces, and an aldehyde or a ketone, or a compound containing an aldehyde group or a ketone group, capable of reacting with free base to form a non-ionic compound, the resin being incapable of modification by aldehyde or ketone under the conditions existing in the coating medium. The component made water-soluble or water dispersible may be the film forming resin or a dispersing or emulsifying resin for such resin. The surface may be of non-absorbent or absorbent materials such as paper, fabrics, non-woven fabrics. The coating can be produced by electro-deposition, and the effect of including an aldehyde or ketone is that pH value in the electro-deposition bath remains constant during coating and may be brought to any desired value. The base may consist of ammonia, primary, secondary, tertiary amines, hydroxylamine or its amine derivatives and compounds capable of reacting with such bases are formaldehyde, paraformaldehyde, acetaldehyde, or polymers thereof, glyoxal, chloral, acetophenone. The reactive substance e.g. formaldehyde may be added in solid, gaseous or aqueous form to the electro-deposition bath so as to be distributed throughout, or added to any liquid used to replenish the bath, or at any stage to reduce the pH as necessary, or to the cathode compartment, or the contents of the bath or cathode compartment may be circulated by pumping through say a tower in which a supply of formaldehyde is maintained. The resin deposited e.g. a phenolic resin may react with the non-ionic product e.g. hexamethylene tetramine to effect cross-linking of the resin, and additional hexamethylene tetramine may be dissolved in the bath to maintain an increased concentration sufficient to complete the cross-linking. The film-forming resin may be natural or synthetic e.g. an ammonium salt of a polycarboxylic resin. In the Examples, steel panels are coated by electro-deposition using a bath containing an aqueous solution of amine neutralised maleinized copolymer resin oil and (1) paraformaldehyde at an initial pH of 8.8 rising to 8.95, (2) formaldehyde at pH 9.0 rising to 9.05; steel panels are coated and form the anode in a bath of paint comprising a water dispersion of (4) a modified carboxylated oil, iron oxide pigment, talc, hexamethylene tetramine, formaldehyde at pH 7.0, (5) the resin of (1), carbon black, hexamethylene tetramine, paraformaldehyde at pH 9.0; in (6) a solution of a methacrylic acid-ethyl acrylate-2 ethyl hexyl acrylate-styrene copolymer rendered soluble by the addition of ammonium hydroxide and containing formaldehyde is applied by electro-deposition at pH 9.7 to zinc; (7) steel panels are coated by electro-deposition using a bath comprising a phenolic-alkyd resin dispersion containing glyoxal; (9) mild steel panels are passed in succession through an electro-deposition bath having the composition described in (5) but omitting paraformaldehyde and replenished by the paint containing formaldehyde; (10) steel panels are coated in an electro-deposition bath comprising the composition described in (1), solid paraformaldehyde being present in the cathode compartment.ALSO:Coatings are produced by the application to the surface to be coated of an aqueous coating medium containing a film-forming resin capable of forming a coherent, paint-like or lacquer coating, such medium including a component which contains solubilising groups and has been made water-soluble or water-dispersible by treatment with a base which is liberated as free base during formation of a water-insoluble coating of the resin on the surfaces, and an aldehyde or a ketone, or a compound containing an aldehyde group or a ketone group, capable of reacting with free base to form a non-ionic compound, the resin being incapable of modification by aldehyde or ketone under the conditions existing in the coating medium. The component made water-soluble or water dispersible may be the film forming resin or a dispersing or emulsifying resin for such resin. The surface may be of non-absorbent or absorbent materials such as paper, fabrics, non-woven fabrics. The coating can be produced by electro-deposition, and the effect of including an aldehyde or ketone is that pH value in the electrodeposition bath remains constant during coating and may be brought to any desired value. The base may consist of ammonia, primary, secondary, tertiary amines, hydroxylamine or its amine derivatives and compounds capable of reacting with such bases are formaldehyde, paraformaldehyde, acetaldehyde, or polymers thereof, glyoxal, chloral, acetophenone. The reactive substance, e.g. formaldehyde may be added in solid, gaseous or aqueous form to the electrodeposition bath so as to be distributed throughout, or added to any liquid used to replenish the bath, or at any stage to reduce the pH as necessary, or to the cathode compartment, or the contents of the bath or cathode compartment may be circulated by pumping through say a tower in which a supply of formaldehyde is maintained. The resin deposited, e.g. a phenolic resin may react with the non-ionic product, e.g. hexamethylene tetramine to effect cross-linking of the resin, and additional hexamethylene tetramine may be dissolved in the bath to maintain an increased concentration sufficient to complete the cross-linking. The film-forming resin may be natural or synthetic, e.g. an ammonium salt of a polycarboxylic resin. In the Examples, steel panels are coated by electrodeposition using a bath containing an aqueous solution of amine neutralised maleinised copolymer resin oil and (1) paraformaldehyde at an initial pH of 8.8 rising to 8.95, (2) formaldehyde at pH 9.0 rising to 9.05; steel panels are coated and form the anode in a bath of paint comprising a water dispersion of (4) a modified carboxylated oil, iron oxide pigment, talc, hexamethylene tetramine, formaldehyde at pH 7.0, (5) the resin of (1), carbon black, hexamethylene tetramine, paraformaldehyde at pH 9.0, in (6) a solution of a methacrylic acid-ethyl acrylate-2 ethyl hexyl acrylate-styrene copolymer rendered soluble by the addition of ammonium hydroxide and containing formaldehyde is applied by spraying or electrodeposition at pH 9.7 to zinc; (7) steel panels are coated by electrodeposition using a bath comprising a phenolic-alkyd resin dispersion containing glyoxal; (8) a paint comprising a copolymer as in (6), zinc-coated rutile titanium dioxide, hexamethoxy-methyl-melamine, formaldehyde is sprayed at pH 9.0 on to glass and baked; (9) mild steel panels are passed in succession through an electrodeposition bath having the composition described in (5) but omitting paraformaldehyde and
GB2012164A 1964-05-14 1964-05-14 Production of surface coatings Expired GB1105139A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2012164A GB1105139A (en) 1964-05-14 1964-05-14 Production of surface coatings

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2012164A GB1105139A (en) 1964-05-14 1964-05-14 Production of surface coatings

Publications (1)

Publication Number Publication Date
GB1105139A true GB1105139A (en) 1968-03-06

Family

ID=10140731

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2012164A Expired GB1105139A (en) 1964-05-14 1964-05-14 Production of surface coatings

Country Status (1)

Country Link
GB (1) GB1105139A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19652884A1 (en) * 1996-12-18 1998-10-15 Basf Coatings Ag Electrocoat and additive for cathodic electrodeposition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19652884A1 (en) * 1996-12-18 1998-10-15 Basf Coatings Ag Electrocoat and additive for cathodic electrodeposition

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