GB1104930A - Organometallic electrolytes for the electrode position of various metals - Google Patents

Organometallic electrolytes for the electrode position of various metals

Info

Publication number
GB1104930A
GB1104930A GB53724/65A GB5372465A GB1104930A GB 1104930 A GB1104930 A GB 1104930A GB 53724/65 A GB53724/65 A GB 53724/65A GB 5372465 A GB5372465 A GB 5372465A GB 1104930 A GB1104930 A GB 1104930A
Authority
GB
United Kingdom
Prior art keywords
atoms
compound
toluene
alkyl
formula
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB53724/65A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siemens Schuckertwerke AG
Siemens AG
Original Assignee
Siemens Schuckertwerke AG
Siemens AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens Schuckertwerke AG, Siemens AG filed Critical Siemens Schuckertwerke AG
Publication of GB1104930A publication Critical patent/GB1104930A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic System
    • C07F3/06—Zinc compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
    • C07F5/06—Aluminium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/54—Quaternary phosphonium compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions
    • C25D3/22—Electroplating: Baths therefor from solutions of zinc
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions
    • C25D3/42—Electroplating: Baths therefor from solutions of light metals
    • C25D3/44—Aluminium
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions
    • C25D3/54—Electroplating: Baths therefor from solutions of metals not provided for in groups C25D3/04 - C25D3/50

Abstract

In the electrolytic deposition of metals from organo-metal complexes, a suitable electrolyte for depositing Al, Zn, Ga, and In, is made by adding a compound of formula MeX1mRn to a compound of formula [R1R2R3R4Y]X2, where Me i Al, Zn, Ga, In, X1 and X2 are halogen, sulphate, cyanide, oxide or trifluoro methyl, R is alkyl of 1 - 6 C atoms, Y is N, P, Te, or As, and R1R2R3R4 of which one or more is phenyl, benzyl, aplobenzyl or strongly branched hydrocarbon of 3 to 12 C atoms and the remainder is alkyl of 1 - 4 C atoms. 1 to 2 mols of the metal complex is added to 1 mol of the second compound with solvents e.g. aromatic hydrocarbons or ethers if necessary. A typical product is [(CH3)3 (C6H5 CH2)N]F.2Al(C2H5)3, and is not spontaneously ignitable, or fuming in air. A table of examples of metal complexes is given with their conductivities. In examples, the aluminium complex diluted with toluene is used to plate copper, brass, nickel, or a molybdenum wafer at 2-5-3V with stirring. If toluene is omitted an atmosphere of inert gas is used. The electrolytes may be used for making semi-conductors, or super conductive elements.
GB53724/65A 1964-12-17 1965-12-17 Organometallic electrolytes for the electrode position of various metals Expired GB1104930A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DES0094664 1964-12-17

Publications (1)

Publication Number Publication Date
GB1104930A true GB1104930A (en) 1968-03-06

Family

ID=7518840

Family Applications (1)

Application Number Title Priority Date Filing Date
GB53724/65A Expired GB1104930A (en) 1964-12-17 1965-12-17 Organometallic electrolytes for the electrode position of various metals

Country Status (8)

Country Link
US (1) US3418216A (en)
AT (2) AT264945B (en)
BE (1) BE673423A (en)
CH (1) CH484195A (en)
DE (1) DE1496993B1 (en)
FR (1) FR1461819A (en)
GB (1) GB1104930A (en)
SE (1) SE344216B (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2453830C2 (en) * 1974-11-13 1986-07-31 Siemens AG, 1000 Berlin und 8000 München Bath and process for the galvanic deposition of shiny aluminum coatings
US3981819A (en) * 1974-12-23 1976-09-21 Rca Corporation Luminescent sulfides of monovalent and trivalent cations
US4076600A (en) * 1976-12-20 1978-02-28 R. O. Hull & Company, Inc. Leveling agent for acid zinc electroplating baths and method
FR2659871B1 (en) * 1990-03-20 1992-06-05 Inst Francais Du Petrole NONAQUEOUS LIQUID COMPOSITION WITH IONIC CHARACTER AND USE THEREOF AS SOLVENT. INVENTION OF MM. YVES CHAUVIN, DOMINIQUE COMMEREUC, ISABELLE GUIBARD, ANDRE HIRSCHAUER, HELENE OLIVIER, LUCIEN SAUSSINE.
CA2502900A1 (en) * 2002-08-16 2004-02-26 Roger Moulton Lewis acid ionic liquids
US7750166B2 (en) * 2002-08-16 2010-07-06 University Of South Alabama Ionic liquids containing a sulfonate anion
EP3066712A4 (en) * 2013-11-06 2017-07-05 Research Foundation Of The City University Of New York Ionic liquid comprising alkaline earth metal

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3268421A (en) * 1961-12-04 1966-08-23 Nat Steel Corp Electrodeposition of metals from a fused bath of aluminum halohydride organic complex and composition therefor
NL300204A (en) * 1962-11-14 1900-01-01

Also Published As

Publication number Publication date
AT264945B (en) 1968-09-25
SE344216B (en) 1972-04-04
US3418216A (en) 1968-12-24
BE673423A (en) 1966-04-01
CH484195A (en) 1970-01-15
DE1496993B1 (en) 1972-05-04
AT266861B (en) 1968-12-10
FR1461819A (en) 1966-12-09

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